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101.
Possible use of methylbenzenes as electrolyte additives for improving the overcharge tolerances of Li-ion batteries 总被引:1,自引:0,他引:1
Based on the voltammetric behaviour of a series of methyl-substituted benzenes in 1M LiPF6/EC-DMC electrolyte, xylene was selected and tested as an electrolyte additive for overcharge protection of Li-ion batteries. From the overcharge curves, CV behaviour and SEM observations of the cells in the presence of xylene, it was found that the additive can polymerize at the overcharged voltage to form a dense layer of isolating polymer film at the cathode surface, which blocks off further oxidation of the electroactive material and electrolyte and, therefore, improves the overcharge tolerance of the Li-ion battery. In addition, the xylene additive has shown only a slight influence on the cycling behaviour. 相似文献
102.
H. J. Dutton S. B. Johnson F. J. Pusch M. S. F. Lie Ken Jie F. D. Gunstone R. T. Holman 《Lipids》1988,23(5):481-489
An approach to the analysis of 55 possible nonconjugated positional isomers of octadecadienoic acid is described and tested
with mixtures of individual synthetic methyl esters. In the first example, by ozonolysis a sevencomponent mixture consisting
ofcis,cis 5,12-, 6,10-, 6,11-, 6,12-, 7,12-, 8,12-, and 9,12-octadecadienoates was converted to aldehydes, aldehyde-esters and dialdehydes.
These fragments were separated on a 50 m×0.2 mm free fatty acid phase (FFAP) vitreous silica capillary column. Equations for
an arbitrarily restricted 12×15 matrix of linear simultaneous equations and a computer solution of the matrix provided the
composition of the initial methyl octadecadienoate mixture. The power and significance of this method became apparent with
the observation that only two of the seven isomers in the known mixture were resolved as single peaks by state-of-the-art
capillary gas chromatography, but all seven were identified and estimated with acceptable error by the ozonolysis-capillary
gas chromatography-computer procedure. In a generalized approach to the analysis of the 55 possible nonconjugated isomers,
a computer program selects the appropriate matrix of linear simultaneous equations based on the aldehyde data supplied by
the analyst. Twenty of 21 combinations of seven isomeric esters taken five at a time have been analyzed to assess the efficiency
of the method. To illustrate applicability at this stage of development, the method has been used to analyze the diene products
of the hydrazine reduction of γ-linolenic acid and the diene products from the biological desaturation of isomeric monoenes.
The possibility of distinguishing geometric and positional isomers of 18∶2 has been opened by the observed separation ofcis-andtrans-unsaturated aldehydes and aldehyde-esters.
Presented in part at the 16th World Congress of the International Society for Fat Research, October 4–7, 1983, in Budapest,
Hungary, and at the American Oil Chemists' Society Meeting, May 15, 1986, in Honolulu, Hawaii. 相似文献
103.
简述了无水焦粉生产过程中的粉尘污染及其危害,分析了目前粉尘污染的现状、研究情况、环境监测及改造的必要性,提出了解决无水焦粉粉尘治理工艺改造的方案及粉尘的综合利用。 相似文献
104.
Decai Yang Bailan Zhang Yongkuan Yang Zheng Fang Guifen Sun Zhiliu Feng 《Polymer Engineering and Science》1984,24(8):612-617
Great attention has been paid to the toughening of isotactic polypropylene (PP) in recent years in order to make full use of this plastic. This paper presents the results of our study on the compatibility of PP with ethylene-propylene-diene rubber (EPT), polybutadiene rubber (PB) or styrene-butadiene rubber (SBR) through characterization of the blends' morphology, and on. the morphology and properties of binary blends of PP with EPT (EPT/PP) and ternary blends of PP, EPT, and polyethylene (PE) (EPT/PE/PP). Morphological structure of solution blends and the great improvement in low-temperature impact strength and other properties of the mechanical blends have shown the difference among EPT, PB, and SBR in compatibility with PP, the effectiveness of using EPT as PP's toughening agent, and the effect of EPT on EPT/PP blend as both toughening agent and compatibilizer. Addition of EPT to EPT/PP made interesting changes in morphology but no effect on properties was observed. 相似文献
105.
106.
Hao Liang Zhiqiang Zheng Zengchang Li Jie Xu Biao Chen Hui Zhao Qijin Zhang Hai Ming 《应用聚合物科学杂志》2004,93(2):681-685
A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004 相似文献
107.
石灰石在煤气化过程中的催化和固硫作用 总被引:1,自引:1,他引:1
基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。 相似文献
109.
研究为在炼油污水的CAST工艺的主反应区中 ,通过恰当控制pH值和DO(污水中溶解氧含量 )值 ,可以使硝化与反硝化反应同步进行 ,在去除COD ,BOD的同时 ,也可提高其脱氮效果 ,从而得出DO的最佳值为 0 .8mg/L ,pH为 7.3~ 7.7之间。 相似文献
110.
竹材丙酮法木质素高效分离技术研究 总被引:6,自引:1,他引:6
在一定的温度、压力条件下,利用丙酮提取竹材中的木质素,丙酮通过蒸馏回收后,可以反复利用;而通过蒸馏,得到的高纯度的木质素是重要的化工原料,整个过程形成一个封闭循环系统,基本上无三废排放;研究结果表明:当丙酮浓度为80%,液固比为10∶1,在最高反应温度160℃下保温3h,降解木质素的效果最佳;为解决制浆造纸行业废水对环境的污染问题提出了一条新的途径。 相似文献