Low-threshold patterned quantum well lasers grown by molecular beamepitaxy

GaAs/AlGaAs patterned quantum well lasers were grown by molecular beam epitaxy on grooved substrates. The carrier confinement and the real-index waveguiding in these lasers rely on lateral thickness variations in the quantum well active layer. Very low threshold currents, as low as 1.8 mA for uncoated devices at room temperature, with 63% differential efficiency have been obtained     

Specific rheological and electrical features of carbon nanotube dispersions in an epoxy matrix

The rheological analysis of epoxy pre-polymer/MWCNT dispersions indicates that a physical network is formed. This is destroyed with an imposed shear, giving a viscoplastic and shear thinning behavior. Such destruction is not reflected in dynamic viscoelastic experiments, due to the very rapid recovery of the MWCNT network in the pre-polymer matrix. This responds to the observed lower electrical than rheological percolation threshold. Electrical conductivity results fulfill electron hopping/tunnelling mechanism, which implies a tube–tube distance close to 5 nm. However, rheological percolation requires nanotubes should touch each other, since no polymer chains are implied in the network.     

Synthesis and Characterization of an Fe/Co Ferrite Spinel Oxide Film Produced by Using N2/Steam Heat Treatment on Two Maraging Steels

An experimental procedure was developed to obtain an oxide layer formed mainly by spinel on maraging steels. It consists of different stages with specific conditions, such as atmospheres rich in nitrogen and water vapor, and different steps of temperatures and times. Tests were performed on grade 300 and 350 maraging steels. Oxide layer characterization was done using optical and electron microscopy, spectroscopy, X-ray diffraction, and nanoscratch tests in order to determine the adhesion force as well as to observe the main deformation mechanism induced under sliding tests. In both steels, oxide layers are formed by the spinel’s Fe₃O₄ and CoFe₂O₄ in amounts close to ca. 85 pct, whereas TiO₂ and MoO₃ represent the other 15 pct. No hematite was found. The low oxygen availability during the heat treatment was fundamental for avoiding hematite formation. A nickel-rich austenitic phase formed at the metal-oxide interface due the kinetics of the oxidation process of the cobalt, iron, and molybdenum. The particular conditions of the heat treatments induced the formation of a mixture of iron, nickel, and cobalt spinel ferrites, thereby contradicting previous studies that said that only magnetite would be formed. The sliding tests at the nanometric length scale highlight that the layer formed on maraging 300 grade presents a better adhesion than the other investigated material due to the fact that it requires more load in order to induce cracks located at the edge of the sliding track and, subsequently, the chipping of the formed layer.

Graphical abstract

     

Dry reforming of methane over LaNi1−yByO3±δ (B = Mg,Co) perovskites used as catalyst precursor

Perovskites LaNiO₃, LaNi_1−xMg_xO_3−δ and LaNi_1−xCo_xO_3−δ were synthesized by auto combustion method. TPR analysis reveled that Mg or Co substituted perovskites were more difficult to reduce. The perovskites were evaluated as catalyst precursors in the dry reforming of methane. Catalysts obtained by reduction of LaNiO₃ and LaNi_1−xMg_xO_3−δ perovskite had the highest catalytic activity for CO₂ reforming of CH₄ at 700 °C using drastic reaction conditions (10 mg of catalyst, a mixture of CH₄/CO₂ without dilution gas). Methane and carbon dioxide conversions were 57% and 67%, respectively, with a H₂/CO ratio equal to 0.47.The presence of cobalt leads to a decrease of the catalytic activity. This decreasing of activity may be attributed to the Co–Ni alloy formation. Computational calculations revealed that Ni atom cleaves the C–H atom while Co is not able to activate the CH₄ molecule. The interaction energy of CH₄ with the Ni and CO atom was 18 kcal/mol and 0.7 kcal/mol, respectively.The catalysts were characterized by TPR, TEM and in situ XRD.     

Curing of epoxy/carbon nanotubes physical networks

A melt‐mixing procedure has been used to disperse multi‐walled carbon nanotubes (MWCNT) in an epoxy matrix. According to dynamic viscoelastic results, a physical network is formed for carbon nanotube concentrations of 0.3 weight per cent (wt%) and above. The temperature activated curing process is followed analyzing the evolution of the dynamic viscoelastic functions and the dielectric loss with time. Curing process from a physical to a chemical network is monitored. The presence of MWCNT accelerates curing, even when the rheological percolation is not reached (absence of physical network). Several hypotheses are considered to explain this result. Electrical conductivity decreases during cure, so lower electrical conductivities are found for cured MWCNT/epoxy samples than for dispersions: this is explained by a distortion of nanotubes physical network and a reduction of the ionic conductivity contribution of the liquid phase. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers     

Pulsed and CW high temperature operation of InGaAs/GaAs strained layer vertical cavity surface emitting lasers

The performance of strained layer InGaAs/GaAs vertical cavity surface emitting lasers defined by ion implantation over a approximately 75 degrees C temperature range is reported on. Maximum CW output levels for the temperature extremes of 10 and 86 degrees C are 7.5 MW and 200 mu W, respectively for 20*20 mu m/sup 2 /devices. The temperature dependence of the CW threshold current exhibits exponential behaviour to 80 degrees C.<>     

A pseudomorphic AlGaAs/n+-InGaAs metal-insulator-dopedchannel FET for broad-band, large-signal applications

Molecular beam epitaxy (MBE)-grown L_g=1.7-μm pseudomorphic Al_0.38Ga_0.62As/n⁺-In_0.15Ga _0.85As metal-insulator-doped channel FETs (MIDFETs) are presented that display extremely broad plateaus in both f_T and f_max versus V_GS, with f_T sustaining 90% of its peak over a gate swing of 2.6 V. Drain current is highly linear with V_GS over this swing, reaching 514 mA/mm. No frequency dispersion in g _m up to 3 GHz was found, indicating the absence of electrically active traps in the undoped AlGaAs pseudoinsulator layer. These properties combine to make the pseudomorphic MIDFET highly suited to linear, large-signal, broadband applications     

Lightweight monitoring of MPI programs in real time

Current technologies allow efficient data collection by several sensors to determine an overall evaluation of the status of a cluster. However, no previous work of which we are aware analyzes the behavior of the parallel programs themselves in real time. In this paper, we perform a comparison of different artificial intelligence techniques that can be used to implement a lightweight monitoring and analysis system for parallel applications on a cluster of Linux workstations. We study the accuracy and performance of deterministic and stochastic algorithms when we observe the flow of both library‐function and operating‐system calls of parallel programs written with C and MPI. We demonstrate that monitoring of MPI programs can be achieved with high accuracy and in some cases with a false‐positive rate near 0% in real time, and we show that the added computational load on each node is small. As an example, the monitoring of function calls using a hidden Markov model generates less than 5% overhead. The proposed system is able to automatically detect deviations of a process from its expected behavior in any node of the cluster, and thus it can be used as an anomaly detector, for performance monitoring to complement other systems or as a debugging tool. Copyright © 2005 John Wiley & Sons, Ltd.     

Multi-domain dual reciprocity for the solution of inelastic non-Newtonian flow problems at low Reynolds number

An efficient boundary element solution of the motion of inelastic non-Newtonian fluids at low Reynolds number is presented in this paper. For the numerical solution all the domain integrals of the boundary element formulation have been transformed into equivalent boundary integrals by means of the dual reciprocity method (DRM). To achieve an accurate approximation of the non-linear and non-Newtonian terms two major improvements have been made to the DRM, namely the use of augmented thin plate splines as interpolation functions, and the partition of the entire domain into smaller subregions or domain decomposition. In each subregion or domain element the DRM was applied together with some additional equations that ensure continuity on the interfaces between adjacent subdomains. After applying the boundary conditions the final systems of equations will be sparse and the approximation of the nonlinear terms will be more localised than in the traditional DRM. This new method known as multidomain dual reciprocity (MD-DRM) has been used to solve several non-Newtonian problems including the pressure driven flow of a power law fluid, the Couette flow and two simulations of industrial polymer mixers. Received 7 February 2001