Synthesis,Structure, and Physicochemical Properties of AI 4[UO2(CO3)3]·nH2O (AI = Li,Na, K,NH4)

Procedures for the synthesis of Li₄[UO₂(CO₃)₃]·1.5H₂O, Na₄[UO₂(CO₃)₃], K₄[UO₂(CO₃)₃], (NH₄)₄[UO₂(CO₃)₃], and K₃Na[UO₂(CO₃)₃] were optimized. The structures of these compounds and their thermolysis were studied by X-ray diffraction, precision IR spectroscopy, and thermal analysis. The standard enthalpies of formation of these compounds at 298.15 K were determined by reaction calorimetry.     

Dissociation of gaseous hydrates in beds

A mathematical model which accounts for the mobility of the liquid phase is constructed to describe the dissociation of gaseous hydrates in beds.Translated from Inzhenerno-fizicheskii Zhurnal, Vol. 60, No. 5, pp. 736–742, May, 1991.     

Increase in urinary calcium and oxalate after fructose infusion

We have previously shown that an oral glucose load increased both calciuria and oxaluria while the ingestion of fructose induced a rise in calciuria and a decrease in oxaluria. This latter effect remains unclear and might be linked to the reduced intestinal oxalate absorption subsequent to digestive intolerance in some subjects. Such a hypothesis could be enlightened by the study of a parenteral fructose load. Therefore in 7 healthy subjects, we compared the effects of fructose infusion (F) (15 min iv infusion at 0.185 mmol/kg BW/min) to a control glucose infusion (G) on urinary calcium and oxalate. In this study, glycemia and insulinemia increased less after (F) than after (G) (respectively + 21% vs + 216%, p < 0.001 and + 230% vs + 402%, p < 0.05) and phosphatemia decreased less after (F) than after (G) (-7% vs -14%, p < 0.05). Urinary calcium and oxalate increased only after (F) (respectively + 64%, p < 0.01 and + 60%, p < 0.05). Urinary uric acid, another urolithiasis factor, increased after both (F) and (G) (respectively + 45%; p < 0.01 and + 42%; p < 0.01) but uricemia increased only after (F) (+ 25%; p < 0.01). Our results suggest an additional reason to avoid the use of fructose in parenteral nutrition, particularly in individuals with a known history of either calcium oxalate or urate urolithiasis.     

Chelated alkoxyalumoxanes and a silica-free binder based on them

Chelated alkoxyalumoxane oligomers have been synthesized through consecutive hydrolysis and alcoholysis of organoaluminum compounds stabilized by compounds capable of keto-enol tautomerism. The chelated alkoxyalumoxanes were used to prepare a silica-free binder for the fabrication of heat-resistant (up to 2050°C), chemically inert corundum ceramic composites. The likely structures of the synthesized preceramic alumoxane oligomers were inferred from physicochemical characterization results (¹H, ¹³C, and ²⁷Al NMR, IR spectroscopy, mass spectrometry, gel-permeation chromatography, thermal analysis, and elemental analysis).     

Schäden durch kerbinduzierte Schwingbrüche

Failures by notch induced fatigue fractures Notches produce local stress concentrations and promote the formation of fatigue cracks. Characteristic types of notches as a result of design, manufacturing and operation are presented and remedial measures are discussed. Examples demonstrate the effect of different kinds of notches on various components.     

Thermal expansion characteristics of a titanium modified austenitic stainless steel: measurement by high-temperature X-ray diffraction and modelling using Grüneisen formalism

The thermal expansion of a titanium modified, swelling resistant austenitic stainless steel designated as D9 is studied by measuring the lattice parameter as a function of temperature in the range 300-1300 K by high-temperature X-ray diffraction technique. The thermal expansion data thus obtained is in reasonable agreement with the typical thermal expansion values reported for similar nuclear grade austenitic stainless steels. However, at temperatures exceeding 900 K, the measured thermal expansivity exhibits a pronounced non-linear increase due partly to the precipitation of complex carbide and intermetallic phases. The high-temperature thermal expansion data obtained in the present study are augmented by modelling the low-temperature thermal expansion behaviour by Grüneisen formalism.     

Natural language interface and database issues in applying expertsystems to power systems

Applying expert systems (ESs) to power system operation means embedding them in an existing environment which consists of computational facilities (SCADA, EMS) on one side, and the operating staff on the other side. An interface between process data and ES data is required to achieve this goal. For an unambiguous and clear information exchange with and good acceptance by the operators, an approximate natural language dialogue of the ES is desirable. Several approaches to these problems are described