Design of a Cost‐Reduced Flexible Plant for Supercritical Fluid‐Assisted Applications

A novel batch plant for supercritical CO₂ applications is proposed which is not equipped with expensive components, such as high‐pressure pumps, making it particularly suitable for bench‐scale use. For the first time, the use of a hanging scale is suggested to weigh the amount of CO₂ required for the experiment and the use of the thermodynamics to reach the working conditions. The rig is able to cover different applications, e.g., aerogel drying, impregnation, and extraction, showing high flexibility. An approximate cost analysis has been performed considering as a reference a 150‐mL vessel. It has been calculated that both the setup and running costs are considerably lower than the common batch and semicontinuous rigs.     

磷酸硼对樟子松的阻燃影响

采用磷酸硼对木材进行改性处理,测定了处理后试材的阻燃性、抗流失性、吸湿性、力学性能.研究结果表明,磷酸硼处理后试材,吸药量达到20.47 kg/m3以上时,垂直燃烧实验可达到到F-0级水平;通过灼烧实验,磷酸硼处理的木粉在500℃灼烧时残留率可达到97.997％;此改性剂具有较好阻燃性能和一定的抗流失性,常压下磷酸硼处理的樟子松试件LRV为50.28％;木材顺纹抗压强度平均下降了 8.67％,无明显变化;木材抗弯曲压强度平均下降了 27.95％.但磷酸硼阻燃剂在高湿条件下有一定的吸湿性,使用性能有待改进,并应注意采取防护措施.     

载锌NaY分子筛对FCC汽油吸附脱硫性能的影响

采用液相离子交换法将锌离子负载到NaY分子筛上,得到ZnY分子筛脱硫吸附剂。考察了锌离子负载浓度和不同焙烧温度对ZnY分子筛吸附脱硫性能的影响。研究脱硫实验中吸附温度和吸附空速对FCC汽油脱硫性能的影响,样品中的硫含量通过微库仑综合分析仪进行测定。结果表明,Zn(NO₃)₂负载浓度0.30 mol·L^-1、焙烧温度500 ℃、吸附温度30 ℃和吸附空速0.5 h^-1条件下对吸附脱硫性能最有利,脱硫率超过80%。考察两种方法对吸附剂进行再生。     

稀土与L-酪氨酸甘氨酸三元固态配合物的合成与表征

在乙醇溶液中合成了四种稀土与 L-酪氨酸、甘氨酸的三元固态配合物 RE( Tyr) 1.5 ( Gly) 4 ( Cl O4) 3( RE=La3+、Ce3+、Gd3+、Y3+) ,并通过摩尔电导、热分析、红外光谱等进行了表征。     

Improvement of PEEM images from thick inhomogeneous antiwear films using a thin Pt coating

Antiwear films formed from zinc dialkyl-dithiophosphate, in base oil, are known to create inhomogeneous agglomeration of patches on metallic surfaces up to 400 nm thick. It has been found that these patches (termed antiwear pads) are also non-conducting. These two features create difficulties in analyzing data obtained using X-ray photoelectron emission microscopy (X-PEEM). Topography and near-surface charging dominate images obtained using X-PEEM techniques, which can alter electron trajectories and lower signal-to-noise counts. It has been found that the application of a thin continuous platinum coating provides sufficient neutralization to eliminate the positive charge-buildup and improve signal-to-noise. This improves data analysis even with the thickest pads. Examples of charging alleviation and improved signal-to-noise ratios (obtained in the P L-edge spectroscopy) are shown. Furthermore, data analysis of the spectromicroscopy stacks show improved fitting and better polyphosphate distribution mapping for the films.     

Stability determination of soy lecithin-based emulsions by Fourier transform infrared spectroscopy

The stability of soy lecithin-stabilized emulsions was determined by Fourier transform infrared spectroscopy. Oilin-water (o/w) emulsions were prepared with 6% (vol/vol) medium-chain triglycerides (MCT), 94% (vol/vol) water, and 4% (wt/vol) Lecigran and Lecimulthin soy lecithin. There were little or no differences between the 4% Lecigran and 4% Lecimulthin emulsions for all vibrational regions studied (OH at 3348 cm⁻¹, C=O at 1741 cm⁻¹, PO and C−O−C at 1157 cm⁻¹, and P−O−C at 1101 cm⁻¹), but the control emulsion, without emulsifier, had increased vibrations as the emulsion separated. The weaker vibrations of the more stable emulsions were probably due to reduced molecular interaction at the interface. However, added magnesium or calcium chloride enhanced the vibration of these groups, probably by disrupting the lecithin interaction at the emulsion interface.     

Study of cryostructuration of polymer systems. XVI. Freeze–thaw‐induced effects in the low concentration systems amylopectin–water

Studies of the freeze–thaw behavior of low‐concentrated (0.01–0.25 g/dL) water solutions and dilute pastes (0.5–1.0 g/dL) of maize starch amylopectin showed that cryogenic treatment of these systems resulted in the formation of precipitated matter, whose yield and thermal characteristics (melting temperature and enthalpy) depended on the initial polymer concentration and conditions of freezing, frozen storage, and thawing. Research of the kinetic features of these cryoprecipitation events revealed at least two stages for this process: (i) a rapid stage, when the precipitation of virtually all of the dissolved polysaccharide occurred while the system was freezing, and (ii) a slower stage, the rate of which was mainly dependent on the thawing regimes or duration of the sample storage frozen at subzero temperatures. Cryoprecipitation phenomena were observed to be most extensive at temperatures 1–2° below the melting point of the frozen system. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 1740–1748, 2000     

加氢工艺技术生产25#变压器油

以江苏常二线油为原料,通过加氢微型试验装置,筛选出加氢精制催化剂3996、FV-1,将上述2种催化剂按照1：1（体积比）进行组合装填,进行一段加氢法生产25^#变压器油试验取得成功,并经过了工业生产试运行。结果表明,在适宜的操作条件下,可以利用原白油加氢装置生产出合格的25^#变压器油产品,优化了装置产品结构,提高了装置创效能力。     

TiO2/α-Fe2O3复合光催化剂的制备及表征

用溶胶-凝胶法在α-FeOOH上负载TiO2,经过煅烧制备了TiO2/α-Fe2O3光催化剂.用Brunauer-Emmett-Teller(BET)法测试氮吸附比表面积.用X射线衍射、透射电镜、扫描电镜、Fourier转换红外光谱等研究了不同煅烧温度制备的光催化剂物相组成和形貌特征.研究了不同煅烧温度制备的光催化剂对活性艳蓝X-BR染料的吸附和光催化性能.结果表明:与未负载TiO2的α-FeOOH相比,经过复合、350℃煅烧制备的TiO2/α-Fe2O3复合材料的比表面积有了显著增加,从35.4m2/g增加到167.7m2/g,但是,当温度高于450℃时,其比表面积又有所下降.随着煅烧温度的增加,其负载的TiO2晶型由锐钛矿转变为金红石型,粒径也逐渐增大.在煅烧温度为350℃时,TiO2/α-Fe2O3催化剂吸附和光催化性能最好,脱色率可达到85.19%.     

Design and measured performance of a solar chimney for natural-circulation solar-energy dryers

The design and construction of a solar chimney which was undertaken as part of a study on natural-circulation solar-energy dryers is reported. The experimental solar chimney consists of a 5.3 m high and 1.64 m diameter cylindrical polyethylene-clad vertical chamber, supported structurally by a steel framework and draped internally with a selectively absorbing surface. The performance of the chimney which was monitored extensively with and without the selective surface in place (to study the effectiveness of this design option) is also reported.