Magnesium-lead chloride batteries

The preparation of lead chloride cathodes, and their discharge in magnesium-lead chloride batteries, is described. The lead chloride blended with graphite is pasted on grids of expanded copper, using urea formaldehyde solutions as the binder. One-, five-, and fifteen-cell batteries were discharged at temperatures between –40°C and +45°C, at low current drains. For five-cell batteries energy densities in the range 10–30 Wh/lb were obtained. Mechanical properties of the cathode, so far as investigated, were excellent. The main difficulty was cathode softening during prolonged runs at high temperatures. At –40°C the battery attained working voltage in about 5 minutes; although slower than the Mg-AgCl system, the Mg-PbCl₂ system should meet many applications at this temperature.     

On the vibrational spectra of poly-1,1,2,2-tetrachlorobutane-a model for head-to-head poly(vinylidene chloride)

Infra-red and Raman spectra of poly (1,1,2,2-tetrachlorobutane), a model polymer for head-to-head poly(vinylidene chloride), are presented. Mutual exclusion of the infra-red and Raman spectra is observed and the polymer appears to be highly ordered. The preferred conformation of the polymer chain is inferred to be most probably in the form of a planar zigzag.     

Absence of tonic electromyographic activity during sleep in normal and spastic nonmimetic skeletal muscles in man

An electromyographic study of nonmimetic skeletal muscles was carried out in 8 normal adults and 4 patients with spastic hemiparesis during all stages of sleep for a total of 21 nights. All normal subjects showed absence of tonic electromyographic activity in all nonmimetic skeletal muscles in all stages of sleep. Also, during quiet, relaxed wakefulness, tonic muscle discharges disappeared in the normal subjects. Three patients with upper motor neuron spasticity demonstrated results during sleep similar to those obtained in the normal subjects. In the fourth patient, tonic muscle discharges persisted into stage 2 non-REM sleep, disappeared within 30 to 240 seconds following the onset of stage 2 sleep, and were absent during stages 3 and 4 sleep and REM sleep.     

Thyroid carcinoma after high-dose external radiotherapy for Hodgkin's disease: report of three cases

Three patients (two female and one male), who had received mantle irradiation for Hodgkin's disease eight, ten, and twelve years previously, developed papillary thyroid carcinoma. The radiation doses to the necks overlying the site of thyroid cancers were 3000, 4000, and 4100 rads, respectively. It has been stated that there is no risk of developing thyroid cancer with such high doses of external irradiation but apparently this complication will be encountered in a small number of patients.     

Granulated activated carbon modified with hydrophobic silica aerogel-potential composite materials for the removal of uranium from aqueous solutions

Aqueous solutions of 100 parts per billion (ppb) uranium at pH 7 were treated with granulated activated carbon (GAC) that had been modified with various formulations of hydrophobic aerogels. The composite materials were found to be superior in removing uranium from a stock solution compared to GAC alone evaluated by a modified ASTM D 3860-98 method for batch testing. The testing results were evaluated using a Freundlich adsorption model. The best performing material has parameters of n = 287 and Kf = 1169 compared to n = 1.00, and Kf = 20 for GAC alone. The composite materials were formed by mixing (CH3O)4Si with the hydrophobic sol-gel precursor, (CH3O)3SiCH2CH2CF3 and with specified modifiers, such as H3PO4, Ca(NO3)2, and (C2H5O)3SiCH2CH2P(O)(OC2H5)2, elation catalysts, and GAC in a supercritical reactor system. After gelation, supercritical extraction, and sieving, the composites were tested. Characterization by FTIR and 31P NMR indicate the formation of phosphate in the case of the H3PO4 and Ca(NO3)2 composites and phosphonic acid related compounds in the phosphonate composite. These composite materials have potential application in the clean up of groundwater at DOE and other facilities.     

Two-phase flow regimes in round, square and rectangular tubes during condensation of refrigerant R134a

An experimental investigation of two-phase flow mechanisms during condensation of refrigerant R134a in six small diameter round (4.91 mm), square (D_h=4 mm, α=1), and rectangular (4×6 and 6×4 mm: D_h=4.8 mm, α=0.67 and 1.5; 2×4 and 4×2 mm: D_h=2.67 mm, α =0.5 and 2) was conducted. Unique experimental techniques and test sections were developed to enable the documentation of the flow mechanisms during phase change. For each tube under consideration, flow mechanisms were recorded over the entire range of qualities for five different refrigerant mass fluxes between 150 and 750 kg m⁻² s⁻¹. The flow mechanisms were categorized into four different flow regimes: intermittent flow, wavy flow, annular flow, and dispersed flow. In addition, the large amount of data enabled the delineation of several different flow patterns within each flow regime, which provides a clearer understanding of the different modes of two-phase flow. Transition lines between the respective flow patterns and regimes on these maps were established based on the experimental data. It was found that for similar hydraulic diameters, flow regime transitions are not very strongly dependent on tube shape or aspect ratio. These maps and the transition lines can be used to predict the particular flow pattern or regime that will be established for a given mass flux, quality and tube geometry.     

Subelement Form-Drag Parameterization in Rough-Bed Flows

Spatial averaging of the Reynolds-averaged Navier–Stokes equations gives the double-averaged Navier–Stokes equations, for which boundary drag appears naturally and explicitly in momentum conservation equations. Increasing use of the double-averaged equations, e.g., for relating flows to three-dimensional bed roughness, for evaluation of profiles of flow stresses and velocities in ecologically significant regions below roughness tops, and for modeling purposes, requires parameterization of boundary drag at subelement scales. Based on seven flows over repeated square-rib roughness and ten flows over repeated fixed simulated sand waves, with measured velocities and bed pressures, expressions for form-drag coefficient CD = f (elevation below roughness top, relative roughness submergence, roughness steepness) are obtained for each of the two-dimensional roughness types. Using these equations, form drag variation with elevation below roughness tops can be calculated using either the double average of the square of local velocity (preferred based on conceptual considerations, trends in coefficient prediction, and also overall drag prediction) or the squared local double-averaged velocity, the roughness area being normal to the flow in each case. Integration of subelement drag given by these expressions is shown to give form-drag coefficient magnitudes and trends for complete individual elements comparable to those obtained by other authors based on measurements or numerical simulations. The ranges of roughness steepness and relative roughness submergence upon which the present equations have been derived need to be noted in consideration of application of the equations. In addition, effective application of the expressions is limited in regions of strongly negative double-averaged velocity. Further work remains to determine drag parameterization for alternative roughness geometries.