全文获取类型
收费全文 | 3221篇 |
免费 | 16篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 15篇 |
化学工业 | 164篇 |
金属工艺 | 18篇 |
机械仪表 | 13篇 |
建筑科学 | 39篇 |
能源动力 | 16篇 |
轻工业 | 44篇 |
水利工程 | 5篇 |
无线电 | 49篇 |
一般工业技术 | 123篇 |
冶金工业 | 2659篇 |
原子能技术 | 5篇 |
自动化技术 | 94篇 |
出版年
2022年 | 10篇 |
2021年 | 16篇 |
2020年 | 10篇 |
2018年 | 13篇 |
2017年 | 14篇 |
2016年 | 11篇 |
2014年 | 21篇 |
2013年 | 39篇 |
2012年 | 23篇 |
2011年 | 50篇 |
2010年 | 27篇 |
2009年 | 33篇 |
2008年 | 22篇 |
2007年 | 27篇 |
2006年 | 37篇 |
2005年 | 28篇 |
2004年 | 16篇 |
2003年 | 25篇 |
2002年 | 18篇 |
2001年 | 12篇 |
2000年 | 12篇 |
1999年 | 90篇 |
1998年 | 717篇 |
1997年 | 453篇 |
1996年 | 287篇 |
1995年 | 157篇 |
1994年 | 138篇 |
1993年 | 168篇 |
1992年 | 25篇 |
1991年 | 31篇 |
1990年 | 32篇 |
1989年 | 39篇 |
1988年 | 30篇 |
1987年 | 29篇 |
1986年 | 26篇 |
1985年 | 26篇 |
1984年 | 9篇 |
1983年 | 29篇 |
1982年 | 28篇 |
1981年 | 22篇 |
1980年 | 37篇 |
1979年 | 18篇 |
1978年 | 20篇 |
1977年 | 76篇 |
1976年 | 162篇 |
1975年 | 15篇 |
1974年 | 9篇 |
1972年 | 9篇 |
1970年 | 9篇 |
1955年 | 9篇 |
排序方式: 共有3244条查询结果,搜索用时 12 毫秒
81.
BACKGROUND: So far only a few cases of carcinoma in situ of the fallopian tube have been reported, but its detailed clinical and pathologic findings, including cytology, have not been fully described. CASE: A 70-year-old female was admitted to our hospital because of irregular genital bleeding. Endometrial smear revealed a small number of atypical cells with a clear background. Hysterectomy, bilateral salpingo-oophorectomy and omentectomy were performed. Grossly, a grayish white papillary tumor, measuring 1.5 x 1.0 cm, was observed within the lumen of the left fallopian tube. Microscopically, the diagnosis of papillary adenocarcinoma in situ of the left fallopian tube was made according to 1992 International Federation of Gynecologists and Obstetricians fallopian tube staging. CONCLUSION: Although endometrial brush cytology is not sensitive enough to detect a primary carcinoma of the fallopian tube, our case indicates that it may contribute useful information on extrauterine diseases and can detect a stage 0 cancer of the fallopian tube. Clinicians, as well as pathologists, should consider the possibility of fallopian tube cancer if cervical or endometrial cytology shows atypical cells with papillary patterns with a clear background but endometrial curettage cannot prove malignancy. 相似文献
82.
AS Shashkov NA Paramonov SP Veremeychenko H Grosskurth GM Zdorovenko YA Knirel NK Kochetkov 《Canadian Metallurgical Quarterly》1998,306(1-2):297-303
The O-specific polysaccharide of Pseudomonas fluorescens biovar B, strain IMV 247, was studied by acid hydrolysis, GLC-MS and 1H and 13C NMR spectroscopy, including 1D and 2D NOE, 2D hybrid TOCSY and ROESY (TORO), and 2D H-detected heteronuclear multiple-bond correlation (HMBC) experiments. The polysaccharide was found to contain L-rhamnose, 3.6-dideoxy-3-[(S)-3-hydroxybutyramido]-D-glucose (D-Qui3NHb), 2-acetamido- 2,4,6-trideoxy-4-[(S)-3-hydroxybutyramido-D-glucose (D-QuiNAc4NHb) and 2-acetamido-2- deoxy-D-galacturonic acid (D-GalNAcA). Partial acid hydrolysis of the polysaccharide resulted in a non-reducing GalNAcA-->QuiNAc4NHb disaccharide with the 3-hydroxybutyryl group glycosylated intramolecularly by the QuiN4N residue. The following structure of the tetrasaccharide repeating unit of the polysaccharide was established:-->4) -alpha-D-GalpNAcA-(1-->3)- alpha-D-QuipNAc4NHb-(1-->2)-beta-D-Quip3NHb-(1-->2)-alpha-L- Rhap(1-->. 相似文献
83.
An experimental investigation was undertaken to measure the intrinsic elastic properties of several of the microstructural components of human vertebral trabecular bone and tibial cortical bone by the nanoindentation method. Specimens from two thoracic vertebrae (T-12) and two tibiae were obtained from frozen, unembalmed human male cadavers aged 57 and 61 years. After drying and mounting in epoxy resin nanoindentation tests were conducted to measure Young's modulus and the hardness of individual trabeculae in the vertebrae and single osteons, and interstitial lamellae in the tibiae. Measurements on the vertebral trabeculae were made in the transverse direction, and the average Young's modulus was found to be 13.5 +/- 2.0 GPa. The tibial specimens were tested in the longitudinal direction, yielding moduli of 22.5 +/- 1.3 GPa for the osteons and 25.8 +/- 0.7 GPa for the interstitial lamellae. Analysis of variance showed that the differences in the measured moduli are statistically significant. Hardness differences among the various microstructural components were also observed. 相似文献
84.
Taylor H. Gerry; Dietrich Ann; Nuss Kathryn; Wright Martha; Rusin Jerome; Bangert Barbara; Minich Nori; Yeates Keith Owen 《Canadian Metallurgical Quarterly》2010,24(2):148
To investigate postconcussive symptoms (PCS) following pediatric mild traumatic brain injury (mTBI), 8- to 15-year-old children with mTBI (n = 186) and a comparison group with uncomplicated orthopedic injuries (OI, n = 99) were recruited from two emergency departments. Parent and child ratings of PCS and symptom counts were obtained within 3 weeks after injury (baseline) and at 1, 3, and 12 months postinjury. The mTBI group also completed magnetic resonance imaging at baseline. Group differences were examined using growth modeling, controlling for age at injury, sex, socioeconomic status, and (for parent-based measures) preinjury symptom levels. Relative to the OI group, the mTBI group had higher ratings of somatic PCS and parent counts of PCS at the initial assessments, but higher parent ratings of cognitive PCS and child counts of PCS throughout follow-up. Higher levels of PCS in the mTBI group were associated with motor-vehicle-related trauma, loss of consciousness, neuroimaging abnormalities, and hospitalization. The findings validate both transient and persistent PCS in children with mTBI and document associations of symptoms with injury and noninjury factors. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
85.
BM Gerlach TA Houser LC Hollis MD Tokach JC Nietfeld JJ Higgins GA Anderson BL Goehring 《Meat science》2012,92(4):805-807
Nursery-age pigs (n=198) were used to evaluate the difference in abscess formation at needle-free jet and conventional needle-and-syringe injection sites. Needle-free jet injection was used to administer injections in the neck and ham on one side of the animal whereas needle-and-syringe was used for neck and ham injections on the opposite side. Immediately prior to injection, the injection site surfaces were contaminated with an inoculum of Arcanobacterium pyogenes. Each pig was humanely euthanized 27 or 28days after injections. Histopathological results showed that needle-free jet injection was associated with more abscesses than needle-and-syringe injection at both neck (P=0.0625) and ham (P=0.0313) injection sites. Out of 792 injection sites, only 13 abscesses were observed, with 12 of those present at needle-free jet injection sites. Needle-free jet injection may increase the occurrence of injection site abscesses that necessitate carcass trimming at pork processing plants. 相似文献
86.
Purification and crystallization of complexes modeling the active state of the fragile histidine triad protein 总被引:1,自引:0,他引:1
Brenner C; Pace HC; Garrison PN; Robinson AK; Rosler A; Liu XH; Blackburn GM; Croce CM; Huebner K; Barnes LD 《Protein engineering, design & selection : PEDS》1997,10(12):1461-1463
Fragile histidine triad protein (Fhit) is a diadenosine triphosphate
(ApppA) hydrolase encoded at the human chromosome 3 fragile site which is
frequently disrupted in tumors. Reintroduction of FHIT coding sequences to
cancer cell lines with FHIT deletions suppressed the ability of these cell
lines to form tumors in nude mice even when the reintroduced FHIT gene had
been mutated to allow ApppA binding but not hydrolysis. Because this
suggested that the tumor suppressor activity of Fhit protein depends on
substrate-dependent signaling rather than ApppA catabolism, we prepared two
crystalline forms of Fhit protein that are expected to model its
biologically active, substrate-bound state. Wild-type and the His96Asn
forms of Fhit were overexpressed in Escherichia coli, purified to
homogeneity and crystallized in the presence and absence of ApppA and an
ApppA analog. Single crystals obtained by vapor diffusion against ammonium
sulfate diffracted X-rays to beyond 2.75 A resolution. High quality native
synchrotron X-ray data were collected for an orthorhombic and a hexagonal
crystal form.
相似文献
87.
The net transfer of labeled α-tocopherol from donor to acceptor lipoproteins at physiological concentrations was investigated.
Labeled lipoproteins were isolated i) followingin vitro addition of [3,4-3H]all rac-α-tocopherol to plasma, or ii) from plasma obtained 12–16 h after ingestion by normal subjects of an oral dose (100 mg each)
of 2R,4′R,8′R-α-[5,7-(C2H3)2]tocopheryl acetate and 2S,4′R′,R-α-[5-C2H3]tocopheryl acetate. A constant amount (on a protein basis) of labeled lipoprotein was incubated with an increasing amount
of unlabeled acceptor lipoprotein for 2 h at 37°C. No discrimination between stereoisomers of α-tocopherol was detected. Labeled
VLDL and labeled LDL (very low and low density lipoproteins, respectively) tended to retain their labeled tocopherol. Labeled
high density lipoproteins (HDL) readily transferred the labeled tocopherol to VLDL (>60% transferred), while the transfer
to LDL was dependent upon the ratio of labeled HDL/LDL with a lower net transfer at higher ratios. This dependency of the
distribution of tocopherol upon the ratio of HDL/LDL was also observedin vivo. The tocopherol/mg HDL protein was measured in 11 subjects with varying HDL levels. As the %HDL in the plasma increased from
14 to 50%, the tocopherol/HDL protein also increased (r2=0.37,P<0.05). 相似文献
88.
José F. Bartolomé Isabel Montero Marcos Díaz Sonia López-Esteban José S. Moya Sylvain Deville Laurent Gremillard Jerome Chevalier Gilbert Fantozzi 《Journal of the American Ceramic Society》2004,87(12):2282-2285
The aging behavior of 3-mol%-yttria-stabilized tetragonal zirconia (3Y-TZP) ceramics sintered in air and in reducing conditions was investigated at 140°C in water vapor. It was observed by X-ray diffraction (XRD) that 3Y-TZP samples sintered in reducing conditions exhibited significantly higher tetragonal-to-monoclinic transformation than samples with similar density and average grain size values but obtained by sintering in air. This fact is explained by the increase of the oxygen vacancy concentration and by the presence at the grain boundary region of a new aggregate phase formed because of the exolution of Fe2+ ions observed by X-ray photoelectron spectroscopy. 相似文献
89.
Mudassar Hussain Turgut Meydan Jerome A. Cuenca Yevgen Melikhov Ghulam Mustafa Ghulam Murtaza Yasir Jamil 《Ceramics International》2018,44(6):5909-5914
A series of co-precipitated Zn1?xCoxGdyFe2?yO4 spinel ferrites (x = 0.0–0.5, y = 0.00–0.10) sintered at 1000 °C were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), vibrating sample magnetometery (VSM) and microwave cavity perturbation (MCP). XRD patterns and FTIR spectra reveal formation of the spinel phase along with few traces of GdFeO3 second phase. The lattice constant decreases with an increasing amount of CoGd ions due to the segregation of Gd3+on the grain boundaries and due to replacement of lager Zn2+ ions with smaller Co2+ ions. SEM shows grain size to decrease with the increase of CoGd contents due to grain growth inhibition by the second phase. VSM results show remanence and saturation magnetization to exhibit an increasing trend due to Co substitution on octahedral sites and presence of a second phase. The coercivity increases with the increase of CoGd contents due to anisotropic nature of Co. MCP shows the complex magnetic permeability to increase with CoGd concentration while the complex permittivity decreases. 相似文献
90.
Conversion of polyhydroxybutyrate (PHB) to methyl crotonate for the production of biobased monomers 下载免费PDF全文
Within the concept of the replacement of fossil with biobased resources, bacterial polyhydroxybutyrate (PHB) can be obtained from volatile fatty acids (VFAs) from agro‐food waste streams and used as an intermediate toward attractive chemicals. Here we address a crucial step in this process, the conversion of PHB to methyl crotonate (MC), which can be converted via cross‐metathesis with ethylene to methyl acrylate and propylene, two important monomers for the plastics industry. The conversion of PHB to MC proceeds via a thermolysis of PHB to crotonic acid (CA), followed by an esterification to MC. At pressures below 18 bar, the thermolysis of PHB to CA is the rate‐determining step, where above 18 bar, the esterification of CA to MC becomes rate limiting. At 200°C and 18 bar, a full conversion and 60% selectivity to MC is obtained. This conversion circumvents processing and application issues of PHB as a polymer and allows PHB to be used as an intermediate to produce biobased chemicals. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42462. 相似文献