非金属掺杂的第二代二氧化钛光催化剂研究进展

寻求廉价、环境友好并具有可见光光催化活性的第二代光催化剂将是光催化发展进一步走向实用化的关键。氮掺杂的TIO2是新发现的具有可见光光催化活性的复合光催化剂,非金属掺杂可以使复合物的复合禁带宽度小于TIO2的禁带宽度,从而使TIO2的吸收边向可见光移动。对TIO2的氮、碳、硫、卤素掺杂国内外研究现状进行了系统评述,分析了提高TIO2可见光活性的原因,指出非金属元素特别是氮元素的阴离子掺杂是在不降低紫外光催化活性的基础上实现可见光响应的较好方法。     

Adjusting Pt Nanoparticle Size on SBA-15 by a Sol-Immobilisation Method Towards Naphthalene Hydrogenation

Regularly dispersed Pt particles on SBA-15 supported catalysts were synthesized with a Pt loading of 5 wt% by a sol-immobilisation method, wherein various Pt particle sizes within 1–5 nm were finely controlled via the adjustment of the addition amount of polyvinyl alcohol (PVA). A high PVA/Pt ratio of the initial solution tended to generate small Pt particles on the SBA-15 support due to intense protection against Pt particle aggregation. In addition, the effect of Pt particle size on naphthalene hydrogenation was investigated in terms of catalytic performance. Compared with the performance of other catalysts with Pt particle sizes greater or less than 3.5 nm, Pt nanoparticles with sizes centered at 3.5 nm exhibited excellent catalytic performance towards decalin. This excellent catalytic performance was mainly attributed to a suitable ratio of the edge sites to flat sites on these Pt nanoparticles, benefitting the rapid adsorption of naphthalene and dissociation of hydrogen.

Graphical Abstract

The Pt/SBA-15 catalysts were prepared by sol-immobilisation method. The highest performance was attributed to the Pt-nanoparticles with suitable flat/edge sites ratio.

     

Computing the Map of Geometric Minimal Cuts

In this paper we consider the following problem of computing a map of geometric minimal cuts (called MGMC problem): Given a graph G=(V,E) and a planar rectilinear embedding of a subgraph H=(V _H ,E _H ) of G, compute the map of geometric minimal cuts induced by axis-aligned rectangles in the embedding plane. The MGMC problem is motivated by the critical area extraction problem in VLSI designs and finds applications in several other fields. In this paper, we propose a novel approach based on a mix of geometric and graph algorithm techniques for the MGMC problem. Our approach first shows that unlike the classic min-cut problem on graphs, the number of all rectilinear geometric minimal cuts is bounded by a low polynomial, O(n ³). Our algorithm for identifying geometric minimal cuts runs in O(n ³logn(loglogn)³) expected time which can be reduced to O(nlogn(loglogn)³) when the maximum size of the cut is bounded by a constant, where n=|V _H |. Once geometric minimal cuts are identified we show that the problem can be reduced to computing the L _∞ Hausdorff Voronoi diagram of axis aligned rectangles. We present the first output-sensitive algorithm to compute this diagram which runs in O((N+K)log² NloglogN) time and O(Nlog² N) space, where N is the number of rectangles and K is the complexity of the Hausdorff Voronoi diagram. Our approach settles several open problems regarding the MGMC problem.     

超磁致伸缩作动器的率相关Hammerstein模型与H∞鲁棒跟踪控制

利用Hammerstein模型对超磁致伸缩作动器（Giant magnetostrictive actuators,GMA）的率相关迟滞非线性进行建模,分别以改进的 Prandtl-Ishlinskii（Modified Prandtl-Ishlinskii）模型和外因输入自回归模型（Autoregressive model with exogenous input,ARX）代表Hammerstein模型中的静态非线性部分和线性动态部分,并给出了模型的辨识方法. 此模型能在1～100Hz频率范围内较好地描述GMA的率相关迟滞非线性. 提出了带有逆补偿器和H∞鲁棒控制器的二自由度跟踪控制策略,实时跟踪控制实验结果证明了所提策略的有效性.     

改性木粉/PVC复合材料的研究进展

概述了PVC木塑复合材料的发展和背景与性能。简述了木质材料的性质和木粉改性的方法,如物理方法和化学方法。介绍了木塑复合材料的生产流程、成型方法(模压成型、挤出成型、注射成型及其成型设备,讨论了对工艺参数的一些要求。指出目前国内PVC木塑复合材料发展存在的一些问题,并指明了PVC木塑复合材料的应用前景。     

阻垢缓蚀剂对不锈钢管缓蚀效果的评定方法

用点蚀电位法和失重法评价了七种阻垢缓蚀剂在不同冷却水样中对不锈钢的缓蚀效果。用腐蚀失重法评价阻垢缓蚀剂对不锈钢的缓蚀效果，既不合理也很难测准。点蚀电位法是评价阻垢缓蚀剂对不锈钢缓蚀效果的有效方法，但要选择合适的空白水样。     

A heuristic biomarker selection approach based on professional tennis player ranking strategy

Extracting significant features from high-dimension and small sample size biological data is a challenging problem. Recently, Micha? Draminski proposed the Monte Carlo feature selection (MC) algorithm, which was able to search over large feature spaces and achieved better classification accuracies. However in MC the information of feature rank variations is not utilized and the ranks of features are not dynamically updated. Here, we propose a novel feature selection algorithm which integrates the ideas of the professional tennis players ranking, such as seed players and dynamic ranking, into Monte Carlo simulation. Seed players make the feature selection game more competitive and selective. The strategy of dynamic ranking ensures that it is always the current best players to take part in each competition. The proposed algorithm is tested on 8 biological datasets. Results demonstrate that the proposed method is computationally efficient, stable and has favorable performance in classification.     

一种基于ARM的集中器的硬件实现

介绍了一种以ARM9为核心,以Windows CE5.0为操作系统的集中器。它符合国家电网的Q/GDW 374.2-2009技术标准,可以在国家电网中使用。给出了集中器的系统框图,介绍了集中器的主要实现电路,论述了其主要工作原理。     

基于CY7C68013A的USB2.0高速接口设计

为了充分利用USB2.0的带宽,解决数据传输时存在的速度瓶颈问题,提出了一种基于CY7C68013A的USB2.0高速接口设计方法。采用CY7C68013A的SLAVE FIFO工作模式,芯片内部CPU不参与数据传输,FPGA设计的外部控制电路直接读写芯片内部FIFO,有效避免了内部CPU参与数据传输时带来的时间开销,从而提高了传输速度。     

钢筋阻锈剂在工业厂房中的应用

介绍了钢筋阻锈剂的基本性能、使用范围和方法。