助模板剂对MCM—41分子筛孔结构和性能的影响

在硅酸钠－硫酸铝－十六烷基三甲基氯化铵－水体系中，加入不同类型，如正庚烷、三甲基苯和十二胺的有机助模板剂（简称助剂）进行ＭＣＭ－４１分子筛的合成试验，并用ＸＲＤ、ＩＲ及Ｎ２吸附等方法考察了助剂对ＭＣＭ－４１分子筛孔径、热稳定性及酸性的影响。结果表明，十二胺助剂对ＭＣＭ－４１分子筛的孔径影响最大，但热稳定性较差，相比之下，三甲基苯助剂合成的ＭＣＭ－４１分子筛具有孔径大、热稳定性好和酸性特征较好的特点。     

感应电动机转速对定子电流暂态过程的影响

本文运用根轨迹法，分析了感应电动机转速对定子电流暂态过程的影响。并通过对稳态时定子电流在电压阶跃干扰下的暂太响应分析，验证了结论有效性。     

Ab initio calculations on the mechanism of isobutane and 2-butene alkylation reaction catalyzed by hydrofluoric acid

Ab initio method was employed to determine the mechanism of alkylation reaction of 2-butene with isobutane. The results indicated that 2-butene is rapidly protonated to form sec-butyl carbonium ion, which then reacts with isobutane to form tert-butyl carbonium ion. The resulting carbonium ion is then deprotonated to form isobutene that reacts rapidly with tert-butyl carbonium ion to form trimethylpentane (TMP) carbonium ion. Finally, the TMP⁺ carbonium ion is converted to TMP via the hydride transfer process. The transition states of the interactions were obtained by using the SCAN method (a calculation key word for potential energy surface) first and then the intrinsic reaction coordinates were traced using the Gaussian program. In addition, the energy changes and geometric parameters of the interactions were analyzed. The computed results indicated that the energy barriers are close to or less than zero for the interaction of isobutane with protonated 2-butene or for the interaction of tert-butyl carbonium ion with isobutene, suggesting rapid reaction steps of the carbonium ions. The 2,2,3-TMP is kinetically controlled, while the formation of 2,2,4-TMP is controlled by reaction equilibrium. The calculated results were in good agreement with the experimental results.     

大庆油田深层岩石力学特性参数的试验研究

通过对岩石可钻性、硬度、抗压强度等参数的测量 ,对大庆油田深井不同深度、不同层位、不同岩性的具有广泛代表性的岩心进行试验。并通过线性回归分析 ,建立了适用性较广的钻井岩石力学特性参数预测模型 ,为深井钻头选型提供了依据。     

岩金矿山空区处理研究

文章阐述了岩金矿山空区处理研究的手段及空区处理的方法，探讨了空区破坏的地质，力学机理。     

Synthesis of Iron-Based Laves Phase Containing Praseodymium Magnetostrictive Materials

The synthesis and magnetostriction of PrxTb1-x.Fe2, PrxTb1-x Fe2BO2 and PrxTb1-x（Fe0.6Co0.4）2 alloys were investigated in this study. The addition of boron or cobalt atom in PrxTb1-xFe2 could effectively prevent the formation of non-cubic phases, and Pr concentration limit was successfully increased from 0.2 to 0.4. X-ray step scanning for the PrxTb1-xFe2BO2 and PrxTb1-x（Fe0.6Co0.4）2 alloys showed that PrFe2 possessed a large spontaneous magnetostriction λ1111.     

基于绿色化学理念的工科(化工类)化学课程体系及内容的改革与实践

我国化工类化学课程体系、教学内容几乎几十年不变,在科学技术突飞猛进的今天,已经远远不能适应培养21世纪人才的要求.本课题以引入绿色化学的理念为基点,对化工类化学课程体系及内容进行了改革与实践,构建了新的化学课程体系、对原四大化学内容进行了整合和拓展、加强了实践环节的培养.实践证明成效显著.     

有机锡类农药——三唑锡液相色谱分析

用高效液相色谱分析农药三唑锡,采用强阳离子交换柱,甲醇、水、冰醋酸作流动相以及紫外检测器。结果表明,此法分离效果好,准确度和精密度高,可用于三唑锡生产控制及原药、各种制剂(粉剂、胶悬剂)产品分析。     

Study of the Mössbauer effect on rare-earth borided surface layers on pure iron

Journal of Materials Science Letters -     

百色盆地林蓬浅层稠油油藏热采开发的可行性研究

百色盆地林蓬油藏为一浅、薄、低产、低渗的普通稠油构造油藏。通过对油藏特征、原油热物性、热采数值模拟初步分析及热米开发经济效益的初步评价，认为林蓬油藏利用我国现有的热采技术投入开发具有可行性，并提出了具体实施方案和工作意见．