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排序方式: 共有433条查询结果,搜索用时 15 毫秒
41.
The commercial development and current economic incentives associated with energy storage using redox flow batteries (RFBs) are summarised. The analysis is focused on the all‐vanadium system, which is the most studied and widely commercialised RFB. The recent expiry of key patents relating to the electrochemistry of this battery has contributed to significant levels of commercialisation in, for example, Austria, China and Thailand, as well as pilot‐scale developments in many countries. The potential benefits of increasing battery‐based energy storage for electricity grid load levelling and MW‐scale wind/solar photovoltaic‐based power generation are now being realised at an increasing level. Commercial systems are being applied to distributed systems utilising kW‐scale renewable energy flows. Factors limiting the uptake of all‐vanadium (and other) redox flow batteries include a comparatively high overall internal costs of $217 kW?1 h?1 and the high cost of stored electricity of ≈ The commercial development and current economic incentives associated with energy storage using redox flow batteries (RFBs) are summarised. The analysis is focused on the all‐vanadium system, which is the most studied and widely commercialised RFB. The recent expiry of key patents relating to the electrochemistry of this battery has contributed to significant levels of commercialisation in, for example, Austria, China and Thailand, as well as pilot‐scale developments in many countries. The potential benefits of increasing battery‐based energy storage for electricity grid load levelling and MW‐scale wind/solar photovoltaic‐based power generation are now being realised at an increasing level. Commercial systems are being applied to distributed systems utilising kW‐scale renewable energy flows. Factors limiting the uptake of all‐vanadium (and other) redox flow batteries include a comparatively high overall internal costs of $217 kW?1 h?1 and the high cost of stored electricity of ≈ $0.10 kW?1 h?1. There is also a low‐level utility scale acceptance of energy storage solutions and a general lack of battery‐specific policy‐led incentives, even though the environmental impact of RFBs coupled to renewable energy sources is favourable, especially in comparison to natural gas‐ and diesel‐fuelled spinning reserves. Together with the technological and policy aspects associated with flow batteries, recent attempts to model redox flow batteries are considered. The issues that have been addressed using modelling together with the current and future requirements of modelling are outlined. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
42.
Shouqi Shao Gareth R.M. Tainton W. J. Kuang Nick Clark Roman Gorbachev Alexander Eggeman Irina V. Grigorieva Daniel J. Kelly Sarah J. Haigh 《Advanced functional materials》2023,33(30):2214390
Intercalation and deintercalation processes in van der Waals crystals underpin their use in nanoelectronics, energy storage, and catalysis but there remains significant uncertainty regarding these materials’ structural and chemical heterogeneity at the nanoscale. Deintercalation in particular often controls the robustness and cyclability of the involved processes. Here, a detailed analysis of potassium ordering and compositional variations in as-synthesised K intercalated MoS2 as well an analysis of deintercalation induced changes in the structure and K/Mo elemental composition is presented. By combining 4D scanning transmission electron microscopy (4DSTEM), in situ atomic resolution STEM imaging, selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDS) the formation of previously unknown intermediate superstructures during deintercalation is revealed. The results provide evidence supporting a new deintercalation mechanism that favors formation of local regions with thermodynamically stable ordering rather than isotropic release of K. Systematic time-temperature measurements demonstrate the deintercalation behavior to follow first-order kinetics, allowing compositional and superstructural changes to be predicted. It is expected that the in situ correlative STEM-EDS/SAED methodology developed in this work has the potential to determine optimal synthesis, processing and working conditions for a variety of intercalated or pillared materials. 相似文献
43.
An improved pulse sequence for the 3D DOSY experiment 2DJ-DOSY, using diffusion encoding internal to the parent 2DJ spectroscopy sequence (2DJ-IDOSY), is presented. The diffusion-encoding pulses are used to enforce the desired coherence transfer pathway, reducing the minimum experimental time by at least a factor of 4, as compared to existing techniques, and approximately doubling the signal-to-noise ratio for small molecules. The new sequence is demonstrated on a simple mixture and on a complex sample with a high dynamic range (port wine). The principle of internal diffusion encoding can be applied with profit to a range of other 3D DOSY experiments. 相似文献
44.
Gareth Edwards 《电子设计应用》2009,(8):70-72,75
本文利 Spartan-3A入门套件,在开发MicroBlaze子系统的基础上,创建了一个能够弹奏管风琴的机器人.实际验证表明,电磁发热和音效都能达到令人满意的效果. 相似文献
45.
Ruibin Liu L.E. Cross Gareth Knowles Bruce Bower Brooks Childers 《Journal of Electroceramics》2000,4(1):201-206
A flextensional actuator was designed using commercial multilayer stacked actuator so as to produce large displacements at intermediate force levels. The simple design chosen eliminated the need for bonding the actuators into the frame and permitted easy series connection of multiple units. To satisfy the need for a fiber grating tuning device to interrogate an array of Bragg grating fiber optic stress sensors, a tuning device using four series connected units was constructed. The unit performs well, but the actual measured amplification is less than theoretical expectation. The problem was traced to unwanted flexing of the simple original frame and a hinged more robust flexing beam construction was shown to eliminate the problem. 相似文献
46.
Shan Liu Michael K. Danquah Jenny Ho Charles Ma Lina Wang Ross Coppel Gareth M. Forde 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(5):782-788
BACKGROUND: A novel ultrasonic atomization approach for the formulation of biodegradable poly(lactic‐co‐glycolic acid) (PLGA) microparticles of a malaria DNA vaccine is presented. A 40 kHz ultrasonic atomization device was used to create the microparticles from a feedstock containing 5 volumes of 0.5% w/v PLGA in acetone and 1 volume of condensed DNA which was fed at a flow rate of 18 ml h?1. The plasmid DNA vectors encoding a malaria protein were condensed with a cationic polymer before atomization. RESULTS: High levels of gene expression in vitro were observed in COS‐7 cells transfected with condensed DNA at a nitrogen to phosphate (N/P) ratio of 10. At this N/P ratio, the condensed DNA exhibited a monodispersed nanoparticle size (Z‐average diameter of 60.8 nm) and a highly positive zeta potential of 38.8 mV. The microparticle formulations of malaria DNA vaccine were quality assessed and it was shown that the microparticles displayed high encapsulation efficiencies between 82–96% and a narrow size distribution in the range of 0.8–1.9 µm. In vitro release profile revealed that approximately 82% of the DNA was released within 30 days via a predominantly diffusion controlled mass transfer system. CONCLUSIONS: This ultrasonic atomization technique showed excellent particle size reproducibility and displayed potential as an industrially viable approach for the formulation of controlled release particles. Copyright © 2009 Society of Chemical Industry 相似文献
47.
Michael K. Cinibulk Gareth Thomas Sylvia M. Johnson 《Journal of the American Ceramic Society》1992,75(8):2044-2049
The oxidation behavior and microstructure of the oxidized surfaces of RE2 Si2 O7 –Si3 N4 ceramics were investigated. The high oxidation resistance of these materials at 1400°C is attributed to the minimization of amorphous phases via devitrification to disilicates that are in equilibrium with SiO2 , the oxidation product of Si3 N4 . Crystals of RE2 Si2 O7 grew out of the surface silicate in prefered orientations that were dictated by crystal structure. The morphology of the microstructure of the oxidized surfaces was shown to be partially dependent on the concentration of impurities; the presence of Ca was found to coincide with the growth of Gd2 Si2 O7 and Dy2 Si2 O7 crystals with high aspect ratios. 相似文献
48.
Macarena Garay Salazar Angel González Ureña Gareth Roberts 《Israel journal of chemistry》1997,37(4):353-358
The total cross section σB(E) for the Ca(1D) + HBr → CaBr(B2Σ+) + H reaction as a function of collision energy has been measured using crossed atomic and molecular beams. The maxima exhibited by σB(E) with increasing energy are attributed to the opening of successive bending vibrational reaction channels that proceed via a [Ca(1D) ⃛ Br ⃛ H]‡ transition state. A dynamical model for the reaction may be constructed in terms of Landau-Zener probabilities for curve crossing at two locations on the reaction path, coupled with a preference for consumption of transition-state vibrational energy. 相似文献
49.
Zhixian Cao Jian Meng Gareth Pender Steve Wallis 《Canadian Metallurgical Quarterly》2006,132(12):1272-1282
New formulations are presented for flow resistance and momentum flux in compound open channels. As implemented in the St. Venant equations, these formulations facilitate a physically enhanced approach to evaluating conveyance, roughness, stage-discharge relationship, and unsteady flood routing in compound open channels. An analysis using steady flow data from the well-controlled experiments at the large-scale Flood Channel Facility, HR Wallingford, demonstrates the ability of the present approach to properly resolve the discontinuity of overall roughness across the main-channel bankfull level. Also, the proposed formulations are shown to be conducive to obviating the long-standing computational difficulty in unsteady flood routing due to small flow depths over flat and wide floodplains. The present work should find general applications in one-dimensional computation of river flows. 相似文献
50.
Razif Harun Michael DavidsonMark Doyle Rajprathab GopirajMichael Danquah Gareth Forde 《Biomass & bioenergy》2011,35(1):741-747
As fossil fuel prices increase and environmental concerns gain prominence, the development of alternative fuels from biomass has become more important. Biodiesel produced from microalgae is becoming an attractive alternative to share the role of petroleum. Currently it appears that the production of microalgal biodiesel is not economically viable in current environment because it costs more than conventional fuels. Therefore, a new concept is introduced in this article as an option to reduce the total production cost of microalgal biodiesel. The integration of biodiesel production system with methane production via anaerobic digestion is proved in improving the economics and sustainability of overall biodiesel stages. Anaerobic digestion of microalgae produces methane and further be converted to generate electricity. The generated electricity can surrogate the consumption of energy that require in microalgal cultivation, dewatering, extraction and transesterification process. From theoretical calculations, the electricity generated from methane is able to power all of the biodiesel production stages and will substantially reduce the cost of biodiesel production (33% reduction). The carbon emissions of biodiesel production systems are also reduced by approximately 75% when utilizing biogas electricity compared to when the electricity is otherwise purchased from the Victorian grid. The overall findings from this study indicate that the approach of digesting microalgal waste to produce biogas will make the production of biodiesel from algae more viable by reducing the overall cost of production per unit of biodiesel and hence enable biodiesel to be more competitive with existing fuels. 相似文献