Dynamic Strain Aging of Nickel-Base Alloys 800H and 690

The objective of the current investigation is to characterize the dynamic strain aging (DSA) behavior in alloys 800H and 690. Constant extension rate tests were conducted at strain rates in the range of 10^?4 s^?1 to 10^?7?s^?1and temperatures between 295?K and 673?K (22?°C and 400?°C), in an argon atmosphere. Maps for the occurrence of serrated flow as a function of strain rate and temperature were built for both alloys. The enthalpy of serrated flow appearance of alloy 800H was found to be 1.07?±?0.30?eV.     

Real-time tool control and job dispatching in flexible manufacturing systems

A method of loading a set of tools to the different machining centres of a shop is presented, where each part visits only one of the machining centres for its entire processing. Any tools which are required but unavailable for the processing of a part are borrowed from other machining centres. As a real-time control, the tool-returning policies for those borrowed tools and the job-dispatching rules at the machining centres are evaluated to maximize the throughput performance of the shop. Some experimental results are provided.     

Structural analysis and optimization of tall buildings connected with skybridges and atria

Multi-level skybridges and atria between tall buildings make possible a new urban paradigm that has the potential to dramatically reduce resource consumption, air pollution, and traffic accidents. Structural analysis and optimization methods and results are presented for tall buildings connected with roller or hinge-skybridges at multiple levels and atria between buildings. Generic building systems were studied with controlled factors such as number of buildings, equal-height vs. variable-height, skybridge connection type, site seismicity and wind intensity, and presence/absence of skybridges and atria. The 48 optimization problems held all other factors constant such as building width, shape, configuration, and spacing. A simplified lateral load analysis model is described which makes optimization of large systems possible. The simplified lateral load analysis model was compared to a finite element model for accuracy. An optimization strategy was developed involving gradient and evolutionary algorithms. Results show that atria and hinge-connected skybridges reduced the total structural volume by as much as 10 %.     

Co-optimization of color and mechanical properties by volumetric voxel control

Structural and Multidisciplinary Optimization - Controlling the composition of individual voxels allows for a co-optimization of 3D-printed part properties such as color and mechanical ones. As a...     

Variation in carotenoid–protein interaction in bird feathers produces novel plumage coloration

Light absorption by carotenoids is known to vary substantially with the shape or conformation of the pigment molecule induced by the molecular environment, but the role of interactions between carotenoid pigments and the proteins to which they are bound, and the resulting impact on organismal coloration, remain unclear. Here, we present a spectroscopic investigation of feathers from the brilliant red scarlet ibis (Eudocimus ruber, Threskiornithidae), the orange-red summer tanager (Piranga rubra, Cardinalidae) and the violet-purple feathers of the white-browed purpletuft (Iodopleura isabellae, Tityridae). Despite their striking differences in colour, all three of these feathers contain canthaxanthin (β,β-carotene-4,4′-dione) as their primary pigment. Reflectance and resonance Raman (rR) spectroscopy were used to investigate the induced molecular structural changes and carotenoid–protein interactions responsible for the different coloration in these plumage samples. The results demonstrate a significant variation between species in the peak frequency of the strong ethylenic vibration (ν₁) peak in the rR spectra, the most significant of which is found in I. isabellae feathers and is correlated with a red-shift in canthaxanthin absorption that results in violet reflectance. Neither polarizability of the protein environment nor planarization of the molecule upon binding can entirely account for the full extent of the colour shift. Therefore, we suggest that head-to-tail molecular alignment (i.e. J-aggregation) of the protein-bound carotenoid molecules is an additional factor.     

MOCVD Growth of Erbium Monoantimonide Thin Film and Nanocomposites for Thermoelectrics

We report the growth of erbium monoantimonide (ErSb) thin films on indium antimonide (100) substrates by low-pressure metalorganic chemical vapor deposition. The growth rate of ErSb thin films shows strong dependency on the growth temperature and the Sb/Er precursor molar flow rate ratio. Scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffractometry (XRD) were employed to study the ErSb thin films grown under the growth conditions that gave the maximum growth rate in the range we investigated. We also report the growth of two types of nanocomposites in which ErSb nanocolumns or nanoslabs with lengths ~500 nm and diameters 20 nm to 30 nm are embedded in Zn-doped InGaSb (ErSb/InGaSb:Zn) and ErSb nanoparticles with diameters of ~30 nm are embedded in Zn-doped InSbAs (ErSb/InSbAs:Zn). These nanocomposites were intended to increase phonon scattering in a mid-to-long phonon wavelength range to reduce lattice thermal conductivity. We used time-domain thermoreflectance to measure total thermal conductivity for the two types of nanocomposites, obtaining 4.0 ± 0.6 W/mK and 6.7 ± 0.8 W/mK for the ErSb/InAsSb:Zn and ErSb/InGaSb:Zn nanocomposites, respectively, which suggests that the thermal conductivity was close to or slightly smaller than the alloy limit of the two ternary alloy hosts. The two nanocomposites were further studied by transmission electron microscopy (TEM) to reveal their microscopic features and by XRD to assess their crystalline structures.     

Linear quadratic performance with worst case disturbance rejection

The method of the calculus of variations and the maximum principle are preposed for the design of 'LQR' controllers with the worst case disturbance rejection for a linear time-varying (LTV) plant on finite horizon. The disturbance is bounded by either the windowed L     

Formation of corn fiber gum-milk protein conjugates and their molecular characterization

Corn fiber arabinoxylan is hemicellulose B isolated from the fibrous portions (pericarp, tip cap, and endosperm cell wall fractions) of corn kernels and is commonly referred to as corn fiber gum (CFG). Our previous studies showed that CFG isolated from corn bran (a byproduct of corn dry milling) contains very little protein and is an inferior emulsifier for oil-in-water emulsion systems as compared to corn fiber gum isolated from corn fiber derived from the corn wet-milling process. The protein deficient CFG isolated from corn bran was covalently conjugated with byproducts of cheese processing, β-lactoglobulin (β-LG) and whey protein isolate (WPI) using an economical food-grade Maillard-type heating reaction for the purpose of increasing their commercialization potential as a food emulsifier and soluble nutritional additive in beverages. The formation of the CFG-protein conjugates has been confirmed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). It has also been demonstrated that CFG-protein conjugates are capable of producing fine emulsions with better stability than either CFG or protein alone. The molecular characterization of CFG-protein conjugates was performed by high-performance size-exclusion chromatography (HPSEC) coupled to on-line multi-angle laser light scattering and viscometric detection. The analysis by HPSEC revealed that CFG-protein conjugates had higher weight-average molar mass (M_w, 340-359 kDa) and polydispersity (M_w/M_n, 1.74) than the corresponding unconjugated CFG (M_w, 290 kDa and M_w/M_n, 1.35). The z-average root-mean-square radius of gyration (R_gz) of CFG-protein conjugates was slightly higher (30.5-33.5 nm) in comparison to CFG (29.5 nm) but their weight-average-intrinsic viscosity (η) remained unchanged (about 1.32 dL g⁻¹). The Mark-Houwink exponent “a” of conjugates (0.40) was lower than the unconjugated CFG (0.53) indicating the formation of a more compact structure after conjugation with protein. These findings should benefit the beverage industry, which can use this information to produce a high quality emulsifier from the low-value byproducts of corn dry milling and cheese processing.