Ringöffnungs- und SubstitutionsReaktionen von 4,4-Dihalogen-pyrazolin-5-onen durch Nucleophile

Ring Opening and Substitution Reactions of 4,4-Dihalo-pyrazolin-5-ones with Nucleophiles 1-Aryl-4,4-dihalo-3-methyl-pyrazolin-5-ones ( 1a – c ) undergo ring opening with alkoxides and form alkyl 3-arylazo-2-halo-2-butenoats ( 2a – d ). Analogous reactions take place with ammonia and amines. 4-Nitro-phenoxide reacts with substitution of both halogens to the 4,4-bis(4-nitro-phenyl)-compound ( 5 ). Phenols are selectively orthobrominated by the title compounds 1a and b .     

Effect of load reduction mechanisms on loads and blade bearing movements of wind turbines

The power control of wind turbines is usually realized via a change in the pitch angle of the rotor blades. Pitching facilitates the exact control of the turbines and the reliable deceleration of the rotor when required. Pitch movements can moreover be used for load control. One of these methods is called individual pitch control (IPC). IPC controls the blades individually and brings about a significant reduction in the fatigue loads and extreme loads placed on the structural components, while at the same time reducing the yield of the turbine only slightly. The lower loads reduce material costs, and thus, the cost of energy (CoE) is reduced, despite the slight reduction in yield. The method is nevertheless not used everywhere since the additional movement cycles put the rotor blade bearings in particular under stress. Special attention must be paid to small amplitude oscillating movements, which carry a high risk of inducing surface damage in the rolling contacts of the blade bearings. This paper uses a cycle analysis of the IWT7.5‐164 reference turbine to illustrate the differences in the movement patterns of wind turbine blade bearings with and without IPC. Moreover, model calculations with single contacts are used to show which of the movement patterns carries a risk of inducing surface damage. The use of IPC leads to the expected load reduction at the blade root. In current literature, IPC is usually assumed to have a negative influence on the life expectancy of blade bearings, but the findings of this study contradict this. The summed blade bearing movement is increased, although the number of very small pitch angles occurring is reduced. This reduction reduces the risk of wear in the blade bearings.     

Correlation of Ⅲ/Ⅴ semiconductor etch results with physical parameters of high-density reactive plasmas excited by electron cyclotron resonance

Reactive ion etching is the interaction of reactive plasmas with surfaces. To obtain a detailed understanding of this process, significant properties of reactive composite low-pressure plasmas driven by electron cyclotron resonance(ECR) were investigated and compared with the radial uniformity of the etch rate. The determination of the electronic properties of chlorine-and hydrogen-containing plasmas enabled the understanding of the pressure-dependent behavior of the plasma density and provided better insights into the electronic parameters of reactive etch gases. From the electrical evaluation of I(V) characteristics obtained using a Langmuir probe,plasmas of different compositions were investigated. The standard method of Druyvesteyn to derive the electron energy distribution functions by the second derivative of the I(V)characteristics was replaced by a mathematical model which has been evolved to be more robust against noise, mainly, because the first derivative of the I(V) characteristics is used. Special attention was given to the power of the energy dependence in the exponent. In particular, for plasmas that are generated by ECR with EM modes, the existence of Maxwellian distribution functions is not to be taken as a self-evident fact, but the bi-Maxwellian distribution was proven for Ar-and Kr-stabilized plasmas. In addition to the electron temperature, the global uniform discharge model has been shown to be useful for calculating the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the noninvasive optical method of emission spectroscopy, particularly actinometry, was investigated,and the resulting data exhibited the same relative behavior as the Langmuir data. The correlation with etchrate data reveals the large chemical part of the removal process—most striking when the data is compared with etching in pure argon. Although the relative amount of the radial variation of plasma density and etch rate is approximately ?5%, the etch rate shows a slightly concave shape in contrast to the plasma density.     

Correlation of III/V semiconductor etch results with physical parameters of high-density reactive plasmas excited by electron cyclotron resonance

Reactive ion etching is the interaction of reactive plasmas with surfaces. To obtain a detailed understanding of this process, significant properties of reactive composite low-pressure plasmas driven by electron cyclotron resonance (ECR) were investigated and compared with the radial uniformity of the etch rate. The determination of the electronic properties of chlorine-and hydrogen-containing plasmas enabled the understanding of the pressure-dependent behavior of the plasma density and provided better insights into the electronic parameters of reactive etch gases. From the electrical evaluation of I(V ) characteristics obtained using a Langmuir probe, plasmas of different compositions were investigated. The standard method of Druyvesteyn to derive the electron energy distribution functions by the second derivative of the I(V ) characteristics was replaced by a mathematical model which has been evolved to be more robust against noise, mainly, because the first derivative of the I(V ) characteristics is used. Special attention was given to the power of the energy dependence in the exponent. In particular, for plasmas that are generated by ECR with EM modes, the existence of Maxwellian distribution functions is not to be taken as a self-evident fact, but the bi-Maxwellian distribution was proven for Ar-and Kr-stabilized plasmas. In addition to the electron temperature, the global uniform discharge model has been shown to be useful for calculating the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the non-invasive optical method of emission spectroscopy, particularly actinometry, was investigated, and the resulting data exhibited the same relative behavior as the Langmuir data. The correlation with etchrate data reveals the large chemical part of the removal process—most striking when the data is compared with etching in pure argon. Although the relative amount of the radial variation of plasma density and etch rate is approximately ±5%, the etch rate shows a slightly concave shape in contrast to the plasma density.     

Evaluation of the Impact of Ruminant Trans Fatty Acids on Human Health: Important Aspects to Consider

The definition and evaluation of trans fatty acids (TFA) with regard to foodstuffs and health hazard are not consistent. Based on the current situation, the term should be restricted only to TFA with isolated double bonds in trans-configuration. Conjugated linoleic acids (CLA) should be separately assessed. Ideally, the origin of the consumed fat should be declared, i.e., ruminant TFA (R-TFA) and industrial TFA (non-ruminant; I-TFA). In ruminant fat, more than 50% of R-TFA consists of vaccenic acid (C18:1 t11). In addition, natural CLA, i.e., c9,t11 CLA is also present. Both are elevated in products from organic farming. In contrast to elaidic acid (t9) and t10, which occur mainly in partially hydrogenated industrial fat, t11 is partially metabolized into c9,t11 CLA via Δ9-desaturation. This is the major metabolic criterion used to differentiate between t11 and other trans C18:1. t11 indicates health beneficial effects in several studies. Moreover, CLA in milk fat is associated with the prevention of allergy and asthma. An analysis of the few studies relating to R-TFA alone makes clear that no convincing adverse physiological effect can be attributed to R-TFA. Only extremely high R-TFA intakes cause negative change in blood lipids. In conclusion, in most European countries, the intake of R-TFA is assessed as being low to moderate. Restriction of R-TFA would unjustifiably represent a disadvantage for organic farming of milk.     

Reactivity characteristics of nanoscale zerovalent iron--silica composites for trichloroethylene remediation

Spherical silica particles containing nanoscale zerovalent iron were synthesized through an aerosol-assisted process. These particles are effective for groundwater remediation, with the environmentally benign silica particles serving as effective carriers for nanoiron transport. Incorporation of iron into porous sub-micrometer silica particles protects ferromagnetic iron nanoparticles from aggregation and may increase their subsurface mobility. Additionally, the presence of surface silanol groups on silica particles allows control of surface properties via silanol modification using organic functional groups. Aerosolized silica particles with functional alkyl moieties, such as ethyl groups on the surface, clearly adsorb solubilized trichloroethylene (TCE) in water. These materials may therefore act as adsorbents which have coupled reactivity characteristics. The nanoscale iron/silica composite particles with controlled surface properties have the potential to be efficiently applied for in situ source depletion and in the design of permeable reactive barriers.     

Effect of Ionic Substitution on the Thermal Expansion of ZrTiO4

New oxide compounds with α-PbO₂ structure have been synthesized by solid-state reactions. These are derived from ZrTiO₄ and HfTiO₄ by a different kind of ionic substitution. The thermal expansion behavior of these phases was investigated by means of a dilatometer and an X-ray heating diffractometer. These measurements revealed rather low expansion for some of the Zr(Me³⁺/Me⁵⁺)O₄, solid solutions. This behavior is attributed to their high expansion anisotropy, which leads to extended formation of microcracks.     

Olefinreaktionen in Gegenwart wolfram- und molybdänhaltiger Katalysatorsysteme vom Ziegler-Natta-Typ

Reactions of Alkenes in the Presence of Tungsten- and Molybdenum-containing Ziegler-Natta-Catalysts In connection with investigations of reactions of alkenes under the conditions of metathesis we studied the reactions of a mixture of 2-pentene/toluene in presence of the catalytic systems WCl₆/EtAlCl₂ and MoCl₅/EtAlCl₂ in homogeneous liquid phase. Alkylation of toluene, metathesis of 2-pentene and also indirect isomerisation of double bonds have been determined in dependence of the molar proportions of 2-pentene/MeCl_x, toluene/2-pentene, and MeCl_x/EtAlCl₂, the addition order (“formation”) of reactants, the “building time” of catalytic system and the reaction time. Compositions of the reaction mixtures have been determined by GLC.