Mussel Inspired Dynamic Cross‐Linking of Self‐Healing Peptide Nanofiber Network

A general drawback of supramolecular peptide networks is their weak mechanical properties. In order to overcome a similar challenge, mussels have adapted to a pH‐dependent iron complexation strategy for adhesion and curing. This strategy also provides successful stiffening and self‐healing properties. The present study is inspired by the mussel curing strategy to establish iron cross‐link points in self‐assembled peptide networks. The impact of peptide‐iron complexation on the morphology and secondary structure of the supramolecular nanofibers is characterized by scanning electron microscopy, circular dichroism and Fourier transform infrared spectroscopy. Mechanical properties of the cross‐linked network are probed by small angle oscillatory rheology and nanoindentation by atomic force microscopy. It is shown that iron complexation has no influence on self‐assembly and β‐sheet‐driven elongation of the nanofibers. On the other hand, the organic‐inorganic hybrid network of iron cross‐linked nanofibers demonstrates strong mechanical properties comparable to that of covalently cross‐linked network. Strikingly, iron cross‐linking does not inhibit intrinsic reversibility of supramolecular peptide polymers into disassembled building blocks and the self‐healing ability upon high shear load. The strategy described here could be extended to improve mechanical properties of a wide range of supramolecular polymer networks.     

A Study on Tunable Viscoelastic Properties of Xhantan Gum and Sodium Alginate Hyrogelling System

Theoretical Foundations of Chemical Engineering - In this study, viscoelastic properties of xhantan gum (XG) and sodium alginate (SA) hydrogelling system were investigated at a definite range of...     

Influence of orbital shaking on microstructure and mechanical properties of A380 aluminium alloy produced by lost foam casting

Using vibration for refining microstructure and improve mechanical properties of aluminium alloys castings are in the interest of researchers for many years. Within the framework of these studies mechanical, ultrasonic and electromagnetic vibration applications were carried out. Results of these processes can be summarized as grain refining and changing the dendritic structure into globular. Accordingly increasing in density and mechanical properties were reported. In this work, orbital shaking technique was used alternatively to conventional mechanical vibration in lost foam casting (LFC) of A380 aluminium alloy. In the experiment castings, effects of shaking movement and speed during pouring were investigated. First of all orbital shaking movement has not damage LFC parts and any shape disorder was not occurred. Optical microstructure observations show that, the increase in shaking speed, decrease secondary dendrite arm spacing (SDAS) and partial dendrite arm fractures were determined at 150 rpm shaking. Density and hardness of as cast specimens were increased with shaking and rising shaking speed as well.     

Pressureless Spark Plasma Sintering: A Perspective from Conventional Sintering to Accelerated Sintering Without Pressure

Powder Metallurgy and Metal Ceramics - Spark plasma sintering (SPS) has been an attractive technique for many researchers seeking to consolidate metals and ceramics. This technique’s high...     

Suitability modeling and sensitivity analysis for biomass energy facilities in Turkey

Clean Technologies and Environmental Policy - Nowadays, problems relating to the inadequacy of energy resources are emerging, due to fast population growth and inevitable urban sprawl. Renewable...     

On the shear failure mode of granular column embedded unit cells subjected to static and cyclic shear loads

Since the initial conception of geosynthetic encased columns (GECs), exhaustion of column capacity due to vertical loads in bulging and punching failure modes were readily recognized. This lead to a vast majority of the available research on GECs to be about the behavior of columns under the action of vertical loads. Recently, two other likely and perhaps more dominant failure modes for granular columns namely, shear and bending failure modes, were identified. The purpose of this paper is to study the behavior of unit cells containing ordinary stone columns (OSCs) and GECs under static and cyclic lateral loads where shear failure of the column is imminent. 1-g physical tests are conducted with a novel apparatus, designated as Unit Cell Shear Device (UCSD), to model the behavior of the unit cells located close to the toe of an embankment where OSCs and GECs experience significant lateral loading. Overall failure envelope and strength parameters for GECs with varying reinforcement stiffnesses are quantified under static and cyclic lateral loading conditions. The distribution and magnitude of reinforcement strains in horizontal (hoop) and vertical direction of the columns are also considered.     

Structural and ESR studies of Cu-doped ZnO nanostructures

Surface morphology, structural phases, and electron spin resonance (ESR) measurements were performed for Zn_1-xCu_xO nanoparticles (x = 0.00, 0.01, 0.02, 0.03, 0.04, and 0.05) synthesized by sol-gel method. The optimum annealing temperature (600°C) and weight loss was clarified using differential thermal analysis (DTA), and thermo gravimetric analysis (TG). By means of X-ray diffraction (XRD) technique, the phase of the samples was defined as single with ZnO wurtzite hexagonal structure and proofed by Rietveld analysis for Zn_0.98Cu_0.02O sample with calculating c/a rate. Spherical shape random particle distributions were observed in all scanning electron microscope (SEM) measurements. ESR measurements were conducted for all samples and g-value and ΔH (G) values were calculated and correlated from ESR measurements.     

Nutritional quality of protein in the leaves of eleven Asphodeline species (Liliaceae) from Turkey

The nutritional quality of the protein in the leaves of 11 Asphodeline (Liliaceae) species was investigated by the determination of the amino acid composition and calculation of several nutritional parameters. The average protein content was 4.7% and ranged from 2.5% in Asphodeline damascena ssp. rugosa to 8.2% in A. turcica. The most abundant essential amino acids were Thr (5.7%), Val (6.0%), Ile (4.7%), and Trp (2.1%). The amino acid composition of Asphodeline peshmeniana was well equilibrated according to Food and Agriculture Organisation standards, but Lys and sulphur amino acids were at limiting concentrations in all the other taxa. Determination of the protein efficiency ratio and biological value revealed that the protein in the leaves of Asphodeline species is of high nutritional quality. Hence, the Asphodeline leaves that are typically used in Turkey for the preparation of salads, represent a good source of protein with high levels of several essential amino acids and a good nutritional value. Analysis of the similarity based on the amino acid composition indicated the existence of different clusters that are consistent with the taxonomical classification, area of distribution, and morphological similarities of the Asphodeline species.