Ultra-high performance concrete and fiber reinforced concrete: achieving strength and ductility without heat curing

Ultra-high performance concrete (UHPC) and ultra-high performance fiber reinforced concrete (UHP-FRC) were introduced in the mid 1990s. Special treatment, such as heat curing, pressure and/or extensive vibration, is often required in order to achieve compressive strengths in excess of 150 MPa (22 ksi). This study focuses on the development of UHP-FRCs without any special treatment and utilizing materials that are commercially available on the US market. Enhanced performance was accomplished by optimizing the packing density of the cementitious matrix, using very high strength steel fibers, tailoring the geometry of the fibers and optimizing the matrix-fiber interface properties. It is shown that addition of 1.5% deformed fibers by volume results in a direct tensile strength of 13 MPa, which is 60% higher than comparable UHP-FRC with smooth steel fibers, and a tensile strain at peak stress of 0.6%, which is about three times that for UHP-FRC with smooth fibers. Compressive strength up to 292 MPa (42 ksi), tensile strength up to 37 MPa (5.4 ksi) and strain at peak stress up to 1.1% were also attained 28 days after casting by using up to 8% volume fraction of high strength steel fibers and infiltrating them with the UHPC matrix.     

Brazil’s new national policy on solid waste: challenges and opportunities

Brazil, one of the world’s largest developing countries, has recently introduced a new solid waste management regulatory policy. This new regulatory policy will have implications for a wide variety of stakeholders and sets the stage for opportunities and lessons to be learned. These issues are discussed in this article.     

Quality assessment of commercial paprikas

Several quality parameters of smoked, oven‐dried and sun‐dried paprikas were studied. Smoked paprikas showed the highest American Spice Trade Association (ASTA) units and pigment concentrations, whereas oven‐dried paprikas showed the best browning index and red/yellow pigment ratio, and sun‐dried paprikas had the highest redness for reflected colour. The colour stability results showed drastic overall colour change (ΔE) and decreased redness and ASTA units of the sun‐dried and oven‐dried paprikas after two and 5 days of UV exposure. Degradation of the smoked paprika colour parameters was progressive, and they showed less degradation even after 30 days. The evaluation of the antioxidant activity showed higher DPPH radical‐scavenging capacity in the smoked samples. The profiles of volatile phenolic compounds of the smoked samples are responsible for the differences in the antioxidant capacity. The great differences in colour stability and antioxidant activity make smoked paprika the best choice for use in the food industry.     

In vitro digestibility of phenolic compounds from edible fruits: could it be explained by chemometrics?

The health benefits of phenolic compounds depend on the ingested amount, molecular diversity and gastrointestinal digestibility. The phenolic profile of eight fruits (blackberry, blueberry, strawberry, raspberry, mulberry, pomegranate, green and red globe grapes) was chemometrically associated with their in vitro digestibility (oral, gastric, intestinal). Extractable phenols, flavonoids and anthocyanins strongly correlated with each other (r ≥ 0.84), proanthocyanidins with anthocyanins (r = 0.62) and hydrolysable phenols with both extractable phenols (r = 0.45) and proanthocyanidins (r = ?0.54). Two principal components explained 93% of the variance [61% (free‐phenols), 32% (bounded‐phenols)], and four clusters were confirmed by hierarchical analysis, based in their phenolic richness (CLT 1‐4: low to high) and molecular diversity. In vitro digestibility of extractable phenols and flavonoids was blackberry (CLT‐4)> raspberry (CLT‐2)> red grape (CLT‐1) related to their phenolic richness (r ≥ 0.96; P < 0.001), but anthocyanins’ digestibility was pH‐dependent. Chemometrics is useful to predict the in vitro digestibility of phenolic compounds in the assayed fruits.     

Influence of Surface Morphology on the Torsion Fracture of NiTi Endodontic Instruments

This study analyzed the influences of manufacturing process (twisting and machining) and surface finishing on the angular distortion, maximum torque, and toughness of two NiTi endodontic instruments (Race—FKG Dentaire and TF—Twisted Files, SybronEndo). Statistical analysis of results showed that TF instruments (twisted) had higher distortion angle (p < 0.05) and lower maximum torque to fracture (p < 0.05) than Race instruments (machined). SEM analysis of fractured instruments showed a surface morphology characteristic of ductile fracture, with plastic deformation in the helical shafts. The results suggest that both instruments are equally suitable for clinical applications. This study is purely scientific as it evaluates only some material properties, and is not intended to endorse a commercial product.     

Real-time scalable hardware architecture for 3D-HEVC bipartition modes

This article presents a real-time scalable hardware architecture for the bipartition modes of 3D high-efficiency video coding (3D-HEVC) standard, which includes the depth modeling modes 1 (DMM-1) and 4 (DMM-4). A simplification of the DMM-1 algorithm was done, removing the refinement step. This simplification causes a small BD-rate increase (0.09 %) with the advantage of better using our hardware resources, reducing the necessary memory required for storing all DMM-1 wedgelet patterns by 30 %. The scalable architecture can be configured to support all the different block sizes supported by the 3D-HEVC and also to reach different throughputs, according to the application requirements. Then, the proposed solution can be efficiently used for several encoding scenarios and many different applications. Synthesis results considering a test case show that the designed architecture is capable of processing HD 1080p videos in real time, but with other configurations, higher resolutions are also possible to be processed.     

Oxygen reduction reaction on a Pt/carbon fuel cell catalyst in the presence of trace quantities of ammonium ions: An RRDE study

The effect of trace quantities of ammonia on oxygen reduction reaction (ORR) on carbon-supported platinum catalysts in perchloric acid solutions is assessed using rotating ring disk electrode (RRDE) technique. The study demonstrates that ammonia has detrimental effects on ORR. The most significant effect takes place in the potential region above 0.7 V vs RHE. The effect is explained by the electrochemical oxidation of ammonia, which blocks Pt active sites and increases the formation of H₂O₂. This leads to losses in the disk currents and increments in the ring currents. The apparent losses in ORR currents may occur in two ways, namely, through the blocking of the active sites for ORR as well as by generating a small anodic current, which is believed to have a lower contribution. In addition, a detrimental effect of sodium cations in the potential range below 0.75 V vs RHE was demonstrated. This effect is most likely due to the co-adsorption of sodium cations and perchlorate anions on the Pt surface.     

Effect of Processing on the Detectability of Pecan Proteins Assessed by Immunological and Proteomic Tools

The present study evaluates the effect of food processing on the antigenicity of pecan proteins as measured by enzyme-linked immunosorbent assay (ELISA). In addition, proteomic tools were used to identify potential pecan markers suitable for confirming the presence of pecan proteins in food and validating new methods developed to detect traces of the commodity. To assess the effects of processing on protein stability and antigenicity, pecan nuts were submitted to heat treatments and extracts were analysed by ELISA, sodium dodecyl sulphate polyacrylamide gel electrophoresis and Western blot. The ELISA method was able to detect pecan traces even after submitting the commodity to rigorous treatments, though these treatments affected the detectability to varying degrees. Proteomic assessment showed that the majority of pecan proteins were matched by homology to walnut proteins, which are more abundantly populated in the protein sequence databases. However, there were a few important exceptions: 7S vicilin, 11S legumin and putative allergen I1, unambiguously identified as pecan in origin. Interestingly, putative allergen I1 offered unique analytical advantages to be used as a pecan marker for validation and confirmation purposes.     

Scenario evaluation for the management of household solid waste in small Brazilian municipalities

As achieving Brazil’s National Policy on Solid Waste-based goals effectively is not simple, there are alternatives such as intermunicipal cooperation by consortium or privatization. Therefore, this study aimed to evaluate the Greenhouse Gas emissions and energy use of six scenarios in two landfills contexts (private and consortium) for small municipalities (less than 100,000 inhabitants as per Brazilian standards) located in São Paulo, Brazil. Through the technique of scenario building and method of Waste Reduction Model was possible to obtain the total energy, the amount of carbon dioxide equivalent (CO₂E) and carbon equivalent (CE) emissions. The best scenario integrates composting and recycling, reducing 72 % for CO₂E and CE emissions, and saving about 410 % in energy. The landfill consortium will only take advantage, if the location is the most ideal as far as possible. Small municipalities that do not dispose their waste in landfills compatible with regulatory standards may seek for intermunicipal cooperation and adopt integrated waste-management programmes to reduce their environmental impacts.     

Determination of alcohols and volatile organic acids in anaerobic bioreactors for H2 production by near infrared spectroscopy

In recent years, near infrared (NIR) spectroscopy has been investigated as a tool for monitoring anaerobic digesters, but several adversities in its application have been reported. This study proposes the application of NIR for the determination of alcohols and volatile organic acids from H₂ production bioreactors and evaluates different approaches to optimize the prediction models. Partial least squad (PLS) models were developed using samples from anaerobic batch reactors fed with crude glycerol for wastewater treatment. The analytes predicted were: methanol, ethanol, 1-butanol, acetic, propanoic, butyric, isocaproic and total volatile organic acids (VFA). The optimization of the predictive capacity of the models was achieved through the orthogonal signal correction (OSC) preprocessing and the selection of variables performed by the genetic algorithm (GA). The application of the proposed models were based on the following figures of merit: accuracy, precision, linearity, limits of detection and quantitation, measurement interval, sensitivity, selectivity, signal-to-noise ratio and bias. Despite the low selectivity (maximum of 0.12%), the models presented high sensitivity [γ^?1 = 0.19 (mg L^?1)^?1], low LOQ (1 mg L^?1) and correlation between reference and predicted values (r) at least 0.93, except for propanoic acid (r_pred = 0.85). The F-test revealed that the selection of variables by GA significantly improved the accuracy and linearity of the prediction models for methanol, acetic acid, isocaproic acid and VFA. NIR spectroscopy has proved to be a powerful tool for monitoring H₂ production bioreactors since provides fast, low cost and multicomponent information.