On-line mass spectrometry system for measurements at single-crystal electrodes in hanging meniscus configuration

We present the construction and some first applications of an On-line electrochemical mass spectrometry system for detecting volatile products formed during electrochemical reactions at a single-crystal electrode in hanging meniscus configuration. The system is based on a small inlet tip made of porous Teflon and a Peek holder, which is brought in close proximity (ca. 10–20 μm) to the electrode surface. The tip is connected to the mass spectrometer by glass and metal tubing. Because of the small amount of gas entering the mass spectrometer, no differential pumping is needed during the measurement. The tip construction and preparation introduced here leads to reproducible voltammetry with very good cleanliness characteristics. The presence of the tip has no significant influence on the blank voltammetry of a Pt(111) in sulfuric acid, and on voltammetric responses for CO adlayer oxidation, methanol oxidation, and hydroxylamine electrochemistry on Pt(111). The formation of gaseous products in these reactions can be followed accurately and is in good agreement with earlier results obtained by other mass spectrometric or spectroscopic techniques. The time response and tailing of the setup is on the order of seconds and mainly determined by the distance between the tip and the electrode.     

Distance measurement sensor with PIN-photodiode and bridge circuit

The presented integrated optical distance measurement sensor works on the time-of-flight principle. The distance information is obtained from the correlation of received light and the transmitted signal. The PIN-bridge circuit concept ensures suppression of background light by equally charging and discharging the capacitor within one period, while integrating the wanted signal. The advantages of the included PIN-photodiode are high bandwidth f/sub 3 dB/>1.35 GHz together with high responsivity R=0.36 A/W at 660 nm. A single distance measurement is performed in 2 ms. With averaging, an accuracy of better than 1% is achieved for distances up to 3.7 m. Effective pixel size is 250/spl times/200 /spl mu/m/sup 2/ having a fill-factor of /spl sim/16%. The sensor was manufactured in a 0.6-/spl mu/m BiCMOS process.     

On the capacity of mobile ad hoc networks with delay constraints

Previous work on ad hoc network capacity has focused primarily on source-destination throughput requirements for different models and transmission scenarios, with an emphasis on delay tolerant applications. In such problems, network capacity enhancement is achieved as a tradeoff with transmission delay. In this paper, the capacity of ad hoc networks supporting delay sensitive traffic is studied. First, a general framework is . proposed for characterizing the interactions between the physical and the network layer in an ad hoc network. Then, CDMA ad hoc networks, in which advanced signal processing techniques such as multiuser detection are relied upon to enhance the user capacity, are analyzed. The network capacity is characterized using a combination of geometric arguments and large scale analysis, for several network scenarios employing matched filters, decorrelators and minimum-mean-square-error receivers. Insight into the network performance for finite systems is also provided by means of simulations. Both analysis and simulations show a significant network capacity gain for ad hoc networks employing multiuser detectors, compared with those using matched filter receivers, as well as very good performance even under tight delay and transmission power requirements.     

Effects of solid retention time on the performance of submerged anoxic/oxic membrane bioreactor.

In this study, four similar bench-scale submerged Anoxic/Oxic Membrane Bioreactors (MBR) were used simultaneously to investigate the effects of solids retention time (SRT) on organic and nitrogen removal in MBR for treating domestic wastewater. COD removal efficiencies in all reactors were consistently above 94% under steady state conditions. Complete conversion of NH(4+)-N to NO(3-)-N was readily achieved over a feed NH(4+)-N concentration range of 30 to 50 mg/L. It was also observed that SRT did not significantly affect the nitrification in the MBR systems investigated. The average denitrification efficiencies for the 3, 5, 10 and 20 days SRT operations were 43.9, 32.6, 47.5 and 66.5%, respectively. In general, the average effluent nitrogen concentrations, which were mainly nitrate, were about 22.2, 27.6, 21.7 and 13.9 mg/L for the 3, 5, 10 and 20 days SRT systems, respectively. The rate of membrane fouling at 3 days SRT operation was more rapid than that observed at 5 days SRT. No fouling was noted in the 10 days and 20 days SRT systems during the entire period of study.     

Grid Computing: A Critical Discussion on Business Applicability

In the last decade, the Grid emerged from computing-intensive application domains. It has become very difficult to distinguish between "real" Grids, Web services, and simply a distributed computing environment. A critical discussion of Grid technologies points out the pros and cons of applying current Grid technologies in a business or enterprise environment.     

Testing multi-characteristic product capability indices

Recently, studies associated with testing the quality and performance of each process for a product with multi-characteristics are proposed more often. However, most studies are limited to discussing one single type of quality characteristic. Practically, a multi-characteristic product is potentially composed of three types: smaller-the-better, larger-the-better, and nominal-the-best. In this paper, we propose an integrated product capability index which considers these three different types of quality characteristics. According to the theory of testing hypothesis, we develop a testing procedure for the product capability index to judge whether the process capabilities of total quality characteristics meet the customers’ demands. In addition, the relationship between the product capability index and the yield of the entire product will be introduced. Finally, an example is provided as a practical application.     

Complete mobile email management

Years have lapsed since the inauguration of the first Wireless Application Protocol (WAP) application. One of the main reasons for the lukewarm response so far may be attributed to the lack of a “Killer” application. Many companies and developers have attempted to replicate email services (an Internet Killer appplication) within the WAP realm, but till now, no significant success has been reported. This paper will first discuss on the key functions which are lacking in the present WAP-email service, and which are arguably necessary if a much larger user base is to be attracted to these services. A new system will be proposed which can enable the user to send files residing in a remote personal computer (PC) as attachments to his emails using WAP-enabled mobile devices. The implementation of the system will be presented in details. Issue relating to the connection to various types of email servers and the security of the system will also be addressed in the paper.     

Supercritical fluid extraction of daphne (Laurus nobilis L.) seed oil

Laurus nobilis L., commonly known as daphne tree, is an evergreen that belongs to the Lauraceae family. Daphne trees produce grape-sized shiny purplish berries having three parts: flesh, skin, and an inner kernel (single seed). This study examines supercritical CO₂ (SC-CO₂) extraction of oil from daphne seeds. The oil yield of ground seeds varied from 14 to 28% depending on the method and particle size used for oil recovery. Yields were similar for both petroleum ether and SC-CO₂ extraction. The extraction yield decreased significantly with increasing particle size. The amount of extract collected increased exponentially with increasing SC-CO₂ pressure. The highest extraction yield was obtained at the highest temperature studied, 75°C. More than 45% of the oil was lauric acid. SC-CO₂ is a viable technique to obtain high-purity L. nobilis L. seed oil, which is a potential ingredient for the cosmetic industry.     

Performance analysis of linear precoding based on field trials results of MIMO-OFDM system

We use field trial results obtained from a multiple-input multiple-output (MIMO) orthogonal frequency-division multiplexing (OFDM) wireless system with two transmitter and three receiver antennas (2/spl times/3), to first validate the properties of the transmit correlation matrix in a macro-cellular environment. We find that approximately 20% of the locations have well-defined transmit correlation matrices. Furthermore, the eigenvectors of the transmit correlation matrix vary slowly over distance with 60% of the locations having eigenvector variation of less than 1 dB over a distance of 20 m. Next, we quantify the performance of the optimal statistical linear precoding (OSLP) , and statistical one-dimensional (1-D) eigenbeamforming (SEB) based on transmit correlation matrices, and the 1-D eigenbeamforming (EB)-based on perfect channel knowledge at the transmitter. We find that the OSLP and SEB schemes obtain array gain over the Alamouti scheme at lower signal-to-noise ratio (SNR) with a median gain of 2.0 (1.5) dB at the 1.0-(3.5) km cell-radii. However, the SEB scheme (unlike the OSLP scheme) looses diversity order at higher SNR that leads to a performance loss. The EB scheme provides the best performance over the Alamouti scheme, at the expense of increased feedback requirements.