高取代度氰乙基纤维素与二醋酸纤维素共混中空纤维纳滤膜的研制

采用高取代度氰乙基纤维素与二醋酸纤维素共混为膜材料,丙酮、二氧六环混合溶剂,以有机醇为主、加入适量其他添加剂为致孔剂,通过冰水凝胶浴干湿法纺丝,制得性能良好的中空纤维纳滤膜,该膜在给水质量浓度1 800 mg/L、操作压力为0.6 MPa、水温25℃条件下,对二价盐CaCl2、一价盐NaCl的水溶液的脱盐率分别大于90%和小于60%,水通量均大于3.5 mL/(cm2.h).还讨论了膜液的组成和纺丝条件对膜性能的影响.     

采煤机破碎机构的设计

结合采煤机破碎机构的传动装置,简要地阐述了应用数学规划理论进行采煤机破碎机构的设计原理,以更好地发挥采煤机的功效。     

单模光纤环轴向磁场问题的理论研究

去偏光纤陀螺的非理想单模光纤,在垂直于光纤环面的轴向磁场作用下,由于Faraday 效应,在其中传播的正反两束光会产生一个与磁场有关的非互易相位差.本文基于单色光对在轴向磁场作用下的单模光纤环进行理论推导、分析,给出仿真结果和实验结果,并提出减小轴向磁场作用下的Faraday非互易相位差的方法.     

AFM氮化硅纳米探针研制

在〈100〉晶向硅片上通过各向异性腐蚀形成作为模板的倒金字塔形尖坑, 用LPCVD和PECVD法淀积一层约 1 μm厚的氮化硅膜, 通过等离子刻蚀形成悬臂梁图形,再把抛光玻璃片静电键合到氮化硅膜上, 最后把衬底硅片腐蚀掉,带有金字塔形针尖的悬臂梁就暴露出来,从而构成可用于原子力显微镜(AFM)描绘纳米图像的氮化硅纳米探针.对针尖的尖度和氮化硅膜悬臂梁的热应力补偿进行了深入研讨, 并报道一种特殊而有效的悬臂梁掩模板图形的新设计.制成的氮化硅纳米探针在原子力显微镜上成功地描绘出了纳米图像, 经检测, 其 Z向偏转检测精度优于10-9量级.     

γ射线辐照水溶液中氯霉素的降解研究

研究了γ射线辐照水溶液中氯霉素的降解规律,并对辐解产物进行了初步探讨.根据辐照前后高效液相色谱(High performance liquid chromatography,HPLC)图谱中氯霉素峰面积变化,分析得出氯霉素随吸收剂量和初始浓度的降解规律.利用液相色谱串联质谱(Liquid chromatography tandem mass spectrometry,LC/MS/MS),定性分析氯霉素的辐解产物.结果表明,氯霉素残留量随吸收剂量和初始浓度的变化关系满足指数方程;氯霉素辐射降解后形成了30个以上的辐解产物,它们在氯霉素检测波长278nm下的响应值均较低;确定了氯霉素在不同辐解条件下均出现的8种主要辐解产物,它们的准分子离子质量[M-H]分别为:353、337、335(A)、335(B)、319、289、127、166,并对主要辐解产物进行了初步的结构解析.     

提高力反馈速率陀螺动态特性的优化设计

陀螺带宽窄将影响系统的动态特性.本文采用比例-积分控制和迟后-超前网络相结合的校正方法,通过优化校正网络的参数、合理配置零极点、设计控制回路,使陀螺系统的带宽提高到150 Hz、输出噪声小于10 mV.并通过仿真验证了控制回路设计的合理性.     

需求弹性对发电系统可靠性的影响

在电力市场环境下,由于负荷需求弹性的存在,面对电价的波动,用户可适时调整负荷计划,改变实际负荷曲线,从而直接影响发电系统可靠性的计算。构筑考虑需求弹性的电价负反馈模型,通过对IEEE30节点系统进行计算,研究了需求弹性对发电系统可靠性的影响,也即对电源充裕度的影响。     

分布式参数输电线路电磁暂态分析新方法

根据函数逼近原理,输电线路的电报方程可以整理为一组正交基的线性组合。文章采用Daubechies正交基,经过投影变换,映像到与依赖于时间变量的和建立在确定架构的函数空间,与输电线路的电压和电流相关的微分方程被转换为代数矢量方程。从而,建立起每一单元的投影等效模型,然后可以在投映域中对输电系统的暂态进行计算。利用EMTP仿真验证了所建议的方法。     

Analysis of microbending of CuZn37 brass foils based on strain gradient hardening models

Microbending experiments of brass foils were conducted and demonstrated clear size effects, i.e., the normalized bending moment increased with the reduction of foil thickness. The experiments were modeled using the classical plasticity model and three strain-gradient plasticity models. A modified Nix-Gao model was proposed to consider the number of twins across the thickness direction in strain hardening. It was found that the proposed model could better predict the normalized bending moment for both fine-grain and coarse-grain foils and the proposed equation for material intrinsic length could better capture the physics of material deformation. Furthermore, micro-hardness distributions in the bending area were measured and obvious lower-hardness region was found in the middle layer of fine-grain foils instead of coarse-grain foils. This indicates that the modified Nix-Gao model and the assumption of fully plastic bending worked better for coarse-grain foils than for fine-grain foils.     

<Superscript>1</Superscript>H-NMR Spectroscopy as a New Tool in the Assessment of the Oxidative State in Edible Oils

Within the course of lipid peroxidation, hydroperoxides are formed as primary products. They can be used as analytical markers to assess the deterioration status of oils and fats. Here a new ¹H-NMR assay to determine the hydroperoxide amount in edible oils is presented. We were able to show that the analytical performance of the method is similar to that of the commonly used peroxide value (PV) according to Wheeler. A total of 290 edible oil samples were analyzed using both methods. For some oil varieties considerable discrepancies were found between the results obtained. In the case of black seed and olive oil, two substances could be identified that cause positive (black seed oil) and negative (olive oils) deviations from the theoretical PV expected from the NMR values.