高质量ZnO薄膜的退火性质研究

在LP－MOCVD中，我们利用Zn(C2H5)2作Zn源，CO2作氧源，在（0002）蓝宝石衬底上成功制备出皮c轴取向高度一致的ZnO薄膜，并对其进行500℃-800℃四个不同温度的退火。利用XRD、吸收谱、光致发光谱和AFM等手段研究了退火对ZnO晶体质量和光学性质的影响。退火后，（0002）ZnO的XRD衍射峰强度显著增强，c轴晶格常数变小，同时（0002）ZnOX射红衍射峰半高宽不断减小表明晶粒逐渐增大，这与AFM观察结果较一致。由透射谱拟合得到的光学带隙退火后变小，PL谱的带边发射则加强，并出现红移，蓝带发光被有效抑制，表明ZnO薄膜的质量得到提高。     

Remarks on validation of uncertainty models using frequencyresponse data

Uncertainty validation using frequency response data has been studied by several authors. If the uncertainty is assumed to be stable, then the problem amounts to one of boundary interpolation. It is shown in this paper that for more general uncertainty models, an additional constraint is needed in order for the results of Boulet et al. (1998) and Chen (1997) to be applicable. Boundary interpolation, together with the proposed constraint, gives a satisfactory answer to the validation problem for uncertainty models     

战术弹道导弹落点预报的一种方法

根据椭圆弹道理论，提出了一种可以用于反战术弹道导弹作战的预测弹道及预报落点的方法，给出了算例，并分析了产生误差的原因和对预测结果的影响程度。     

Structure and properties of CE/CTBN/EP blends: II. Effect of EP on the mechanical properties and thermostability of the CE/CTBN system

Carboxyl‐terminated butadiene‐acrylonitrile rubber (CTBN) has often been used to improve the toughness of cyanate ester (CE) resin while sacrificing modulus and thermostability. In this paper, the addition of the appropriate amount of epoxy resin (EP) to the CE/CTBN system is shown to not only increase the modulus and thermostability of the blend, but also improve the toughness. The values of impact strength showed a maximum for the CE/CTBN/EP 100/5/5 blend. The temperature of 10 % weight loss (T₁₀) improves from 376 °C for CE/CTBN 100/5 to 407 °C for the CE/CTBN/EP 100/5/2.5 blend. It is proposed that addition of the appropriate amount of EP can decrease the mobility and increase the stability of CTBN via the reaction between the terminal carboxyl group of CTBN and the hydroxyl group of EP. But a very high EP concentration will decrease the crosslinking density of CE, consequently reducing the mechanical properties and thermostability of the blends. Copyright © 2004 Society of Chemical Industry     

Application of a multi-channel system for continuous monitoring and an early warning system.

A multi-channel continuous toxicity monitoring system developed in our laboratory, based on two-stage mini-bioreactors, was successfully implemented in the form of computer-based data acquisition. The multi-channel system consists of a series of a two-stage minibioreactor systems connected by a fiber optic probe to a luminometer, and uses genetically engineered bioluminescent bacteria for the detection of the potential toxicity from the soluble chemicals. This system can be stably and continuously operated due to the separation of the culture reactor from the test reactor and accomplish easy and long-term monitoring without system shut down by abrupt inflows of severe polluting chemicals. Four different recombinant bioluminescent bacteria were used in different channels so that the modes of the samples toxicities can be reasonably identified and evaluated based upon the response signature of each channel. The bioluminescent signatures were delivered from four channels by switching one at once, while the data is automatically logged to an IBM compatible computer. We also achieved the enhancement of the system through the manipulation of the dilution rate and the use of thermo-lux fusion strains. Finally, this system is now being implemented to a drinking water reservoir and river for remote sensing as an early warning system.     

Fabrication of multi-walled carbon nanotube reinforced polyelectrolyte hollow nanofibers by electrospinning

Hybrid hollow multi-walled carbon nanotubes (MWCNTs)/polyelectrolytes (PE) nanofibers were prepared by a combination of the electrospinning method and layer-by-layer (LbL) technique. The mixed polystyrene (PS)/MWCNTs nanofibers were obtained by electrospinning method, which were employed as templates to self-assembly multilayered polyelectrolytes by LbL technique. Hollow MWCNTs/PE nanofibers were obtained by selectively removed part of the template: PS, which is confirmed by Raman spectra, transmission electron microscopy (TEM) and scanning electron microscopy (SEM).     

螺栓角钢钢节点的三维非线性有限元分析

对螺栓角钢钢节点半刚性连接采用非线性有限元分析方法 ,对连接中的主要构件的顶部、底部、腹板角钢、高强螺栓、梁翼缘、柱翼缘和柱翼缘加劲肋进行三维非线性有限元精细模拟 ,针对有无柱加劲肋、有无腹板角钢等几种连接的情况进行比较分析 ,探讨了螺栓角钢半刚性连接的受力性能。     

Preparation and Compressive Stress Effect of Polymer Matrix RE-Fe Giant Magnetostrictive Composite

Polymer matrix RE-Fe giant magnetostrictire composite （GMPC） was prepared using bonding and magnetic field forming technique, and magnetostriction of samples was measured for different compressive stress. The experimental results show thai there is certain compressive effect in GMPC. And the influence of compressive stress on magnetostriction of sample was investigated. It offers essential reference for application and device design of GMPC.     

Preparation and characterization of cuprous iodide nanoparticles

A new technique for the preparation of CuI nanoparticles from CuSO₄ and KI ethanol solutions has been developed. Preparation conditions were optimized through a series of experiments. Under these conditions, the yield of CuI reached 95.39%. The product was characterized and the reaction kinetics was studied. The results show that the product takes a roughly spherical shape with an average particle size of less then 50 nm. The activation energy of the formation of CuI is found to be E _a = 0.58 × 10² kJ/mol, and the preexponential factor in the Arrhenius equation is k ₀ = 7.43 × 10¹⁶ mol/(l s). The text was submitted by the authors in English.