Oxygen segregation and Ge diffusion in annealed oxygen ion-implanted relaxed SiGe/Si heterostructures

Relaxed SiGe-on-insulator (SGOI) is a suitable material to fabricate strained Si structures. Separation-by-implantation-of-oxygen (SIMOX) is a competing method to synthesize SGOI materials. In this work, SiGe/Si samples were implanted with 3×10¹⁷ cm⁻² oxygen ions at 60 kV, followed by high-temperature annealing. Oxygen segregation and Ge diffusion during the annealing process were investigated using Rutherford backscattering spectroscopy/channeling (RBS/C), high-resolution x-ray diffraction (HRXRD), and high-resolution transmission electron microscopy (HRTEM). Our results show that the sample structure strongly depends on the thermal history and Ge diffuses mainly at the beginning stage of the high-temperature process. The process can be improved by introducing an annealing step at a medium temperature before high-temperature annealing, and sharper interfaces and good crystal quality can be obtained. Our results indicate that the SIMOX process for silicon-on-insulator (SOI) fabrication can be adopted to produce SGOI.     

Microstructural considerations for ultrafine lead free solder joints

As solder joints become increasingly miniaturised to meet the challenging demands of future electronic packaging, it is vitally important to consider whether the solder joint size and geometry could become a reliability issue and thereby affect the implementation of the Pb-free solders. In this study, different bumping techniques, e.g., solder dipping, stencil printing followed by solder reflow, and electroplating of solders and subsequent reflow, were used to investigate the microstructure and interfacial interactions of molten Sn and Sn-based Pb-free solders on different metallizations, e.g., copper and electroless nickel immersion gold (ENIG). The resultant microstructures from a variety of pad sizes, ranging from 1 mm down to 25 μm, and representing different solder bump geometries have been investigated. In addition, thermodynamic and combined thermodynamic-kinetic modelling has been used in order to understand the microstructure of Pb-free solders, the kinetics of dissolution of the metallizations and the formation of interfacial intermetallic compounds (IMCs). Both the experimental results and theoretical predictions suggest that the solder bump size and geometry can influence the as-soldered microstructure. In the light of the increasing importance of the microstructural features of the ultrafine solder joint in determining its long term reliability, a novel computational interface between software for thermodynamic calculations, high-level scientific computing and multiphysics modelling, is introduced. This modelling methodology provides a potential platform for microstructure-based Finite Element (FE) reliability modelling of ultrafine interconnects for future microelectronic products.     

Mobile Ferroelastic Domain Walls in Nanocrystalline PZT Films: the Direct Piezoelectric Effect

Ferroelastic (90°) domain wall motion occurs readily in bulk samples of displacive ferroelectrics such as Pb(Zr,Ti)O₃ (PZT), dictating critical piezoelectric, dielectric, and polarization switching properties. Many prior studies have used converse piezoelectric measurements to probe the dynamics of ferroelastic domains in thin films; however, such experiments are strongly influenced by the mechanical clamping effect of the substrate, which inhibits electric field‐induced 90° domain wall motion. Nevertheless, these observations raise a tantalizing question: Does the application of mechanical stress, rather than electric field, result in an entirely different response in thin films? Here we report biaxial stress‐driven crystallographic reorientation of (100)/(001) textured, 70 nm thick Pb(Zr_0.25Ti_0.75)O₃ films via 90° domain wall motion, measured in situ by both x‐ray diffraction and piezoforce microscopy. Visual evidence of nanoscale mechanisms that underlie the direct piezoelectric effect is shown. Mobile 90° domain walls effect complete orientation switching in the grains in which they operate, without apparent wall pinning, indicating that bulk‐like ferroelastic behavior can extend to nanocrystalline films in the absence of substrate clamping.     

Mirror or Molder? A Study of Media Coverage,Stock Prices,and Trading Volumes in Germany

This article investigates the short‐term relationship between media coverage, stock prices, and trading volumes of eight listed German companies. A content analysis of news reports about the selected companies and a secondary analysis of the daily changes in closing prices and the trading volumes of these companies were combined in a time‐series design. After ARIMA‐modeling each of them, the results suggest that media coverage rather reflects than shapes the development at stock exchanges from a short‐term perspective (2 months). There were almost no hints for a widespread media effect, that is, an impact on so many investors that it will result in a measurable change in stock prices or trading volumes. Finally, theoretical and methodological consequences for exploring widespread media effects are discussed.     

Nonparametric 1-D temperature restoration in lossy media using Tikhonov regularization on sparse radiometry data

Microwave thermometry has the potential to characterize thermal gradients in lossy materials down to a few centimeters depth. The problem of retrieving temperature profiles from sets of brightness temperatures is studied using Galerkin expansion of one-dimensional (1-D) temperature profiles combined with Tikhonov regularization and predefined boundary conditions. From a priori knowledge of the temperature field shape, smooth Chebyshev polynomials are used as basis functions in the series expansion. The proposed estimator does not require iterative calculations that are normally performed using conventional numerical methods for signal parameter estimation and is, thus, very fast. Noise effects versus bandwidth limitations (smoothness of solutions) are studied in terms of four performance indexes defined in the text. In general, statistical spread of the temperature estimator increases with increasing number of Chebyshev polynomials. Systematic deviation from true values (bias) decreases as the number of Chebyshev polynomials increases. Results show that smooth temperature profiles can be reproduced using 6-7 Chebyshev polynomials. With additional constraints such as boundary conditions and maxima localization, a three-frequency-band radiometric scan is sufficient to produce acceptable results in regions with low thermal gradients. As the spatial variability of the 1-D temperature profile increases, more radiometric bands (5-6) are required to provide nonbiased estimates.     

Realization of an active inductance for a low power high bandwidth DC power line communication network transceiver

An active inductor based on an improved gyrator circuit is proposed. The active inductor is developed to be implemented in a high impedance transceiver for a wearable DC power line communication network where requirements such as low power consumption, high bandwidth and numerous nodes support are prioritized. A load isolation step is introduced to ensure the stability of the active inductance's size on different load currents. The proposed gyrator circuit is analyzed and optimized by means of theoretical calculations. The theoretical results are then verified by simulations and experiments in the frequency range up to 10 MHz.     

Social media and political partisanship – A subaltern public sphere’s role in democracy

Social media, as a subaltern public sphere (Fraser, 1990), have a democratic function in providing an alternative platform for minorities and marginalized to defy mainstream discourses in the public sphere. However, social media have been found to have an echo chamber effect, which may be detrimental to democracy. They may help to accelerate the ascendancy of a “post-truth” era in which objective facts are less influential in shaping public opinion than appeals to emotion and personal belief. A study on political polarization, however, showed that selective exposure and avoidance in social media are weak indicators of polarization (Johnson et al., 2017). This study examines the role of social media in democracy and partisan politics. The authors considered that despite the echo chamber effect, social media have a limited part to play in the formation of polarized stances compared with other factors, such as demographics, political orientation, and mass media use. The study tested two main hypotheses: H1: Social media use is associated with political stance that is marginalized in the mainstream media; H2: Political orientation has a stronger relationship than social media use with the stance toward political values and social issues.The results supported both hypotheses. Social media are associated with political stance that is marginalized in the mainstream media. However, when compared with other factors, the relationship between social media and stance becomes less obvious. Although the echo chamber effect may reinforce the original stance, social media do not exhibit a strong relationship with the stance toward political values and social issues. Partisan orientation and use of partisan mass media are found to have stronger links with variations in stance. Social media, however, provide a subaltern public sphere for those excluded from the dominant public sphere, thus extending the public sphere to accommodate multiple opinions and perspectives.     

Self‐Compensation in Transparent Conducting F‐Doped SnO2

The factors limiting the conductivity of fluorine‐doped tin dioxide (FTO) produced via atmospheric pressure chemical vapor deposition are investigated. Modeling of the transport properties indicates that the measured Hall effect mobilities are far below the theoretical ionized impurity scattering limit. Significant compensation of donors by acceptors is present with a compensation ratio of 0.5, indicating that for every two donors there is approximately one acceptor. Hybrid density functional theory calculations of defect and impurity formation energies indicate the most probable acceptor‐type defects. The fluorine interstitial defect has the lowest formation energy in the degenerate regime of FTO. Fluorine interstitials act as singly charged acceptors at the high Fermi levels corresponding to degenerately n‐type films. X‐ray photoemission spectroscopy of the fluorine impurities is consistent with the presence of substitutional F_O donors and interstitial F_i in a roughly 2:1 ratio in agreement with the compensation ratio indicated by the transport modeling. Quantitative analysis through Hall effect, X‐ray photoemission spectroscopy, and calibrated secondary ion mass spectrometry further supports the presence of compensating fluorine‐related defects.     

Gas Responsive Nanoswitch: Copper Oxide Composite for Highly Selective H2S Detection

A nanocomposite material based on copper(II) oxide (CuO) and its utilization as a highly selective and stable gas‐responsive electrical switch for hydrogen sulphide (H₂S) detection is presented. The material can be applied as a sensitive layer for H₂S monitoring, e.g., in biogas gas plants. CuO nanoparticles are embedded in a rigid, nanoporous silica (SiO₂) matrix to form an electrical percolating network of low conducting CuO and, upon exposure to H₂S, highly conducting copper(II) sulphide (CuS) particles. By steric hindrance due to the silica pore walls, the structure of the network is maintained even though the reversible reaction of CuO to CuS is accompanied by significant volume expansion. The conducting state of the percolating network can be controlled by a variety of parameters, such as temperature, electrode layout, and network topology of the porous silica matrix. The latter means that this new type of sensing material has a structure‐encoded detection limit for H₂S, which offers new application opportunities. The fabrication process of the mesoporous CuO@SiO₂ composite as well as the sensor design and characteristics are described in detail. In addition, theoretical modeling of the percolation effect by Monte‐Carlo simulations yields deeper insight into the underlying percolation mechanism and the observed response characteristics.