White Electroluminescence by Supramolecular Control of Energy Transfer in Blends of Organic‐Soluble Encapsulated Polyfluorenes

Here, it is demonstrated that energy transfer in a blend of semiconducting polymers can be strongly reduced by non‐covalent encapsulation of one constituent, ensured by threading of the conjugated strands into functionalized cyclodextrins. Such macrocycles control the minimum intermolecular distance of chromophores with similar alignment, at the nanoscale, and therefore the relevant energy transfer rates, thus enabling fabrication of white‐light‐emitting diodes (CIE coordinates: x = 0.282, y = 0.336). In particular, white electroluminescence in a binary blend of a blue‐emitting, organic‐soluble rotaxane based on a polyfluorene derivative and the green‐emitting poly(9,9‐dioctylfluorene‐alt‐benzothiadiazole ( F8BT ) is achieved. Morphological and structural analyses by atomic force microscopy, fluorescence mapping, µ‐Raman, and fluorescence lifetime microscopy are used to complement optical and electroluminescence characterization, and to enable a deeper insight into the properties of the novel blend.     

跟踪正负峰值的整流器

从音乐到复杂的控制系统等各种信号波形也许包含不相等的正负峰值幅度“。包络线跟随”电路能跟踪不相等的峰值,而选择预期峰值的能力能增强该电路的性能(参考文献1)。图1中的电路向经典的绝对值电路施加了一项新方法。向R(1全波)施加一个输入信号,就会产生一个等于输入绝对值的输出。向R(6正)或R7(负)施加一个输入信号,就会分别产生正或负半周期输出。图2描绘了所有三种工作模式。如果你考虑到运算放大器IC1力求把自己的反相输入保持在虚拟地,那么对该电路的理解就简单了。例如,向负输入R7施加-1V,就会把D1的阳极驱动到-333mV。IC1A的…     

Should mobile Internet be an extension to the fixed web? Fixed-mobile reinforcement as mediator between context of use and future use

As the fixed and mobile Internet are converging, the question emerges whether consumers expect mobile Internet services to replicate services they know from the fixed Internet. Literature on reinforcement and displacement suggests that the use of new media depends on whether users are inclined to replace or reinforce their existing media use on a new device. This paper analyzes whether the importance that users attribute to using similar services on their mobile phone as on the fixed Internet can explain the intention to adopt mobile services. Specifically, we investigate if such fixed-mobile reinforcement could mediate the impact of personal innovativeness and several dimensions of context. We compare basic Internet services, entertainment services and transaction services. We find that especially the intention to adopt basic Internet services largely depends on the importance of using similar services in the mobile domain as on the fixed Internet. Several context-of-use predictors are partially or even fully mediated by fixed-mobile reinforcement. The results convey a positive message to operators that are betting on converged multimedia services that can be accessed from any device and from any fixed or mobile network.     

传统中药现代化--中药健康食品的开发

传统中药是现代生活健康的宝库,其功效在保健及慢性疾病的治疗方面尤其显著,并已备受世界重视.要成功将中药引进世界市场,最基本要求是要从科学方法去证明其效用及安全性;更重要是依从传统中医学对复方应用的要求去作研究.本文陈述了我们对传统中药古方"生脉散"研究及开发抗氧化健康食品的经验.透过现代生化及药理技术,我们发现"生脉散"中的五味子含丰富的抗氧化活性成分,为传统中医学利用"生脉散"治疗心脏病提供了理论依据.     

0.18μm铜金属双重镶嵌工艺中空间成像套刻精度分析

由于空间成像套刻(Overlay)技术的预算随集成电路(IC)设计规范的紧缩而吃紧,因此,Overlay测量技术准确度的重要意义也随之提高。通过对后开发(AfterDevelopDI)阶段和后蚀刻(AfterEtchFI)阶段的Overlay测量结果进行比较,研究了0.18μm设计规范下的铜金属双重镶嵌工艺过程中的Overlay准确度。在确保对同一个晶圆进行后开发(DI)阶段和后蚀刻(FI)阶段测试的条件下,我们对成品晶圆的5个工艺层进行了比较。此外,还利用CD-SEM(线宽-扫描电子显微镜)测量了某个工艺层(PolyGate)上的芯片内Overlay,并与采用分割线方法的光学Overlay测量结果进行了比较。发现对芯片内overlay的校准存在着严重的局限性,即在应用CD-SEM时缺乏合适的结构进行Overlay测量。我们还将继续为大家提供定量的比较结果,同时也会向大家推荐组合的CD-SEM测量结构,使其能够被应用到今后的光刻设计中。     

Scheduling Combined Unicast and Multicast Traffic in Broadcast WDM Networks

This paper studies the performance of various strategies for scheduling a combined load of unicast and multicast traffic in a broadcast WDM network. The performance measure of interest is schedule length, which directly affects both aggregate network throughput and average packet delay. Three different scheduling strategies are presented, namely: separate scheduling of unicast and multicast traffic, treating multicast traffic as a number of unicast messages, and treating unicast traffic as multicasts of size one. A lower bound on the schedule length for each strategy is first obtained. Subsequently, the strategies are compared against each other using extensive simulation experiments in order to establish the regions of operation, in terms of a number of relevant system parameters, for which each strategy performs best. Our main conclusions are as follows. Multicast traffic can be treated as unicast traffic, by replicating all multicast packets, under very limited circumstances. On the other hand, treating unicast traffic as a special case of multicast traffic with a group of size 1, produces short schedules in most cases. Alternatively, scheduling and transmitting each traffic component separately is also a good choice.     

A Comparison of Allocation Policies in Wavelength Routing Networks*

We consider wavelength routing networks with and without wavelength converters, and several wavelength allocation policies. Through numerical and simulation results we obtain upper and lower bounds on the blocking probabilities for two wavelength allocation policies that are most likely to be used in practice, namely, most-used and first-fit allocation. These bounds are the blocking probabilities obtained by the random wavelength allocation policy with either no converters or with converters at all nodes of the network. Furthermore, we demonstrate that using the most-used or first-fit policies gives an improvement on call blocking probabilities that is equivalent to employing converters at a number of nodes in a network with the random allocation policy. These results have been obtained for a wide range of loads for both single-path and general mesh topology networks. The main conclusion of our work is that the gains obtained by employing specialized and expensive hardware (namely, wavelength converters) can be realized cost-effectively by making more intelligent choices in software (namely, the wavelength allocation policy).     

A study of the thermal behaviour of a specimen during fatigue

A steel specimen (XC 10), submitted to fatigue by alternating symmetrical torsion, gives rise to heat dissipation, which is a function of the amplitude of the applied forces.The relationship between the amplitude of the applied forces and the quantity of heat dissipated was measured while a specimen underwent fatigue testing (E_n curves).The results appear to show that this relation is not identical for similar specimens at the beginning of the tests, initial state which is assumed to correspond to something like a “virgin state”, but that there is a convergence of the E_n curves as rupture is approached.     

Polymers Containing Highly Polarizable Conjugated Side Chains as High‐Performance All‐Organic Nanodielectric Materials

The discovery of nanodipolar π‐conjugated oligomer‐containing polymers as high performance nanodielectric materials with high permittivity and low dielectric loss over a wide range of frequency (100 Hz–4 MHz) is reported. Terthiophene‐containing methacrylate polymers are synthesized by reversible addition fragmentation transfer (RAFT) polymerization. Both X‐ray and thermal studies indicate the formation of small crystalline domains of terthiophene side chains dispersed in amorphous matrix. The highly polarizable and fast‐responsive nanodipoles from the nanoscale crystalline domains (<2 nm) are believed to dictate the performance. These polymers uniquely satisfy nanodipole architectures conjectured two decades ago to guide the design of high performance nanodielectric materials. This unprecedented approach can be generalized to a variety of π‐conjugated oligomer‐containing polymers for the development of high energy density capacitor materials.     

Self‐Assembled Conjugated Thiophene‐Based Rotaxane Architectures: Structural,Computational, and Spectroscopic Insights into Molecular Aggregation

A comparative study of the self‐assembly at a variety of surfaces of a dithiophene rotaxane 1 ?β‐CD and its corresponding dumbbell, 1, by means of atomic force microscopy (AFM) imaging and scanning tunneling microscopy (STM) imaging on the micrometer and nanometer scale, respectively. The dumbbell is found to have a greater propensity to form ordered supramolecular assemblies, as a result of π–π interactions between dithiophenes belonging to adjacent molecules, which are hindered in the rotaxane. The fine molecular structure determined by STM was compared to that obtained by molecular modelling. The optical properties of both rotaxane and dumbbell in the solid state were investigated by steady‐state and time‐resolved photoluminescence (PL) experiments on spin‐cast films and diluted solutions. The comparison between the optical features of the threaded and unthreaded systems reveals an effective role of encapsulation in reducing aggregation and exciton migration for the rotaxanes with respect to the dumbbells, thus leading to higher PL quantum efficiency and preserved single‐molecule photophysics for longer times after excitation in the threaded oligomers.