Hot Isostatic Pressing of Reactive SnO2 Powder

Tin(IV) oxide (SnO₂) crystallizes at room temperature by adding hydrazine monohydrate ((NH₂)₂· H₂O) to a hydrochloric acid solution of tin, followed by washing and drying. Well-densified SnO₂ ceramics (99.8% of theoretical) with an average grain size of 0.9 μm have been fabricated by hot isostatic pressing for 2 h at 900°C and 196 MPa. Their Vickers hardness and bending strength are 14.4 GPa and 200 MPa, respectively. They exhibit an electrical conductivity of 2 × 10⁻³−9 × 10⁻³ S·cm⁻¹ at room temperature.     

Synthesis of Microcrystalline Hematite and Magnetite in Organic Solvents and Effect of a Small Amount of Water in the Solvents

Microcrystalline magnetite (Fe₃O₄) particles having diameters of 7-34 nm were synthesized by thermal treatment of iron(III) acetylacetonate in organic solvents at high temperatures (423-573 K) and under autogenous pressures of the solvents. When the treatment was conducted in 1-propanol containing a small amount of water (1-3 vol%), nanosized hematite (α-Fe₂O₃) crystallized, which then was reduced to magnetite after a prolonged reaction time, indicating that a small amount of water in 1-propanol drastically changed the reaction mechanism for the formation of iron oxides.     

High-efficiency InGaP/In0.01Ga0.99As tandem solar cells lattice-matched to Ge substrates

Conversion efficiency (AM1.5G) of more than 30% was achieved by adding a small quantity of Indium into a GaAs bottom cell in the conventional tandem solar cell on Ge substrate. It was found that the lattice-mismatch between GaAs and Ge caused misfit-dislocations in thick GaAs layers and reduced an open-circuit voltage (V_oc) of the cell. An In_0.49Ga_0.51P/In_0.01Ga_0.99As tandem cell lattice-matched to Ge showed a great improvement in efficiency, which was attributed to an increase in the V_oc of the bottom cell and increases in the photocurrents both in the top and bottom cells due to reductions in band-gap energy.     

Preparation of Transparent Polyimides Derived from cis‐ and trans‐Dicyclohexyl‐3,3′,4,4′‐tetracarboxylic Dianhydrides

Two series of alicyclic polyimides composed of cis‐ and trans‐dicyclohexyl‐3,3′,4,4′‐tetracarboxylic dianhydrides (DCDAs) and aromatic diamines were prepared. All cis‐polymers could be readily prepared both in a one‐step method and a two‐step method. However, a two‐step method is preferably applied in the preparation of trans‐polymers, because in a one‐step method the trans‐configuration is partially lost at higher temperatures. These polyimide solutions could be cast into tough and flexible films, which were characterized by inherent viscosity, GPC, DSC, TGA measurements, and UV‐vis spectroscopy. The glass transition temperatures (T_g's) of the polymers were in the range of 210–270°C and the 5% weight loss temperatures were around 480°C for all PIs prepared. The optical transmittances of these films were more than 80% at 350 nm for ca. 15 μm thickness.     

Theoretical analysis of transient recovery voltages when clearing a transformer secondary fault

An analytical formula for the transient recovery voltage and its derivative dv/dt across a circuit breaker has been derived for the case of a transformer secondary fault. A comparison of the calculated results with field test and EMTP simulation results has demonstrated it to have satisfactory accuracy. By applying the formula, the effects of various circuit parameters on the transient recovery voltage and its derivative dv/dt are elucidated. The derivative dv/dt, defined conventionally as the ratio of the crest value and the time to the crest, is found to be about two‐thirds of the maximum value of dv/dt given as a function of time. In addition, a formula for the critical circuit parameters at which dv/dt across a vacuum circuit breaker reaches the critical condition, that is, the circuit breaker fails to interrupt a fault current, is derived. © 2000 Scripta Technica, Electr Eng Jpn, 134(3): 44–52, 2001     

Autotaxin May Have Lysophosphatidic Acid-Unrelated Effects on Three-Dimension (3D) Cultured Human Trabecular Meshwork (HTM) Cells

Purpose: The objective of the current study was to evaluate the effects of the autotaxin (ATX)–lysophosphatidic acid (LPA) signaling axis on the human trabecular meshwork (HTM) in two-dimensional (2D) and three-dimensional (3D) cultures of HTM cells. Methods: The effects were characterized by transendothelial electrical resistance (TEER) and FITC-dextran permeability (2D), measurements of size and stiffness (3D), and the expression of several genes, including extracellular matrix (ECM) molecules, their modulators, and endoplasmic reticulum (ER) stress-related factors. Results: A one-day exposure to 200 nM LPA induced significant down-sizing effects of the 3D HTM spheroids, and these effects were enhanced slightly on longer exposure. The TEER and FITC-dextran permeability data indicate that LPA induced an increase in the barrier function of the 2D HTM monolayers. A one-day exposure to a 2 mg/L solution of ATX also resulted in a significant decrease in the sizes of the 3D HTM spheroids, and an increase in stiffness was also observed. The gene expression of several ECMs, their regulators and ER-stress related factors by the 3D HTM spheroids were altered by both ATX and LPA, but in different manners. Conclusions: The findings presented herein suggest that ATX may have additional roles in the human TM, in addition to the ATX–LPA signaling axis.     

Experimental study on laboratory scale Totalized Hydrogen Energy Utilization System using wind power data

The renewable energy source like wind energy generates electric power with intermittent nature. Hydrogen energy system can help to solve the fluctuation problem of the wind power. Totalized Hydrogen Energy Utilization System (THEUS) consists of a Unitized Reversible Fuel Cell (URFC), a hydrogen storage tank, and other auxiliary components. Wind power is inherently variable; the URFC will be subjected to a dynamic input power profile in water electrolyzer mode operation. This paper describes the THEUS operation and performance at different variations in intermittent wind power. The performance of the THEUS was evaluated in water electrolyzer and fuel cell mode operation. The stack efficiency, system efficiency, and system efficiency including heat output from the URFC were presented at each operation. The total efficiency of the URFC and THEUS were also investigated. The maximum total efficiency of the URFC and THEUS were 53% and 66%, respectively.     

Hydrogel of biodegradable cellulose derivatives. I. Radiation‐induced crosslinking of CMC

Radiation crosslinking of carboxymethylcellulose (CMC) with a degree of substitution (DS) from 0.7 to 2.2 was the subject of the current investigation. CMC was irradiated in solid‐state and aqueous solutions at various irradiation doses. The DS and the concentration of the aqueous solution had a remarkable affect on the crosslinking of CMC. Irradiation of CMC, even with a high DS, 2.2 in solid state, and a low DS, 0.7 in 10% aqueous solution, resulted in degradation. However, it was found that irradiation of CMC with a relatively high DS, 1.32, led to crosslinking in a 5% aqueous solution, and 20% CMC gave the highest gel fraction. CMC with a DS of 2.2 induced higher crosslinking than that with a DS of 1.32 at lower doses with the same concentration. Hence, it was apparent that a high DS and a high concentration in an aqueous solution were favorable for high crosslinking of CMC. It is assumed that high radiation crosslinking of CMC was induced by the increased mobility of its molecules in water and by the formation of CMC radicals from the abstraction of H atoms from macromolecules in the intermediate products of water radiolysis. A preliminary biodegradation study confirmed that crosslinked CMC hydrogel can be digested by a cellulase enzyme. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 278–283, 2000     

Economic evaluation of independent power producers viewed from total generating costs of electric power systems

In Japan, electric power utilities purchase electricity from independent power producers (IPPs) through competitive bidding; the IPP evaluation is based on the avoided costs of corresponding generators of utilities. In this evaluation, however, nonpricing factors such as power flow constraints in the electric power system cannot be considered. In this paper, we propose a new approach to evaluate economic impacts of IPPs, the IPP electricity being priced on the basis of total generating costs of the electric power utilities. Such a price to purchase the electricity of IPPs is referred to as the “break‐even cost.” The main results are summarized as follows: 1) Break‐even cost depends on not only the power flow constraints in the system, but also various IPP factors such as generating pattern, location, and capacity, 2) Break‐even cost for the base‐type IPP is higher than the avoided cost of corresponding utility generators, because IPPs located on demand sides can reduce the transmission power loss in the electric power system, 3) Break‐even cost is affected by available capacity of utility generators, especially for the peak‐type IPP generating only during peak demand periods. © 2000 Scripta Technica, Electr Eng Jpn, 133(2): 20–30, 2000