Microprocessor-Based Universal Regulator Using Dual-Rate Sampling

Standard single-rate sampling self-tuning regulators may not be able to effectively control fast-acting systems if the minimum computation time required is larger than the largest sampling period permissible. A dual-rate sampling self-tuning regulator that overcomes this problem by allowing a data sampling rate to be chosen consistent with the system time constants and a control output interval based on the computation time is described in this paper. This algorithm is also very suitable for implementation using fixed word-length processors as the quantization problems are minimized. The algorithm has been implemented on a microprocessor. Implementation details with emphasis on data acquisition, interrupt controlled sampling, time sufficiency test and scaling, and experimental results are also given.     

Effect of free monomer content on the drawing behavior of poly(methyl methacrylate)

Cold drawing has been used to produce oriented samples of various molecular weight grades of poly(methyl methacrylate), all of which exhibited marked strain hardening characteristics over a range of drawing temperatures. The differences between the yield and drawing behavior of the grades did not correlate with molecular weight but could instead be attributed to the plasticizing effect of additional free monomer, generated by degradation during melt processing of the polymer.     

A model for the presence of polychlorinated biphenyls (PCBs) in the Willamette River Basin (Oregon)

The Willamette River drains a 32,000 km2 basin (Basin) in northwestern Oregon. Owing to their persistence and toxicity, polychlorinated biphenyls (PCBs) in resident fish within the Basin at levels above consumption advisory thresholds are a human and environmental health concern. This concern may trigger a Willamette River Total Maximum Daily Load (TMDL) for PCBs, at which time both their probable sources and the mechanism by which they came to be distributed throughout the Basin will be of considerable regulatory interest. Deposition within the Basin of some portion of global primary (1930-1980) and secondary (post-1980) emissions arriving via long-range advective transport in the atmosphere was posited as an explanation. This proposition was explored with a seasonally responsive, dynamic mass balance watershed-scale model that estimated concentrations of toxicologically relevant congeners (PCB-077, -118, -169) in various environmental media over a 90-year period, assuming advective inflow to the Basin's atmosphere to be the only PCB congener source. Model results suggest that rising air concentrations, and associated advective inflows, from increasing primary emissions between 1930 and 1975 (PCB-118 peak inflow, 1970, approximately equal to 11 kg y(-1)) and declining primary and secondary emissionsthereafter, could have yielded congener concentrations observed in air, soil, and fish between 1993 and 2003. The possibility that observed concentrations may be obtainable entirely with inputs from global legacy sources raises questions as to the efficacy of a TMDL directed primarily at local point or area sources. Better characterization of potential sources, and collection of additional soil and air data combined with more sophisticated modeling, appear to be necessary precursors to any PCB TMDL for the Willamette River.     

A study of the methylolation of phenol using gel permeation chromatography

Gel permeation chromatography (GPC) was used to investigate the course of the sodium hydroxide catalysed methylolation of phenol in dilute aqueous solution. At low concentrations, the initial rate of methylolation was directly proportional to the concentrations of sodium hydroxide and of formaldehyde. By computer integration of the rate equations for the methylolation of phenol, of 2-methylol phenol and of 4-methylol phenol, the experimental rate curves were simulated and optimal values for the rate constants of all the methylolation steps were obtained.     

Spontaneous emission from the C3 radical in carbon plasma

Spontaneous emission measurements are discussed for the Swings transitions of the C(3) radical in laser-generated graphite plasma, and the spectroscopy of the C(3) radical in carbon vapor and plasma is summarized. A review is given of some theoretical calculations and emission spectroscopic investigations are presented. Time-averaged, laser-induced optical breakdown spectra are reported from Nd:YAG laser generated graphite microplasma. In 200-300 Torr of argon and helium, and depending on the specific experimental configuration, a weak emission continuum is observed centered at 400 nm when using a laser fluence of typically 1 J/cm(2). Such continua were not detected in our previous experiments using focused laser radiation. The possibilities for the origin of this continuum are considered.