CuAlCl4 doped MIL-101 as a high capacity CO adsorbent with selectivity over N2

A CuAlCl₄ doped metal organic framework, CuAlCl₄@MIL-101, was prepared by introducing CuAlCl₄ into the pores of MIL-101 for the selective adsorption of CO over N₂. The CuAlCl₄ molecules were evenly distributed into various pores sizes and did not change the intrinsic structure of the MIL-101. Isotherms for CO and N₂ adsorption at 298 K showed that the CO capacity on CuAlCl₄@MIL-101 was much higher than that on virgin MIL-101, whereas the N₂ capacity decreased. The selectivity for CO over N₂ improved from 4.64 to 31.5 at 298 K and 1 bar. The CuAlCl₄@MIL-101 adsorbent displayed outstanding CO adsorption stability and the adsorbent could be regenerated by applying a simple vacuum of 4 mmHg.     

谈修辞手法在水景营造中的应用

结合园林水景多变的状态、多变的感官感受、多变的意境特征,对排比、通感、夸张、引用、比拟五种修辞手法在水景营造中的应用技巧进行了探讨,指出在水景的营造中适宜地运用修辞手法可使水景设计更加合理、动人,从而提高景观品质。     

涂料中可溶性Pb、Cr含量测定结果误差原因分析

研究并详细讨论了涂料样品制备与样品前处理过程中,各个因素对可溶性Pb、Cr含量测定结果的影响。结果表明:漆膜的厚度、粒径、提取液的酸度、温度等因素对结果的测定有较大的影响,应当对这些因素予以控制以提高实验室间结果一致性。     

Study on purification and application of novel precipitant for ceria-based polishing powder

Novel precipitant prepared through carbonation with MgCl2 wastewater generated from rare earth extraction separation process and low-price dolomite as raw materials was studied in this paper. The purification methods of novel precipitant by adding appropriate oxidizing agent were studied. It was found that optimal purification result could be achieved with sodium hypochlorite as iron removal reagent and the iron removal rate could reach up to 90% when the adding amount was 0.1 vol.%. During the preparation, the particle size and distribution of ceria-based polishing powder were affected obviously by the parameters such as concentration, reaction temperature and feeding rate. The results showed that ceria-based polishing powder with D50 =2.5-3.5 μm and the particle size distribution of 0.65-0.75 μm could be prepared when the concentration of CeCl3 was 0.6 mol/L, the reaction temperature was maintained at 50 °C and the feeding speed was controlled at 25 ml/min. Compared with commercial powder, the self-made polishing powder had roughly the same cutting amount, but the surface finish of polished glass was better than that of commercial polishing powder.     

Compressive sensing-based wind speed estimation for low-altitude wind-shear with airborne phased array radar

An important issue in low-altitude wind-shear detection is to estimate the wind speed of wind field. In this paper, a novel method for wind speed estimation with airborne phased array radar is proposed by combining space time adaptive processing and compressive sensing. The proposed method is able to achieve accurate wind speed estimate in the condition of limited number of sampling pulses, as demonstrated by numerical examples.     

Novel poly(3‐hydroxybutyrate) composite films containing bioactive glass nanoparticles for wound healing applications

Bioactive glass is considered an ideal material for haemostasis as it releases Ca²⁺ ions upon hydration, which is required to support thrombosis. In this study the effects of the presence of nanoscaled bioactive glass (n‐BG) in poly(3‐hydroxybutyrate) (P(3HB)) microsphere films on the structural properties, thermal properties and biocompatibility of the films were studied. The n‐BG with a high surface area was also tested for its in vitro haemostatic efficacy and was found to be able to successfully reduce clot detection time. In an effort to study the effect of the roughness induced by the formation of hydroxyapatite on cellular functions such as cell adhesion, cell mobility and cell differentiation, the composite films were immersed in simulated body fluid for periods of 1, 3 and 7 days. From scanning electron microscopy images, the surface of the P(3HB)/n‐BG composite microsphere films appeared fairly uniform and smooth on day 1; however on day 3 and day 7 a rough and uneven surface was observed. The presence of hydroxyapatite on the composite microsphere films on day 3 and day 7 influenced the surface roughness of the films. However, when the P(3HB)/n‐BG composite microsphere films with enhanced surface roughness were tested for biocompatibility, reduced amounts of protein adsorption and cell adhesion were observed. This study thus revealed that there is an optimal surface roughness for the P(3HB) microsphere films for increased cell adhesion, beyond which it could be deleterious for cell adhesion and differentiation. © 2016 Society of Chemical Industry     

Interactions among biomass components during co-pyrolysis in (macro)thermogravimetric analyzers

The interactions of biomass components (hemicellulose, cellulose, and lignin) during co-pyrolysis were investigated in a thermogravimetric analyzer (TGA) as well as a self-designed Macro-TGA with higher heating rate and larger amount of sample. The overlap ratio (OR) was used to evaluate the interaction of biomass components quantitatively. In TGA, the pyrolysis of xylan was not significantly affected by cellulose, whereas the pyrolysis of cellulose was markedly influenced by xylan. The interactions between xylan and lignin were weak with an overlap ratio of 0.9869, whereas co-pyrolysis of cellulose and lignin was strongly inhibited by interactions with the overlap ratio of 0.9737. In Macro-TGA, interactions between components were stronger than that in TGA due to more considerable heat and mass transfer effect.     

一起220kV电容式电流互感器爆炸事故的分析

介绍了爆炸事故的简要经过和设备概况,为分析事故的原因对互感器进行了解体检查,结合解体检查结果,分析互感器设计制造工艺中存在的问题,分析事故原因和事故发展过程,并提出几点建议和预控措施。     

基于RBF神经网络的FeO-MnO渣系ZGMn13堆焊焊条的设计

为设计一种ZGMn13堆焊焊条,提出了一种基于RBF神经网络的FeO-MnO渣系焊条配方优化设计方法.利用试验采集的数据对网络进行训练,以加工硬化后的硬度为优化目标,得到最优的焊条配方.试验结果表明:优化后熔敷金属的动载加工硬化性能和静载加工硬化性能良好.