Long-term aging of Ag/a-C:H:O nanocomposite coatings in air and in aqueous environment

Nanocomposite coatings of silver particles embedded in a plasma polymer matrix possess interesting properties depending on their microstructure. The film microstructure is affected among others also by the RF power supplied during the deposition, as shown by transmission electron microscopy. The optical properties are characterized by UV–vis–NIR spectroscopy. An anomalous optical absorption peak from the Ag nanoparticles is observed and related to the microstructure of the nanocomposite films. Furthermore, a long-term aging of the coatings is studied in-depth in ambient air and in aqueous environments. It is shown that the studied films are not entirely stable. The deposition conditions and the microstructure of the films affect the processes taking place during their aging in both environments.     

Crack propagation in layered Al<Subscript>2</Subscript>O<Subscript>3</Subscript>/ZrO<Subscript>2</Subscript> composites prepared by electrophoretic deposition

Crack propagation through layered Al₂O₃/ZrO₂ composites was studied. The specimens were prepared via electrophoretic deposition of alumina and zirconia powders from suspensions with monochloroacetic acid and isopropanol. The kinetics of electrophoretic deposition could be described fully if the electrophoretic mobility and conductivity of suspensions were known. The conductivity of suspensions increased in the course of deposition. Adjusting to properly controlled kinetics of deposition and sintering, deposits were prepared with strongly bonded layers of different pre-defined thicknesses and, consequently, with different magnitudes of residual stress. Cracks, produced by an indentation technique, propagated askew towards layer interfaces deflected towards the interface in the Al₂O₃ layers and away from the interface in the ZrO₂ layers. Changes in the direction of crack propagation were described for the whole range of angles of incidence (0°–90°). The biggest change in the crack propagation was observed for the angle of incidence 45° and was ca. 15°, irrespective of the magnitude of residual stress in the layers.     

Nanocomposites and nanostructures based on plasma polymers

Nanocomposite metal/plasma polymer films have been deposited since the seventies of the last century using sputtering or thermal evaporation of a metal simultaneously with a plasma polymerization process. The main attention was paid to fluorocarbon and hydrocarbon plasma polymers as matrices for the incorporation of metals such as Au and Ag. Main deposition techniques used for the fabrication of such nanocomposites are reviewed together with an overview of their basic optical and electrical properties, composition and structure. Proposed applications are mentioned as well. In addition, RF magnetron co-sputtering of a polymer such as polytetrafluoroethylene, is also mentioned. Nanostructuring of a fluorocarbon plasma polymer by changing deposition parameters including deposition system geometry is revealed and the application in terms of superhydrophobic coating is mentioned. Cluster sources, namely the gas aggregation (condensation) cluster source (GAS) based on a planar magnetron in a compact and simple form is described and its performance for the preparation of nanocomposite and nanostructured metal/plasma polymer films is discussed.     

Time-domain terahertz study of defect formation in one-dimensional photonic crystals

One-dimensional photonic crystals composed of silicon and air layers with and without twinning defect (i.e., a periodicity break where one half of the photonic structure is a mirror image of the other one) are studied by means of terahertz time-domain transmission and reflection spectroscopy. The structure with defect is decomposed into building blocks: two twins and a defect. A phase-sensitive characterization in transmission and reflection allows us to fully determine the transfer matrices of any block and consequently to predict the properties of composed structures regardless of the microstructure of the constituting blocks. It is shown and experimentally demonstrated that the defect level position is controlled by the reflectance phase of the twins. Possible approach of the reflectance phase determination by use of Kramers-Kronig analysis is also discussed.     

Digital holography using a digital photo-camera

The possibilities of running digital holography using commonly available digital zoom photo-cameras are studied. A new modified method of the holographic set-up exploiting the properties of a photo-camera is suggested. This method offers a straightforward and simple way of both digital hologram recording and reconstructing. In order to verify the feasibility of the method, the holograms acquired are digitally reconstructed using a computer code based on the fast Fourier transform algorithm. Experimental results obtained are presented and discussed.     

Magnetically induced behaviour of ferritin corpuscles in avian ears: can cuticulosomes function as magnetosomes?

Magnetoreception is an enigmatic, poorly understood sensory ability, described mainly on the basis of behavioural studies in animals of diverse taxa. Recently, corpuscles containing superparamagnetic iron-storage protein ferritin were found in the inner ear hair cells of birds, a predominantly single ferritin corpuscle per cell. It was suggested that these corpuscles might represent magnetosomes and function as magnetosensors. Here we determine ferritin low-field paramagnetic susceptibility to estimate its magnetically induced intracellular behaviour. Physical simulations show that ferritin corpuscles cannot be deformed or rotate in weak geomagnetic fields, and thus cannot provide magnetoreception via deformation of the cuticular plate. Furthermore, we reached an alternative hypothesis that ferritin corpuscle in avian ears may function as an intracellular electromagnetic oscillator. Such an oscillator would generate additional cellular electric potential related to normal cell conditions. Though the phenomenon seems to be weak, this effect deserves further analyses.     

Searching for Major Urinary Proteins (MUPs) as Chemosignals in Urine of Subterranean Rodents

Chemosensory information mediates behavior in many rodent genera. Major Urinary Proteins (MUPs) facilitate chemical communication in some species of mice. We sought to demonstrate the importance of MUPs in chemosignaling across a range of rodent genera that live in different habitats and social structures. We analyzed urine from three subterranean rodent genera from different continents, and with diverse social systems: eusocial Zambian mole-rats (Fukomys), solitary Israeli blind mole rats (Spalax), and social Chilean coruros (Spalacopus). 2D gel electrophoresis revealed low levels of protein, with sequences similar to aphrodisin, in Fukomys mole-rat urine, but no MUPs in urine of any of the studied species. Previous research demonstrated that subjects from the tested genera responded differentially to odors indicating transmission of individuality, family/colony or population, species, and reproductive state in secretions and excretions of conspecifics. This extends, to subterranean rodents, the evidence that rodent species can successfully transmit and receive chemosignals without the necessity of MUPs.     

Deposition of Al nanoparticles and their nanocomposites using a gas aggregation cluster source

The study describes the preparation and properties of Al/Al _x O _y nanoparticles and their nanocomposites with hydrocarbon plasma polymer. The nanoparticles were deposited using a simple gas aggregation cluster source based on a planar magnetron. The influence of deposition parameters on size distribution was studied. It was found that Al nanoparticles may be deposited with mean diameter ranging from 30 to 60 nm by varying magnetron current from 0.4 to 0.2 A. Attention was also paid to the investigation of the charge of the nanoparticles. It is shown that a large portion of Al _x O _y nanoparticles leave the gas aggregation source as negatively charged. The nanoparticles were also embedded into the plasma polymer matrix by their simultaneous co-deposition with plasma-polymerized n-hexane. Morphology and chemical composition of such fabricated nanocomposites were determined. It was shown that Al _x O _y nanoparticles embedded into the polymeric matrix exhibit localized surface plasmon resonances in the deep ultraviolet region of the electromagnetic spectrum and the position of the plasmon peak is strongly correlated with nanoparticle size.     

Flow method for study of gas transport in polymers. Application to the study of oxygen,nitrogen, and carbon dioxide permeation through cellulose acetate membranes

Transient permeation of oxygen, nitrogen, and carbon dioxide through certain cellulose acetate (CA) dense membrances made from solutions in dioxane and dioxane-added ethanol were studied by the flow method. In order to explain the overshoots for transient permeation rates in the latter case, a new model is proposed. It postulates a time-dependence solubility coefficient, in the form of a series of exponential terms, which is combined in Fick's second law and solved. The model fits well the obtained permeation kinetics, leading to values of the diffusion, and permeation coefficients, and the structure change-related time. The overshoots are explained by the formation of unstable structure from dioxane-ethanol solvent mixtures, a memory effect of aggregated chains, which undergoes consolidation upon gas penetration. The stable state which results from the consolidation process is the same as that of membrances obtained from pure dioxane solutions. © 1994 John Wiley & Sons, Inc.