Secondary Aluminum Production Waste — A Raw Material for the Refractory Industry

Secondary aluminum waste products, and processes that occur during heating and mineral formation on introducing fine periclase powder into the composition of waste products are studied. It is demonstrated that secondary aluminum production waste may be used as a raw material for synthesizing aluminomagnesia spinels. Translated from Novye Ogneupory, No. 6, pp. 15–18, June 2008.     

Influence of the preparation conditions on the size and morphology of nanocrystalline lanthanum orthoferrite

Nanocrystalline LaFeO₃ is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO₃ nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.     

Optimizing the selective flocculation of coal by means of a selective reagent

The need to improve coal enrichment stems from the sharp deterioration in the coal being enriched (increasing ash and moisture content, content of small classes, rock content, etc.), which results from the widespread mechanization of mining operations, the development of high-ash deposits, and dust suppression [1].     

Testing a new composition of periclase spinel objects

On the basis of periclase powder (70%) and aluminomagnesia spinel (30%), synthesized from secondary aluminum production waste and caustic magnesite, test objects are produced of periclase spinel composition satisfying the requirements of GOST 1579-006-00190495-98. The articles are successfully tested in the working layer for lining tunnel furnace cars of OAO Kombinat Magnezit. __________ Translated from Novye Ogneupory, No. 8, pp. 16–17, August 2008.     

Heating furnace monolithic refractory lining

Contemporary solutions are presented for completion of a monolithic refractory lining for a heating furnace using products produced by OOO Keralit. __________ Translated from Novye Ogneupory, No. 3, pp. 80–83, March 2008.     

Formation of the complex oxide NaNdTiO<Subscript>4</Subscript>

The processes of phase formation in the Na₂CO₃-TiO₂ and Na₂CO₃-TiO₂-Nd₂O₃ systems are investigated in the temperature range 600–900°C. The high-temperature solid-phase reactions underlying the process of formation of complex oxide NaNdTiO4 are studied. It is established that the synthesis of the NaNdTiO₄ compound occurs through the reaction of the intermediate product Na₈Ti₅O₁₄ with neodymium oxide in the temperature range 720–780°C. The optimum method is proposed for synthesizing NaNdTiO₄, which makes it possible to reduce the temperature of the synthesis, to avoid the formation of impurities, and to obtain the product in a finely dispersed state.     

Synthesis of nanocrystalline solid solutions based on zirconia and hafnia

Nanosized (2–8 nm) amorphous powders of the solid solution based on zirconia and hafnia are synthesized through back coprecipitation upon treatment of gels at temperatures from +20 to −77°C. Heat treatment of these powders at temperatures up to 1000 and above 1100°C leads to the formation of cubic (fluorite type, O _h ⁵ = Fm3m) and tetragonal phases of the Zr₈₂Hf₁₀Y₃Ce₅O _x composition, respectively. It is revealed that a decrease in the synthesis temperature (from +20°C to −6°C) results in a decrease in the size of gel agglomerates from 30 to 1 μm. Recrystallization processes in the gels prepared using cryochemical treatment are developed very slowly in the temperature range 500–1200°C (the crystallite size does not exceed 25 nm). Original Russian Text ? T.I. Panova, V.B. Glushkova, A.E. Lapshin, 2008, published in Fizika i Khimiya Stekla.     

Aggregate stability of ZrO2 aqueous sols in electrolyte solutions

The aggregate stability of submicron and nanosized ZrO₂ aqueous sols of different origins and different dispersities at pH 3–10 in the KCl concentration range 10^?3–10^?1 M is investigated by flow ultramicroscopy and photometry. The results obtained are analyzed in the framework of the extended Derjaguin-Landau-Verwey-Overbeek theory and the Muller-Martynov theory of reversible aggregation. The extension of boundary layers of water near the surface of the ZrO₂ particles is estimated.