X-ray topography studies of dislocations in single crystal CVD diamond

X-ray topography has been used to study single crystal diamond samples homoepitaxially grown by microwave plasma-assisted chemical vapour deposition (CVD) on high pressure high temperature (HPHT) and CVD synthetic diamond substrates. Clusters of dislocations in the CVD diamond layers emanated from points at or near the interface with the substrate. The Burgers vectors of observed dislocations have been determined from sets of {111} projection topographs. Dislocations have line directions close to the [001] growth direction and are either edge or 45° mixed dislocations. Where groups of dislocations originated at isolated points they tended to be of the edge variety. Where the substrate surface was deliberately damaged before growth, two sets of dislocations were observed to have propagated from each line of damage and there was a tendency for dislocations to be of the 45° mixed variety with a component of their Burgers vector parallel to the polishing direction. It is demonstrated that X-ray topography can be used to deduce the growth history of CVD synthetic diamond samples produced in multiple growth stages.     

An efficient electron-beam-pumped semiconductor laser for the green spectral range based on II–VI multilayer nanostructures

Emission characteristics of an electron-beam-pumped Cd(Zn)Se/ZnMgSSe semiconductor laser are studied. The laser’s active region consists of a set of ten equidistant ZnSe quantum wells containing fractional-monolayer CdSe quantum-dot inserts and a waveguide formed by a short-period superlattice with the net thickness of ～0.65 μm. Lasing occurs at room temperature at a wavelength of 542 nm. Pulsed power as high as 12 W per cavity face and an unprecedentedly high efficiency of ～8.5% are attained for the electron-beam energy of 23 keV.     

Total classes of composition systems of discrete signals in isomorphous Galois fields

It is proposed a rule of total classes of composition systems of discrete frequency signals (CDF-signals) construction in extended Galois fields. It is carried out modeling and research a correlation properties of CDF-signals, and determined their practical attraction.     

An Experimental Investigation into the Feed Rate Capacity of Rotary Valve and Blow Tank Feeders

Industry widely uses rotary valves and blow tanks for the pneumatic conveying of products, each having their pros and cons depending on the specific application. This article shows the differing results obtained when low-velocity conveying a product through a common pipeline using both a drop-through rotary valve and a bottom-discharge blow tank feeder. A number of issues arise in the rotary valve system, the main one being rotary valve air leakage. A blow tank system, on the other hand, does not leak, as it is an enclosed system. The experimental results show dramatic differences in product throughput. Further exploration leads to a novel modification being made to the rotary valve system in an attempt to increase its capacity. The result of this modification shows a slight increase in output tonnage, but still significantly less than that obtained from the blow tank.     

A prototype of a superconducting magnet for a 170-GHz gyrotron

Within the framework of the “International Thermonuclear Experimental Reactor” (ITER) program, a prototype of a superconducting magnet for a 170-GHz gyrotron has been developed, manufactured, and tested. The operating induction value (7.1 T at the center of a 219-mm-diameter cold hole and 8.1 T on the winding) is reached at a current of 185.2 A. In the final version of the magnet, the required induction value was reached without aging. Special requirements are imposed on the distribution of the magnetic field along the axis, including an abrupt field decrease on both sides of the magnet. Axial forces are additionally taken by a special device. The magnet’s sections are wound with multifiber conductors based on niobium-tin and niobium-titanium alloys. Seventeen resistive shunts are provided for protecting sections during their transition to the normal state. The magnet is equipped with a device for removing a part of energy from the sections. Mechanical stresses in the magnet’s sections and the structure’s power elements have been measured during tests.     

A device for measuring the equivalent resistance of an energized circuit section

A device for measuring the active resistance of a direct current energized circuit section is described. Owing to the use of up-to-date electronic components, an iteration measurement algorithm, and a sinusoidal signal as a test one, the following performance characteristics have been obtained: the measurement time is <1 s, and the error varies from 0.3 to 2.0% in a 100-Ω to 1-MΩ range and ≤25% in 10-to 100-Ω and 1-to 10-MΩ ranges.     

Effect of ultrasonic treatment on photoelectric and luminescent properties of ZnSe crystals

The results of the effect of ultrasonic treatment of ZnSe crystals on the structure of the energy spectrum of electronic states of centers with deep levels forming photoelectric and luminescent properties of this compound are presented. It is for the first time proved experimentally that the climb of edge dislocations under the effect of ultrasound leads to regrouping and generation of defects forming deep levels, which manifest themselves in phenomena of photosensitivity and radiative recombination.     

Xylene Isomerization in a ZSM-5/SS Membrane Reactor

A membrane reactor containing different types of ZSM-5/porous SS membranes was used to perform the xylene isomerization reaction. The parent Na-ZSM-5 layer was synthesized by secondary growth on top of porous stainless steel tubes. The xylene isomerization reaction was carried out at different temperatures in the membrane reactor and in a fixed-bed reactor of identical geometry for comparison. Two different kinds of membranes were prepared by ion exchange: a Pt/H-ZSM-5 catalytic membrane and two Ba-ZSM-5 composites with different Ba²⁺ concentration. The p-xylene production using 100% exchanged Ba-membrane was about 28% higher than the fixed-bed reactor at 370 °C, when m-xylene was fed.     

Electrophoretic deposition of electrolyte materials for solid oxide fuel cells

Electrophoretic deposition of electrolyte materials for solid oxide fuel cells, including La_0.8Sr_0.2Ga_0.875Mg_0.125O_3–x , yttria stabilized zirconia and (Ce_0.8Gd_0.2)O_1.9, was studied under various experimental conditions. The use of phosphate ester as a dispersant and poly (vinyl butyral) as a binder enabled high deposition rate and formation of crack-free, adherent deposits. Electrodeposition rates were quantified in experiments performed at constant current and constant voltage modes from suspensions in ethanol, isopropanol and mixed ethanol—isopropanol solvents. The microstructure of as prepared and sintered deposits was studied by electron microscopy. The bath composition was optimized to enable formation of dense deposits.