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In this paper we review a recently developed finite-difference time-domain (FDTD) iterative technique for the analysis of periodic structures at oblique incidence. We show how it can be implemented in FDTD code and estimate required computer memory and time resources. To illustrate performance of our technique we demonstrate the plasmon formation in a thin gold film placed at air/glass interface and calculate reflectance from silicon textured coating at oblique incidence. 相似文献
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IL Kim Jong-Seok Kim Oh-Seung Kwon Sung-Tae Ahn John S. Chun Won-Jong Lee 《Journal of Electronic Materials》1995,24(10):1435-1441
The tantalum oxide thin films with a thickness of 14 nm were deposited at 95°C by electron cyclotron resonance plasma enhanced
chemical vapor deposition (ECRPECVD), and annealed at various temperatures (700∼850°C) in O2 and N2 ambients. The microstructure and composition of the tantalum oxide thin films and the growth of interfacial silicon oxide
layer were investigated and were related to the electrical characteristics of the film. Annealing in an O2 ambient led to a high dielectric constant (εr(Ta2O5) = 24) as well as a small leakage current (Ebd = 2.3 MV/cm), which were due to the improved stoichiometry and the decreased impurity carbon content. Annealing in an N2 ambient resulted in poor and nonuniform leakage current characteristics. The as-deposited tantalum oxide films were crystallized
into δ-Ta2O5 after annealing at above 750°C regardless of the ambient. The leakage current of the film abruptly increased after annealing
at 850°C probably because of the stress caused by thermal expansion or contraction. 相似文献
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It is commonly assumed that essentially all of the water in cells has the same ideal motional and colligative properties as does water in bulk liquid state. This assumption is used in studies of volume regulation, transmembrane movement of solutes and electrical potentials, solute and solution motion, solute solubility and other phenomena. To get at the extent and the source of non-ideally behaved water (an operational term dependent on the measurement method), we studied the motional and colligative properties of water in cells, in solutions of amino acids and glycine peptides whose surface characteristics are known, and in solution of bovine serum albumin, hemoglobin and some synthetic polypeptides. Solutions of individual amino acids with progressively larger hydrophobic side chains showed one perturbed water molecule (structured-slowed in motion) per nine square angstroms of hydrophobic surface area. Water molecules adjacent to hydrophobic surfaces form pentagonal structural arrays, as shown by X-ray diffraction studies, that are reported to be disrupted by heat, electric field, hydrostatic pressure and phosphorylation state. Hydrophilic amino acids demonstrated water destructuring (increased motion) that was attributed to dielectric realignment of dipolar water molecules in the electric field between charge groups. In solutions of proteins, several methods indicate the equivalent of 2-8 layers of structured water molecules extending beyond the protein surface, and we have recently demonstrated that induced protein conformational change modifies the extent of non-ideally behaved water. Water self-diffusion rate as measured in three different cell types was about half that of bulk water, indicating that most of the water in these cells was slower in motion than bulk water. In different cell types the extent of osmotically perturbed water ranged from less that half to almost all of the intracellular water. The assumption that essentially all intracellular water has ideal osmotic and motional behavior is not supported by the experimental findings. The non-ideally of cell water is an operational term. Therefore, the amount of non-ideally behaving water is dependent on the characteristics of water targeted, i.e. the measurement method, and a large fraction of it is explainable in mechanistic terms at a molecular level based on solute-solvent interactions. 相似文献
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IL Cameron WE Hardman GD Fullerton A Miseta T Koszegi A Ludany M Kellermayer 《Canadian Metallurgical Quarterly》1996,20(2):127-137
The proportional odds model is illustrated in the analysis of two efficacy scales used in a phase II clinical trial involving 81 schizophrenic patients. The proportional odds model preserves the discrete, ordinal nature of one of the scales. The analysis of this data suggested that the relationship between the two scales is not captured by a linear proportional odds model. A linear model and a piecewise linear model for the explanatory variable were therefore compared using likelihood-based analyses. Residuals from both models were compared. Predicted probabilities for the ordinal categories were constructed from the estimated model. Extensions and limitations of the model for interpretation of other trials and for the planning of future trials are discussed. 相似文献
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