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101.
Fatma Nur Arslan Huseyin Kara Hamide Filiz Ayyildiz Mustafa Topkafa Ismail Tarhan Adnan Kenar 《Journal of the American Oil Chemists' Society》2013,90(8):1179-1193
The main goal of the present study was (i) to determine the formation of degradation products in cottonseed oil (CSO) blends during deep frying process by adsorption and high performance size exclusion chromatography techniques and (ii) to evaluate the impacts of food additives on total polar (TPC) and polymeric compound (PTAG) formation using a chemometric approach. In order to prepare the frying CSO blends; ascorbic palmitate, mixed tocopherols, dimethylpolysiloxane, lecithin and sesame oils were used as additives. To determine the real impacts of additives, a quarter-fraction factorial experimental design with two levels and five factors was used. The changes in TPC and PTAG data were carefully evaluated during 10 h of frying at 170 ± 5 °C with normal distribution (ND) graphs and analyzed using a one-way analysis of variance (ANOVA), followed by Tukey’s Post-hoc test (α = 0.05). The results indicated that the increasing values for TPC and PTAG during the frying processes for all blends, TPC and PTAG contents reached maximum levels of 16.37 and 6.01 % respectively, which are below the limit values stated by official authorities for the quality assessment of frying oils. The ANOVA test results were in good agreement with ND graphs and data indicated that the impact of mixed tocopherols was significant for TPC formation, meanwhile the impact of lecithin and ascorbic palmitate × dimethylpolysiloxane were significant for PTAG formation. Thus, the present study should be considered to be a very useful guide for developing new frying oil formulations based on CSO by using food additives. 相似文献
102.
This study focused on the degradation of hydrolysed Remazol Black B (CI Reactive Black 5), a common diazo reactive dye, in aqueous solution. In the presence of various dye auxiliary chemicals a typical Remazol Black exhausted dyebath liquor simulated, which was then treated with homogeneous [ozonation with hydroxy ions, and Fe(II) or Fe(III) with hydrogen peroxide] and heterogeneous (titanium dioxide with UV-A irradiation) advanced oxidation processes. Treatment performance of the investigated advanced oxidation systems was comparatively assessed in terms of the environmental sum parameters total organic carbon, biochemical oxygen demand and spectrophotometric measurements. The results obtained clearly reveal that the investigated advanced oxidation processes are capable of completely decolourising and partially mineralising the dye solution and its simulated dyebath effluent under predetermined reaction conditions. During the application of alkaline ozonation at an ozone dose of 2340 mg/ml, a three-fold biodegradability enhancement was observed. 相似文献
103.
Both IS-136 and PDC digital cellular systems employ forward error correction (FEC) encoding followed by a form of DQPSK modulation. In this letter, we derive the maximum a posteriori (MAP) bit detector for DQPSK modulation in non-ISI channels for a coherent receiver with one or more antennas. The MAP detector forms a bit log-likelihood ratio, which provides the optimal “soft information” for MLSE or MAP convolutional decoding. MAP detection requires exponentiation and logarithm operations, as well as knowledge of the noise covariance. To avoid these operations, two approximate forms are developed, which do not require the noise covariance value under certain assumptions. Both approximate approaches, when used with soft FEC decoding, are within 0.5 dB of the optimal approach 相似文献
104.
The behavior of granular materials mainly depends on the mechanical and engineering properties of particles in its structural
matrix. Crushing or breakage of granular materials under compression or shear occurs when the energy available is sufficient
to overcome the resistance of the material. Relatively little systematic research has been conducted regarding how to evaluate
or quantify particle crushing and how it effects the engineering properties of the granular materials. The aim of this study
is to investigate the effect of crushing on the bulk behavior of granular materials by using manufactured granular materials
(MGM) rather than using a naturally occurring cohesionless granular material. MGM allow changing only one particle parameter,
namely the “crushing strength”. Four different categories of MGM (with different crushing strength) are used to study the
effect on the bulk shear strength, stiffness modulus, friction and dilatancy angle “engineering properties”. A substantial
influence on the stress–strain behavior and engineering properties of granular materials is observed. Higher confining stress
causes some non-uniformity (strong variations/jumps) in volumetric strain and a constant volumetric strain is not always observed
under large shear deformations due to crushing, i.e. there is no critical state with flow regime (with constant volumetric
strain). 相似文献
105.
In this study, a new reactively fibrous adsorbent was prepared by grafting 4-vinly pyridine (4-VP) and 2-hydroxyethylmethacrylate (HEMA) monomer mixture onto poly(ethylene terephthalate) (PET) fibers for removal of Cr(VI), Cu(II) and Cd(II) metal ions from aqueous solution by using batch adsorption method. The influence of various parameters such as graft yield (GY), pH, adsorption time, initial ion concentration and adsorption temperature was investigated. The selectivity of the reactive fiber was also examined. The results show that the adsorbed amount of metal ions followed as given in the order Cr(VI) > Cd(II) > Cu(II). At pH 3, Cr(VI) was removed by 99% while the initial concentration of ions was at 5 mg L−1 and by 94% at 400 mg L−1. It was found that the grafted fiber is more selective for Cr(VI) ions in the mixed solution of Cr(VI)–Cu(II), Cr(VI)–Cd(II) and Cr(VI)–Cu(II)–Cd(II) at pH 3 and it was observed that the grafted fibers are stable and regenerable by acid and base without losing their activity. 相似文献
106.
Mohammed Saleh Zeynep Bilici Merve Kaya Mutlu Yalvac Hudaverdi Arslan H. Cengiz Yatmaz Nadir Dizge 《Advanced Powder Technology》2021,32(4):1264-1275
The use of naturally present heterogeneous catalysts has recently been an essential issue in the Fenton and photo-Fenton processes. In this study, the uses of basalt as a catalyst for the Fenton and photo-Fenton reactions for methylene Blue (MB) and Basic Red 18 (BR18) degradations were investigated. Basalt was selected because of the presence of the iron (III) oxide in the structure. Basalt was characterized by X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) analysis to obtain the chemical composition and the crystalline phase. The surface charge and the surface area were obtained by zeta potential and Brunauer Emmett-Teller (BET) analysis. Fourier Transform Infrared Spectroscopy (FTIR) and scanning electron microscope (SEM) were utilized to explore the functional group and the surface morphology. Fenton and photo-Fenton processes were applied to explore the best degradation method. Adsorption was also tested and the adsorption process had minimum removal efficiency (12% for MB and 17% for BR18). The removal efficiencies for MB and BR18 by the Fenton process were 87% and 28%, respectively. The photo-Fenton process had maximum removal efficiency with 100% for MB and 70% for BR18. The optimum conditions were 70 mg/L dye concentration, 5 mM H2O2, 1.0 g/L basalt loading and pH 2. Basalt has shown reuse capability as a catalyst for three consecutive cycles. 相似文献
107.
Nihan Kaya Ferhat Arslan Zeynep Yildiz Uzun 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(10):769-780
AbstractIn this study, hazelnut shell and walnut shell which are the agricultural wastes existent abundantly in many countries were pyrolyzed at different temperatures in the temperature range of 400–700?°C in order to optimize the physicochemical properties of biochars. The biochars with large surface area were used to removal of lead (Pb2+) ions, one of the most important heavy metal pollutant, from aqueous solutions. The characterization of raw biomass and also biochars produced by pyrolysis were performed using FT-IR, BET, SEM, partial and elemental analysis techniques. In order to determine the adsorption characteristics of both biochars, batch adsorption experiments were carried out under different experimental conditions. The optimum conditions were determined by investigating the effect of adsorption parameters (initial heavy metal concentration, temperature, adsorbent amount, pH, contact time and mixing speed) for efficient removal of Pb2+ ions from aqueous solution. The experimental results were investigated in terms of Langmuir, Freundlich and Temkin isotherm models. Together with the calculated thermodynamic parameters, the adsorption mechanism was tried to be explained. In order to determine the kinetic model of the adsorption process, the experimental data were applied to pseudo first-order, pseudo second-order and intra-particle diffusion model, and the model constants were investigated. 相似文献
108.
Abdul Qayoom Mugheri Aijaz Ali Otho Arslan Ahmed Mugheri 《International Journal of Hydrogen Energy》2021,46(44):22707-22718
Hydrogen is zero-emission fuel production for a clean environment as alternative effective the energy source is still moreover, an effective challenge in near future due to the lack of efficient and inexpensive catalysts. An efficient electrocatalysts structure having logical design which holds a paramount significance for the hydrogen evolution reaction (HER) but rarely noble metal Pt-like activity achieved by the transition metal oxides electrocatalysts based on oxides matured and cooperative with coupling metal oxides could be considered as a desired substitute electrocatalysts to change Pt/C based nano composite materials. Herein, un-noble the metal oxides of hetero structure consisting of Co3O4/MoS2 based-electrocatalysts nanocomposite material. The desirable out-comes show that Co3O4/MoS2 composite material providing extraordinary efficient HER kinetics activity in different experimental designs. The Co3O4/MoS2 based electro-catalyst increases the best activity of HER kinetics performance especially measured in 1 M KOH solution condition and offers an influential interfacing engineering strategy at very minute over potential of 348 mV evaluated and small Tafel slopes 46 mV/dec for HER performance. This work elucidates interest for efficient electrocatalysts for a broader range of scalable applications in the development of renewable energies, the functional materials such as solar cells, lithium sulphur-batteries and energy chemistry advancing. 相似文献
109.
110.