Recycled Polyolefin Blends: Effect of Modified Natural Zeolite on their Properties and Morphology

The purpose of this study is to investigate the effect of treated natural zeolite on the flow behavior, morphology, thermal, and mechanical properties in recycled polyolefin blends. A model polymer blend consisting of 95 wt% polyolefines and 5 wt% polystyrene was studied. Compositions from this recycled blend and dehydrated zeolite in a narrow concentration range (0–5 wt%) were treated with maleic anhydride-grafted polypropylene and initiator dicumyl peroxide. The compositions were characterized by capillary rheometry, wide-angle X-ray scattering, differential scanning calorimetry, scanning electron microscopy, and mechanical tests. The results show a compatibilizing effect of treated zeolite expressed by increase of shear viscosity and improvement of interfacial interactions and impact strength. The results can open wide possibilities for utilization of treated zeolite in recycling of unsorted polymer wastes.     

Effect of Acute Sprint Exercise on Myokines and Food Intake Hormones in Young Healthy Men

Physical exercise is known to influence hormonal mediators of appetite, but the effect of short-term maximal intensity exercise on plasma levels of appetite hormones and cytokines has been little studied. We investigated the effect of a 30 s Wingate Test, followed by a postprandial period, on appetite sensations, food intake, and appetite hormones. Twenty-six physically active young males rated their subjective feelings of hunger, prospective food consumption, and fatigue on visual analogue scales at baseline, after exercise was completed, and during the postprandial period. Blood samples were obtained for the measurement of nesfatin-1, ghrelin, leptin, insulin, pancreatic polypeptide (PP), human growth factor (hGH) and cytokine interleukin-6 (IL-6), irisin and plasma lactate concentrations, at 30 min before exercise, immediately (210 s) after exercise, and 30 min following a meal and at corresponding times in control sedentary males without ad libitum meal intake, respectively. Appetite perceptions and food intake were decreased in response to exercise. Plasma levels of irisin, IL-6, lactate, nesfatin-1 and ghrelin was increased after exercise and then it was returned to postprandial/control period in both groups. A significant rise in plasma insulin, hGH and PP levels after exercise was observed while meal intake potentiated this response. In conclusion, an acute short-term fatiguing exercise can transiently suppress hunger sensations and food intake in humans. We postulate that this physiological response involves exercise-induced alterations in plasma hormones and the release of myokines such as irisin and IL-6, and supports the notion of existence of the skeletal muscle–brain–gut axis. Nevertheless, the detailed relationship between acute exercise releasing myokines, appetite sensations and impairment of this axis leading to several diseases should be further examined.     

Cytotoxicity of new Ho(III) and Pr(III) complexes

New complexes of coumarin-3-carboxylic acid (HCCA) with Ho(III) and Pr(III) were synthesized and their structures and spectral properties were investigated by elemental analysis, IR, Raman and NMR measurements. According to the experimental data the complexes' formula and geometries were suggested. Vibrational frequencies, IR intensities and Raman activities as well as ¹H NMR chemical shifts of HCCA and its Ho(III) and Pr(III) complexes were presented. The comparative experimental vibrational and NMR analyses of both the ligand and the Ln(III) complexes predicted the bidentate binding to Ho(III) and Pr(III) through the deprotonated carboxylic oxygen and the carbonylic oxygen of the ligand. The cytotoxic/cytostatic properties of the ligand and the newly synthesized complexes of coumarin-3-carboxylic acid with Ho(III) and Pr(III) were tested by MTT reduction assay against two mouse tumor cell lines: melanoma B16 and fibrosarcoma L929. They were also tested for cytotoxicity against normal mouse peritoneal macrophages. The proliferation inhibitory effect of the complexes compared to that of the ligand proved their cytotoxic/cytostatic properties against both the tumor cell lines. In addition, the complexes were less cytotoxic against normal mouse macrophages and were able to modulate NO release by activated macrophages. The obtained results were in accordance with our previously published data concerning the activity of lanthanide(III) complexes with other coumarin derivatives.     

Sandwiches and milk with varying fat and sodium contents: What is the best combination?

Saltiness and fattiness were systematically varied in combinations of wheat bread (unsalted vs regular-salt), spread (none vs regular-salt and regular-fat), cheese (low-salt and low-fat vs low-fat). All possible combinations, amounting to sixteen samples of sandwich and milk, were presented to 43 subjects for ratings of pleasantness. The subjects also rated the pleasantness of individual components. The unsalted bread without spread but with low-salt, low-fat cheese and any of the milk types received the lowest hedonic ratings, whereas the regular-salt bread with spread and with any of the cheese and milk options received the highest. The pleasantness of individual components predicted the pleasantness of a combination by only 10–40% (multiple regression analysis). Thus the pleasantness of an entity depended on the pleasantness of components only to a very limited extent. The absence of major elements, such as spread on bread or the salty taste in bread, had major effects on acceptance.     

First dc Measurements of Electrons on Liquid Helium: the Helium-FET

We present the first dc-measurements on a 2-dimensional (2D) electron system floating above a liquid ⁴ He-film which covers a structured metal surface. With our arrangement of a source-, gate-, and drain-electrode a 2-dimensional charge transport is realized in analogy to a field-effect-transistor. The electrons which are moving along the x-direction due to different dc potentials are directly measured. This dc current, of the order of pA, is strongly dependent on the applied split-gate voltage. So the electrons were laterally confined to a narrow channel between the two gate electrodes. The effective width of the channel is reduced by the gate potential, so that a quasi-1D configuration can be realized. The measured electron current through the split-gate is analyzed and discussed on grounds of reduced dimensionality and 1D electron transport behaviour.     

Evaluation of functional properties of offal proteins

Evaluation of functional properties of beef heart and lip tissue proteins was based on the data obtained in the following determinations: protein extractability, fat emulsifying capacity, emulsion stability, gel forming ability, and water holding capacity after heat treatment. Beef skeletal muscles were used as the control. It was found that extractability of proteins of the raw materials was low as well as their ability to stabilize emulsions was on a low level. Proteins soluble at high ionic strength (fraction HIS) of beef heart and lip tissue emulsified 80.7 ml and 68.9 ml of oil/100 mg of protein, respectively, as compared to 106.6 ml in the control group. Analogically, protein soluble at low ionic strength (fraction LIS) emulsified 77.9 ml, 61.2 ml and 100.4 ml of oil, respectively. Emulsion stability of offal proteins appeared to be dependent on ionic strength. Generally at higher concentrations of salt their ability to stabilize emulsions was better as well as their water holding capacity increased. Their gelation properties as compared to control were also low. In each case, the functionality of cardiac proteins proved to be better than that of beef lip tissue.     

The structure and electro‐mechanical properties of novel hybrid CNT/PANI nanocomposites

Electrically conductive elastomeric nanocomposites containing carbon nanotubes (CNT) and polyaniline (PANI) are reported in the present investigation. The synthesis procedure included an in situ inverse emulsion polymerization of aniline doped with dodecylbenzene sulfonic acid (DBSA) in the presence of CNT and dissolved styrene‐isoprene‐styrene (SIS) block copolymer. The PANI synthesis step was carried out by applying ultrasonic energy. The dispersions obtained were processed by two methods: a recently developed precipitation‐filtration procedure, and a conventional drop‐cast procedure. The techniques developed resulted in homogeneous exfoliated PANI coated nanotubes within the elastomeric matrix. The presence of CNT/PANI in the SIS elastomeric matrix affects thermal, mechanical, and electrical properties of the nanocomposites. The formation of continuous three‐dimensional CNT/PANI networks prepared via the precipitation‐filtration method enhances the nanocomposite properties. Contrarily, the intermittent three‐dimensional network prepared by conventional drop‐cast method leads to inferior properties. Nanocomposites produced by both techniques are observed by HRSEM. The two processing techniques result in different structures, which affect the physical properties of the materials produced. A relatively low percolation threshold for both methods was determined. The Young's modulus of the SIS/CNT/PANI significantly increased in the presence of CNT. The precipitation‐filtration technique yields an improved nanocomposite product compared to the drop‐cast route. POLYM. COMPOS., 35:788–794, 2014. © 2013 Society of Plastics Engineers     

Phenol content,antioxidant activity and metal composition of Croatian wines deriving from organically and conventionally grown grapes

The present study was performed to evaluate the antioxidant capacity, the polyphenol and metal content of conventionally and organically produced wines, which underwent similar winemaking processes. The wine grapes were grown under well-defined organic and conventional conditions from the two different wine-growing sub-regions of Croatia, Prigorje and Southern Dalmatia. The values of antioxidant activity, as evaluated by two free radical methods, ABTS and DPPH, was found systematically higher in organic wines compared to conventional ones. In a reversed phase HPLC analysis, used in order to characterise the phenol fraction of wines, higher concentrations of chlorogenic acid, ferulic acid, catechin, trans-resveratrol, all studied hydroxybenzoic acids and flavonols were found in the organically produced wines. No apparent trend was found in the metal contents of the wines, but ICP-MS analysis confirmed that both wine productions, organic and conventional, were well within the toxicological safety limits.     

Excitation and spectral dependence of the rise and decay time responses of Eu2+- and Dy3+-doped strontium aluminates

Journal of Materials Science: Materials in Electronics - In this paper, we study the phosphorescence rise and decay time responses of Eu2+- and Dy3+-doped strontium aluminates prepared by different...