Single-bonded cubic form of nitrogen

Nitrogen usually consists of molecules where two atoms are strongly triple-bonded. Here, we report on an allotropic form of nitrogen where all atoms are connected with single covalent bonds, similar to carbon atoms in diamond. The compound was synthesized directly from molecular nitrogen at temperatures above 2,000 K and pressures above 110 GPa using a laser-heated diamond cell. From X-ray and Raman scattering we have identified this as the long-sought-after polymeric nitrogen with the theoretically predicted cubic gauche structure (cg-N). This cubic phase has not been observed previously in any element. The phase is a stiff substance with bulk modulus >or=300 GPa, characteristic of strong covalent solids. The polymeric nitrogen is metastable, and contrasts with previously reported amorphous non-molecular nitrogen, which is most likely a mixture of small clusters of non-molecular phases. The cg-N represents a new class of single-bonded nitrogen materials with unique properties such as energy capacity: more than five times that of the most powerfully energetic materials.     

Selecting exposure measures in crash rate prediction for two-lane highway segments

A critical part of any risk assessment is identifying how to represent exposure to the risk involved. Recent research shows that the relationship between crash count and traffic volume is non-linear; consequently, a simple crash rate computed as the ratio of crash count to volume is not proper for comparing the safety of sites with different traffic volumes. To solve this problem, we describe a new approach for relating traffic volume and crash incidence. Specifically, we disaggregate crashes into four types: (1) single-vehicle, (2) multi-vehicle same direction, (3) multi-vehicle opposite direction, and (4) multi-vehicle intersecting, and define candidate exposure measures for each that we hypothesize will be linear with respect to each crash type. This paper describes initial investigation using crash and physical characteristics data for highway segments in Michigan from the Highway Safety Information System (HSIS). We use zero-inflated-Poisson (ZIP) modeling to estimate models for predicting counts for each of the above crash types as a function of the daily volume, segment length, speed limit and roadway width. We found that the relationship between crashes and the daily volume (AADT) is non-linear and varies by crash type, and is significantly different from the relationship between crashes and segment length for all crash types. Our research will provide information to improve accuracy of crash predictions and, thus, facilitate more meaningful comparison of the safety record of seemingly similar highway locations.     

Algorithm for the retrieval of columnar water vapor from hyperspectral remotely sensed data

A new algorithm for the retrieval of columnar water vapor content is presented. The proposed procedure computes the area of the H2O absorption centered about 940 nm to allow its integrated columnar abundance as well as its density at ground level to be assessed. The procedure utilizes the HITRAN 2000 database as the source of H2O cross-section spectra. Experimental results were derived from radiometrically calibrated hyperspectral images collected by the Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) sensor over the Cuprite mining district in Nevada. Numerical simulations based on the MODTRAN 4 radiative transfer code were also employed for investigating the algorithm's performance. An additional empirical H2O retrieval procedure was tested by use of data gathered by the VIRS-200 imaging spectrometer.     

High-resolution photometric optical monitoring for thin-film deposition

Real-time monitoring of thin-film deposition with high resolution is important for precise fabrication of thin-film devices in a technological environment with ever-increasing demands for smaller size and better performance. Using photometry, we were able to achieve a real-time optical monitoring resolution of film thickness that is comparable with a single atomic layer scale (i.e., subnanometer). Filtering noise efficiently and compensating for sources of error by use of an appropriate model produced this high resolution. The procedure proved reliable and can be useful in the thin-film-deposition industry.     

Low-Power Log-Domain CMOS Filter Bank for 2-D Sound Source Localization

This paper proposes the design of a novel current-mode front-end for the extraction of localization spectral cues from two audio signals, together with test results. The front-end consists of two parallel filter banks, envelope extraction and comparison circuitry, together with an AGC loop. The extracted cues are intended to be further processed in order to determine the source azimuth and elevation. A current-mode log-domain implementation using subthreshold MOS operation is used for micropower operation while still achieving a good bandwidth and linearity. A current-mode solution is also preferred because of the ease of implementation of certain mathematical operations. The front-end splits the input signals into different frequency bands and computes monaural and interaural spectral cues from the resulting signal envelopes for each band. The front-end has been optimized to operate at a supply voltage of 1.8 V and most blocks have been designed using a differential architecture. To our knowledge, this is the first log-domain implementation of a front-end for 2-D localization cues extraction. The design has been carried out using a standard double-poly double-metal 0.8 m CMOS process with V _T = 0.8 V. The bandpass filters which form the main core of the chip exhibit a measured dynamic range of 62 dB corresponding to 1.9% THD, while the total power dissipation is 890 W.     

Special features of formation and characteristics of Ni/21<Emphasis Type="Italic">R</Emphasis>-SiC Schottky diodes

The Ni/n-21R-SiC(0001) and \(Ni/n - 21R - SiC(000\bar 1)\) surface-barrier structures formed on 21R-SiC crystals doped to a concentration of (1–2)×10¹⁸ cm^?3 and grown by the Lely method were investigated prior to and after rapid thermal annealing (RTA) in vacuum (10^?2 Pa) in the temperature range of 450–1100°C. Using X-ray diffraction analysis and Auger analysis, it is shown that cubic NiSi₂ and orthorhombic δ-Ni₂Si and NiSi silicides coexist with pure Ni in starting samples. The RTA brings about a polymorphic transformation of these phases, which causes the transformation of a barrier contact to a rectifying one independently of the SiC face type, even at T?600°C. The physicochemical mechanisms of degradation of these barrier structures are discussed.     

Reliable fabrication technologies for optical resonant filters

A reliable technology for optical resonant filters can be useful for optoelectronics technologies, optical communications systems, and biomedical applications. Positioning the resonance at a specific target wavelength is challenging because of the sensitivity of placing a narrow spectral filtering window tothe error factors that are associated with the fabrication and characterization processes. We describe and prove experimentally two fabrication approaches to overcome this challenge.     

Using the Curriculum Vita to Study the Career Paths of Scientists and Engineers: An Exploratory Assessment

In this paper we assess the utility of the curriculum vita (CV) as a data source for examining the career paths of scientists and engineers. CVs were obtained in response to an email message sent to researchers working in the areas of biotechnology and microelectronics. In addition, a number of CVs were obtained "passively" from a search of the Internet. We discuss the methodological issues and problems of this data collection strategy and the results from an exploratory analysis using OLS regression and event history analysis. In sum, despite difficulties with coding and variation in CV formats, this collection strategy seems to us to hold much promise.