Distributed mathematical model supporting design and construction of solar collectors for drying

Coupled partial differential equations were developed to investigate which collector lengths are appropriate for drying and adsorbent regeneration under prevailing Ghanaian weather. Unlike approaches based on empirical data, the numerical model is more flexible. Effects of operational and design variables on outlet temperature and performance were systematically studied. Collector length and air speed affect performance indicators. Operational overall heat loss coefficient, an important characteristic of the collector, is not constant but varies during the day. With plausible physical parameters, the model describes the experimental data well. Collector lengths of 1.5 and 4.5?m suited drying and regeneration, respectively.     

The Brazilian experience of rural electrification in the Amazon with decentralized generation - The need to change the paradigm from electrification to development

There are at least 607 thousand households in the Brazilian Amazon that need to be attended with some form of regular electricity service. These households are not attended by the electricity sector through its electricity distribution companies and most of them have some form of precarious decentralized electricity generation that is not registered or regulated in the institutional framework. Diverse initiatives were taken by Brazilian government to attend these household through alternatives that relied on locally available renewable energy. This paper accesses this initiatives of rural electrification in the Brazilian Amazon. First an overview of the problems of rural electricity are discussed and its specificities in the Brazilian Amazon. Then the Brazilian institutional framework that organizes the decentralized electricity generation is described with its various limitations. The diverse initiatives undertaken to attend the rural communities in the Amazon since the 1990s are described, as well as how these initiatives are linked to the policies for rural electrification. The results shows that it can be inferred that sole market mechanisms are not sufficient to guarantee economic sustainability of these projects. This can be one of the reasons why traditional electricity distribution companies showed the lack of interest in promoting rural electrification with other means than grid extension. The most successful projects had financed efforts to integrate the generation of electricity into local development initiatives in order to guarantee sustainability and used substantial part of funding for local mobilization and organization. It needs a paradigm chance by treating these initiatives as local development initiatives and promoting alternative ways for its implementation through partnership between local new actors in the electricity sector and government and implementing policy on a local municipal level.     

Advantages and challenges with using hypoxic air venting as fire protection

The use of hypoxic air venting system as fire protection is increasing and is sometimes used to replace traditional extinguishing systems. An oxygen level of 15% is generally used because a lower concentration could pose serious health risks. On the request of the Swedish Radiation Safety Authority, a literature review was conducted to determine advantages and challenges with the system and further research needs. The main advantages with a reduced oxygen environment are the reduced probability of ignition and lowered heat release rate. However, at 15% oxygen level, risk for fire still exists, and the system cannot be seen as an alternative to extinguishing systems. Reduced oxygen environment also results in higher production rates of soot and smoke, and there is limited knowledge regarding the effect of fuel configuration and fire behavior of products. In addition, a first evaluation of the test method specified in the hypoxic air venting standards was carried out through testing. The testing showed that the particleboard passed the test criteria at normal atmosphere even though it is commonly known that a particleboard burns in normal air. It is concluded that the test method has deficiencies, and there is clearly a need for development of the test method to guarantee safety levels. © 2013 The Authors. Fire and Materials published by John Wiley & Sons, Ltd.     

A Primary Method for the Determination of Hydroxyl Value of Polyols by Fourier Transform Mid-Infrared Spectroscopy

A primary Fourier transform infrared (FTIR) method was developed to determine the hydroxyl value (OHV) of polyols produced from edible oils. The method is a modification of American Society for Testing and Materials 1899‐08, using toluene as the solvent to dissolve the sample and to carry the reactive reagent p‐toluenesulfonyl isocyanate (TSI). TSI reacts with OH groups to produce a carbamate, a functional group that can be measured spectrally between ~1780 and 1690 cm^?1 in the differential spectrum that is obtained from spectra collected before and after the reaction. Commercially available 1‐nonanol, which has a defined OHV, is used to develop a calibration. The OHV for a variety of 1° and 2° alcohols, as well as petrochemical and lipid‐based polyols, were then measured to evaluate the performance of the method and to assess the effects of moisture on the results. The FTIR OHV were in accord with the results obtained by AOCS method Cd 13‐60 and were demonstrated to be unaffected by the presence of moisture in the sample. The new TSI‐FTIR method is simpler, much faster (~10 min), and more reproducible and accurate than the AOCS OHV titrimetric methods and is not affected by carboxylic acids, amines or moisture.     

Process and performance optimization by selective assembly of battery electrodes

The increasing demand for electric vehicles and thus lithium-ion batteries results in a multitude of challenges in production technology. The reproducibility and performance of large scale batteries for automotive applications are very high. At the same time the production processes are complex and involve many uncertainties. Two essential process steps are the electrode coating and electrode package assembly. The mass loading of anodes and cathodes are determined by the coating process, where deviations can be caused by different reasons. The selective assembly of the electrodes is a reasonable way to balance the production variances. The contribution shows extended algorithms and their benefits and drawbacks of matching electrodes in order to improve the subsequent electrode packaging process. Here, the aim is to reach higher cell capacities and optimized performance values by “optimally” balanced electrodes regarding the mass loading ratio, which is also related to the specific material capacity.     

Alterations in gap junction connexin43/connexin45 ratio mediate a transition from quiescence to excitation in a mathematical model of the myometrium

The smooth muscle cells of the uterus contract in unison during delivery. These cells achieve coordinated activity via electrical connections called gap junctions which consist of aggregated connexin proteins such as connexin43 and connexin45. The density of gap junctions governs the excitability of the myometrium (among other factors). An increase in gap junction density occurs immediately prior to parturition. We extend a mathematical model of the myometrium by incorporating the voltage-dependence of gap junctions that has been demonstrated in the experimental literature. Two functional subtypes exist, corresponding to systems with predominantly connexin43 and predominantly connexin45, respectively. Our simulation results indicate that the gap junction protein connexin45 acts as a negative modulator of uterine excitability, and hence, activity. A network with a higher proportion of connexin45 relative to connexin43 is unable to excite every cell. Connexin45 has much more rapid gating kinetics than connexin43 which we show limits the maximum duration of a local burst of activity. We propose that this effect regulates the degree of synchronous excitation attained during a contraction. Our results support the hypothesis that as labour approaches, connexin45 is downregulated to allow action potentials to spread more readily through the myometrium.     

Managing risks in public-private partnership formation projects

While sourcing by means of Public-Private Partnerships has been lauded over recent years, increasingly risks appear to jeopardise public organisations' unique societal tasks. Integrated Risk Management has not yet been applied to public organisations getting involved in PPP in the sense of understanding risk management capabilities. This article explores risk awareness and risk management practices underpinning maintenance partnership formation by means of a dual case study of two PPP projects and a short industry survey. The results suggest that organisations face several “intolerable risks” linked to project governance and project management responsibilities: insufficient representation of qualified employees, absence of a shared performance system, assignment of responsibilities and decision-making authority, impractical or inappropriate partnership agreement, and timing of the partnership initiative. Cross-case analysis revealed the role of different levels of risk awareness and senior management involvement. Drawing on these findings, a framework for risk management for PPP formation projects is developed.