Modification of a carbon/carbon composite with a thermosetting resin precursor as a matrix by the addition of carbon black

Carbon/carbon composites were made through the pyrolysis of stabilized PAN felt and phenolic resin with the addition of 5 or 10 wt % carbon black to the matrix and then heat treatment at 600–2500°C. The effects of adding carbon black to the matrix precursor on the physical properties, microstructure, and mechanical properties of the resultant composites were investigated. Adding carbon black not only reduced the weight loss but also limited the shrinkage of the resultant composites. Adding carbon black also accelerated the formation of carbon basal planes in the matrix. At 2500°C, the crystalline stacking height in the composite with 10 wt % added carbon black was 200% greater than that with no additive. The flexural strength of the composite also increased from 15 to 42 MPa (almost 300%). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 333–337, 2006     

Electrorheological properties of chemically modified chitosan suspension with various functional pendants

In this study, functional pendants of chitosan were focused on enhancing the shear stress of electrorheological (ER) fluids. Chitosan succinates and chitosan phthalate were synthesized for ER particles and ER fluids were prepared by dispersing the particles in silicone oil. After comparing the shear stress of all prepared ER fluids, obtained conclusions were that ER particle having two functional groups (one is +ve charge and another is ?ve charge) showed higher shear stress than that having only one functional group like the comparison between chitosan succinate(I) and chitosan succinate(II). However, though expect of the intermolecular overlapping between the π electrons clouds supporting the charge carrier generation and transport leading to a significant delocalization of electrons, chitosan phthalate shows lower shear stress than chitosan succinate(I) and chitosan succinate(II). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4937–4942, 2006     

Fabrication of SiO2-ZrO2 composite fiber mats via electrospinning

(1 ? x)SiO₂-(x)ZrO₂ (x = 0.1, 0.2) composite fiber mats were prepared by electrospinning their sol-gel precursors of zirconium acetate and tetraethyl orthosilicate (TEOS) without using a polymer binder. The electrospun composite fibers were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FT-IR) and mercury porosimetry. The composite fibers having a tetragonal crystalline ZrO₂ were obtained by calcining the electrospun composite fibers at high temperatures. The results show that the structure and crystallization of ZrO₂ in the composite fibers can be controlled by sintering temperature, while the porosity and morphology of the fiber mats did not depend on the sintering temperature.     

Blue‐light‐emitting poly(arylene ethynylenes) containing alternating sequences of biphenylene or fluorenediyl and p‐phenylene moieties linked through triple bonds

Two new poly(arylene ethynylenes) were synthesized by the reaction of 1,4‐diethynyl‐2.5‐dioctylbenzene either with 4,4′‐diiodo‐3,3′‐dimethyl‐1,1′‐biphenyl or 2,7‐diiodo‐9,9‐dioctylfluorene via the Sonogashira reaction, and their photoluminescence (PL) and electroluminescence (EL) properties were studied. The new poly(arylene ethynylenes) were poly[(3,3′‐dimethyl‐1,1′‐biphenyl‐4,4′‐diyl)‐1,2‐ethynediyl‐(2,5‐dioctyl‐1,4‐phenylene)‐1,2‐ethynediyl] (PPEBE) and poly[(9,9‐dioctylfluorene‐2,7‐diyl)‐1,2‐ethynediyl‐(2,5‐dioctyl‐1,4‐phenylene)‐1,2‐ethynediyl] (PPEFE), both of which were blue‐light emitters. PPEBE not only emitted better blue light than PPEFE, but it also performed better in EL than the latter when the light‐emitting diode devices were constructed with the configuration indium–tin oxide/poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonic acid) (50 nm)/polymer (80 nm)/Ca:Al. The device constructed with PPEBE exhibited an external quantum efficiency of 0.29 cd/A and a maximum brightness of about 560 cd/m², with its EL spectrum showing emitting light maxima at λ = 445 and 472 nm. The device with PPEFE exhibited an efficiency of 0.10 cd/A and a maximum brightness of about 270 cd/m², with its EL spectrum showing an emitting light maximum at λ = 473 nm. Hole mobility (μ_h) and electron mobility (μ_e) of the polymers were determined by the time‐of‐flight method. Both polymers showed faster μ_h values. PPEBE revealed a μ_h of 2.0 × 10^?4 cm²/V·s at an electric field of 1.9 × 10⁵ V/cm and a μ_e of 7.0 × 10^?5 cm²/V·s at an electric field of 1.9 × 10⁵ V/cm. In contrast, the mobilities of the both carriers were slower for PPEFE, and its μ_h (8.0 × 10^?6 cm²/V·s at an electric field of 1.7 × 10⁶ V/cm) was 120 times its μ_e (6.5 × 10^?8 cm²/V·s at an electric field of 8.6 × 10⁵ V/cm). The much better balance in the carriers' mobilities appeared to be the major reason for the better device performance of PPEBE than PPEFE. Their highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels were also a little different from each other. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 299–306, 2006     

Pulsed current activated combustion synthesis and consolidation of ultrafine NbSi2 from mechanically activated powders

Dense ultrafine NbSi₂ was synthesized using the pulsed current activated combustion synthesis (PCACS) method within 2 min and in one step from mechanically activated powders of Nb and 2Si. Simultaneous combustion synthesis and densification were accomplished under the combined effects of a pulsed current and mechanical pressure. Highly dense NbSi₂ with a relative density of up to 98 % was produced under simultaneous application of a 60 MPa pressure and a pulsed current. The average grain size and mechanical properties (hardness and fracture toughness) of the compound were investigated.     

Effect of aluminum nitride-scandia content on the microstructural and mechanical properties of sintered silicon carbide ceramics

Two different SiC ceramics, one with 10 vol.% AlN-Sc₂O₃ in a 2:3 molar ratio, and the other with 20 vol.% of the same additives with the same ratio, were fabricated by hot-pressing at 1900 °C for 1 h and subsequent annealing at 2000 °C for 6 h in nitrogen. The grain boundary structures of both materials were observed by using high-resolution transmission electron microscopy. The results showed that both materials had clean boundaries without any amorphous films. Although both samples exhibited the same boundary structure, the sample with the higher AlN-Sc₂O₃ content contained more junction phases. The SiC ceramic with 10 vol.% AlN-Sc₂O₃ maintained its room-temperature strength up to 1400°C, whereas the SiC ceramic with 20 vol.% AlN-Sc₂O₃ showed a gradual decrease in strength at above 900 °C. The present results suggest that the high-temperature strength is dependent on the amount of junction phase, as well as the characteristics of the intergranular phase.     

Development of 2-axis hybrid positioning system for precision contouring on micro-milling operation

A 2-axis hybrid positioning system was developed for precision contouring on micro-milling operation. The system was developed to overcome the micro-positioning limitations of conventional linear stage positioning system on machine tools. A 2-axis flexure hinge type piezoelectric stage was added on a standard milling machine to obtain better machining results. The control method used for the hybrid system was active error compensation type, where errors from linear stages are cancelled by the piezoelectric stage motion. Positioning experiments showed an improvement of machine accuracy which was confirmed by the machining results. A micro-pillar was fabricated for the validation of long-range and high-precision contouring capability. The system was successfully implemented on micro-milling machining to achieve high-precision machining results.     

On-machine measurement using a noncontact sensor based on a CAD model

Once a machining process is finished, an inspection process is carried out to check whether the part is within dimensional tolerances. A coordinate measuring machine (CMM) is a general metrological device for assessment of dimensions on the shop floor. It cannot be ignored, however, that CMM measurements require significant resources in operating time and cost, which has led to many studies into on-machine measurement (OMM) systems. This study aims to develop an OMM system with a noncontacting laser displacement sensing apparatus and a computer-aided design (CAD) model for ease of operation, improved operating speed, and free form profiling. The system is composed of two software modules, one for sensor alignment with the machine tool and the other for measurement based on CAD/CAM (computer-aided machining). Consequently, the system was verified on the shop floor at a numerical control (NC) machining center.     

A study on the force balance of an unbalanced globe valve

A pneumatic control valve is a piping element that controls the volumetric flow rate and pressure of a fluid; it is necessary to analyze the characteristics of the forces with respect to the opening of the valve in order to evaluate its operating performance. The forces occurring during operation are: resisting force and actuator force, where the load resistance is mostly affected by the fluid pressure difference of the valve. In this study, a force balance equation derived from the equilibrium relationship between the resisting force and the actuator force of an unbalanced globe valve is proposed, and the force balance equations are used to model the dynamic equations of a pneumatic unbalanced globe valve installed in nuclear power plants. A CFD analysis is also carried out to evaluate the pressure distribution and forces acting on the top and bottom planes of the valve plug. The results of this analysis have been verified through experimentation. This study has shown that the fluid pressure difference between the inlet and outlet of the valve, measured from the force balance equation of an unbalanced valve, should actually be examined with the fluid-pressure difference between the top and bottom side of the valve plug.