一种全新矿用高弹性联轴器动态性能的研究

用试验和理论相结合的方法,提出了建立新型矿用高弹性联轴器恢复务动态模型与参数辨识方法和技术,由此建立其恢复力学数学模型,用此模型研究和描述联轴器动态特性,研究表明,弹性恢复力是非线性单值力,是刚度函数的函数,阻尼力是双值非线性力,是阻尼函数和阻尼成分函数的函数,阻尼成分函数和阻尼函数概念的,使得模型能反映阻尼成分的组成和阻尼的大小变化规律,能全面地揭示联轴器中阻尼的变化情况,滞回线的形状和宽窄由模型中参数控制,这种联轴器的阻尼成分丰富,既有粘性阻尼,又有干摩擦阻尼的“高阶”阻尼。通过研究了解了联轴器的动态特性,为设计宽频多工作区奠定了动力学基础。     

数理统计与遥感信息在预测找矿靶区中的应用(——以湖北金山店地区为例)

笔者将数学地质与遥感地质两者相结合,在湖北金山店地区用概率论的方法处理通过遥感技术获得的大量信息,在将地质模型转变为数学模型方面,取得了一些成果,建立了金山店地区一元线性回归模型,并圈出了成矿远景区。     

水雷武器安全保险系统可靠性评估探讨

可靠性是水雷武器完成预定作战任务的有力保障,尤其对于水雷武器安全保险系统这种结构、运行模式复杂的子系统,保证其达到可靠性指标尤为重要。评估可靠性的方法是可靠性研究的关键,尝试对其可靠性的评估方法进行了探讨,并结合某型水雷实例作出具体分析。     

雷达组网的精确极大似然误差配准算法

针对最小二乘法和卡尔曼滤波方法在雷达网系统中的误差配准问题,提出一种雷达组网的精确极大似然误差配准算法。采用基于圆极投影的极大似然配准算法,利用各雷达站的几何关系,通过极大似然混合高斯一牛顿迭代方法估计出雷达网的系统误差,并进行仿真。仿真结果证明：该配准方法具有良好的一致性,可以用于多雷达组网的误差配准。     

Mechanism and kinetic study for the intensification of two-step synthesis of a dolutegravir intermediate in microreactor

Multi-step reaction processes are frequently encountered in the synthesis of pharmaceuticals, separate study on each step however is easily neglected. Herein, we separately investigated two reaction steps for the synthesis of an intermediate (DTG-6) of an anti-HIV drug dolutegravir (DTG) in microreactors. The first step (i.e., deprotection of DTG-4) was optimized to achieve a high DTG-5 yield (i.e., 96.7%) in the microreactor after the parametric screening on the DTG-4 concentration, methanesulfonic acid loading, molar ratio of reaction components, and so forth. Reaction kinetics was revealed based on substantial experimental data and mechanism cognition. Validation experiments showed the accuracy of this reaction kinetics. After thoroughly understanding this deprotection step, we combined it with the following annelation step in a cascade microreactor system for the two-step synthesis of DTG-6 with a much higher yield even at a remarkably shorter residence time compared with literature reports, thus indicating efficient process intensification.     

Large electrocaloric effect with ultrawide temperature span in Na1/2Bi1/2TiO3-based lead-free ceramics

Innovative cooling technologies are recognized by many industries as a crucial part of their system design. A large electrocaloric effect (ECE) and extended working temperature are the key issues hindering the realization of electrocaloric refrigeration technology. In this work, large ECE (ΔT = 0.8–0.9°C @ 4 kV/mm) with an ultrawide temperature span from 30 to 120°C is noted for lead-free (Na_1/2Bi_1/2)_0.80Sr_0.20(Zn_1/3Nb_2/3)_xTi_1-xO₃ ceramics. The excellent ECE performance can be ascribed to the evolution of polar nanoregions. Our work suggests that this material is promising for applications in solid-state refrigeration systems with a broad range of operating temperatures.     

Surface modification with cobalt oxide nanocluster for enhanced surface oxygen exchange reactions of GDC-LSCF membrane: fabrication,electrochemical kinetic properties,and stability

Journal of Applied Electrochemistry - Surface oxygen exchange is a critical reaction process involved in ceramic devices for energy conversion and storage such as gas separation membranes and solid...     

Pebax/a-MoS2/MIP-202混合基质膜的制备及CO2分离性能

为了获得高性能的CO₂/N₂分离膜,把空气中氧刻蚀的二硫化钼（a-MoS₂）和金属有机框架材料MIP-202通过机械力化学反应制备的双功能填料作为分散相,聚醚嵌段酰胺（Pebax-1657）作为连续相,采用溶液浇铸法制备了Pebax/a-MoS₂/MIP-202混合基质膜。采用FT-IR表征了填料的化学结构,借助ATR-FTIR、SEM、TG和力学性能测试表征了混合基质膜的化学结构、微观形貌结构、热稳定性和物理力学性能。研究了水含量、双功能填料配比、含量、膜两侧压差和操作温度对膜气体分离性能的影响,并考察了模拟烟道气（CO₂/N₂体积比15/85）条件下混合基质膜的长时间运行稳定性。结果表明：在温度为25℃、膜两侧压差为0.1 MPa的操作条件下,a-MoS₂与MIP-202质量比为5∶5和双功能填料含量为6%（质量）时,膜的气体分离性能达到最优,CO₂渗透性和CO₂/N₂选择性分别为380 Barrer和124.7,超过了2019年McKeown等提出的上限值。连续测试360 h后,混合基质膜的性能没有明显降低,其平均CO₂渗透性和CO₂/N₂选择性分别为358 Barrer和120.1。这主要是由于a-MoS₂和MIP-202协同提高了膜的气体分离性能。     

烯丙基三甲氧基硅烷封端溶聚丁苯橡胶的合成

以丁二烯和苯乙烯为单体、正丁基锂为引发剂、双四氢糠丙烷为结构调节剂、1,1-二苯基乙烯为“盖帽剂”、烯丙基三甲氧基硅烷（TIOS）为封端剂,采用负离子聚合法合成了TIOS封端的溶聚丁苯橡胶（SSBR）。采用凝胶渗透色谱和核磁共振波谱表征了封端前后SSBR的结构和分子量及其分布,考察了封端反应时间、反应温度、TIOS用量及SSBR分子量对封端效率的影响。结果表明,封端反应时间为30 min、反应温度为60 ℃、TIOS与正丁基锂摩尔比为2.0及SSBR相对分子质量约为60 000时封端效率较高。     

电解水制氢耦合碳酸盐还原展望

无机金属碳酸盐是一类具有高附价值和地球储量丰富的矿物质资源,且碳酸盐热分解是制备金属氧化物的主要途径。但是,该类反应通常需要在高温、氧气气氛下焙烧获得,从而造成大量二氧化碳排放,与其相关的碳排放总量超过了全国工业碳排放的50%。为了解决这一问题,无机金属碳酸盐加氢热分解逐渐引起关注。本文首先介绍了碳酸盐加氢热分解的研究进展,进一步结合本文作者课题组近期关于电解水制氢和碳酸盐加氢还原的最新成果,提出电解水制氢耦合碳酸盐还原的观点,其有望成为制备金属氧化物的新型技术路线,对我国重排放过程工业的减排增效具有借鉴意义。