Antibacterial Surface Coatings from Zinc Oxide Nanoparticles Embedded in Poly(N‐isopropylacrylamide) Hydrogel Surface Layers

Despite multiple research approaches to prevent bacterial colonization on surfaces, device‐associated infections are currently responsible for about 50% of nosocomial infections in Europe and significantly increase health care costs, which demands development of advanced antibacterial surface coatings. Here, novel antimicrobial composite materials incorporating zinc oxide nanoparticles (ZnO NP) into biocompatible poly(N‐isopropylacrylamide) (PNIPAAm) hydrogel layers are prepared by mixing the PNIPAAm prepolymer with ZnO NP, followed by spin‐coating and photocrosslinking. Scanning electron microscopy (SEM) characterization of the composite film morphology reveals a homogeneous distribution of the ZnO NP throughout the film for every applied NP/polymer ratio. The optical properties of the embedded NP are not affected by the matrix as confirmed by UV‐vis spectroscopy. The nanocomposite films exhibit bactericidal behavior towards Escherichia coli (E. coli) for a ZnO concentration as low as ≈0.74 μg cm^?2 (1.33 mmol cm^?3), which is determined by inductively coupled plasma optical emission spectrometry. In contrast, the coatings are found to be non‐cytotoxic towards a mammalian cell line (NIH/3T3) at bactericidal loadings of ZnO over an extended period of seven days. The differential toxicity of the ZnO/hydrogel nanocomposite thin films between bacterial and cellular species qualifies them as promising candidates for novel biomedical device coatings.     

Experimental demonstration of real-time spectrum analysis using dispersive microstrip

We demonstrate the use of dispersive microstrip as a mechanism for obtaining the real-time Fourier transform of a time-limited signal within a predefined bandwidth. By etching a linearly-chirped impedance modulation into the upper plane strip-width, dispersive microstrip lines are created in which group-delay depends linearly on frequency within a prescribed bandwidth. When the group-delay satisfies a condition that is the temporal analog of the spatial Fraunhofer (far-field) condition of diffraction, the spectral components of an input signal are reordered in time such that the temporal envelope of the output signal corresponds to the Fourier-transform of the input. Experimental results are demonstrated for signals with frequency content from 4 to 8GHz in a 1.2-ns window.     

开放源代码与开放性标准之辨

长期以来，技术供应商在使用“开放”一词的同时，也在滥用它。因此，现在轮到技术用户大量使用开放一词，也就不足为奇了。如今，“开放”一词已经和软件源代码、工业标准、开发商社团和各种许可模型等四个完全不同的技术术语联系在一起。而这四个技术术语经常被人们以含糊的方式混为一谈。软件源代码、工业标准、开发商社团和许可模型都在发挥着各自的作用。但重要的是应该了解到，其中每一种技术指的是什么、不是什么。在这四种技术中，开放性标准最为关键，因为你今天做出的选择不应该妨碍你明天做出另外一种选择。这就是开放性标准的全…     

Interface dipole engineering at buried organic–organic semiconductor heterojunctions

A general technique for modifying energy level alignment at organic–organic heterojunctions is introduced, and is demonstrated here for phenyl-C₆₁-butyric acid methyl ester (PCBM) and N,N′-Di-[(1-naphthyl)-N,N′-diphenyl]-1,1′-biphenyl)-4,4′-diamine (α-NPD). An ultra-thin layer (∼1 nm) of TiO₂ is used as an adhesion template to attach a self-assembled monolayer of dipolar phosphonate (PA) molecules to the lower interface of a two-stack ensemble. This modification induces shifts in the vacuum level and work function over ∼1.0 eV depending on the molecular dipole moment of the PA, which in turn modifies the electronic level alignment across the organic heterojunction interface by up to 0.5 eV.     

Partial-response coding, maximum-likelihood decoding: capitalizing on the analogy between communication and recording - [History of communications]

Signal processing and coding technology for digital magnetic recording is the core technology of the channel electronics module in a hard disk drive (HDD) that processes signals read from magnetic media. In this historical review I focus on what is now widely known as partial-response, maximum-likelihood (PRML) technology, which takes advantage of the inherent redundancy that exists in signals read out of magnetic media; its theoretical foundation goes back to 1970, and it capitalizes on the analogy between high-speed data transmission and high-density digital recording, and that between a convolutional code and a partial-response signal. The first PRML-based product was introduced by IBM in 1990, and PRML technology soon became the industry standard for all digital magnetic recording products, ranging from computers' HDDs and tape drives to micro hard discs used in PCs, mobile phones, and MP3 players; use of the PRML principle has recently been extended to optical recording products such as CDs and DVDs. Its improved version, called NPML (noise-predictive, maximum-likelihood), and variants have been adopted by the HDD industry since 2000. Today, a large number of communication and information theory researchers are investigating use of advanced techniques such as turbo coding/decoding to further improve the density and reliability of both magnetic and optical recording systems.     

Understanding Local and Macroscopic Electron Mobilities in the Fullerene Network of Conjugated Polymer‐based Solar Cells: Time‐Resolved Microwave Conductivity and Theory

The efficiency of bulk heterojunction (BHJ) organic photovoltaics is sensitive to the morphology of the fullerene network that transports electrons through the device. This sensitivity makes it difficult to distinguish the contrasting roles of local electron mobility (how easily electrons can transfer between neighboring fullerene molecules) and macroscopic electron mobility (how well‐connected is the fullerene network on device length scales) in solar cell performance. In this work, a combination of density functional theory (DFT) calculations, flash‐photolysis time‐resolved microwave conductivity (TRMC) experiments, and space‐charge‐limit current (SCLC) mobility estimates are used to examine the roles of local and macroscopic electron mobility in conjugated polymer/fullerene BHJ photovoltaics. The local mobility of different pentaaryl fullerene derivatives (so‐called ‘shuttlecock’ molecules) is similar, so that differences in solar cell efficiency and SCLC mobilities result directly from the different propensities of these molecules to self‐assemble on macroscopic length scales. These experiments and calculations also demonstrate that the local mobility of phenyl‐C₆₀ butyl methyl ester (PCBM) is an order of magnitude higher than that of other fullerene derivatives, explaining why PCBM has been the acceptor of choice for conjugated polymer BHJ devices even though it does not form an optimal macroscopic network. The DFT calculations indicate that PCBM's superior local mobility comes from the near‐spherical nature of its molecular orbitals, which allow strong electronic coupling between adjacent molecules. In combination, DFT and TRMC techniques provide a tool for screening new fullerene derivatives for good local mobility when designing new molecules that can improve on the macroscopic electron mobility offered by PCBM.     

Models for Audiovisual Fusion in a Noisy-Vowel Recognition Task

This paper presents a study of models for audiovisual (AV) fusion in a noisy-vowel recognition task. We progressively elaborate audiovisual models in order to respect the major principle demonstrated by human subjects in speech perception experiments (the synergy principle): audiovisual identification should always be more efficient than auditory-alone or visual-alone identification. We first recall that the efficiency of audiovisual speech recognition systems depends on the level at which they fuse sound and image: four AV architectures are presented, and two are selected for the following of the study. Secondly, we show the importance of providing a contextual input linked to the Signal-to-Noise Ratio (SNR) in the fusion process. Then we propose an original approach using an efficient nonlinear dimension reduction algorithm (curvilinear components analysis) in order to increase the performances of the two AV architectures. Furthermore, we show that this approach allows an easy and efficient estimation of the reliability of the audio sensor in relation to SNR, that this estimation can be used to control the AV fusion process, and that it significantly improves the AV performances. Hence, altogether, nonlinear dimension reduction, context estimation and control of the fusion process enable us to respect the synergy criterion for the two most used architectures.     

Application of multilayer feedforward neural networks toprecipitation cell-top altitude estimation

The use of passive 118-GHz O₂ observations of rain cells for precipitation cell-top altitude estimation is demonstrated by using a multilayer feedforward neural network retrieval system. Rain cell observations at 118 GHz were compared with estimates of the cell-top altitude obtained by optical stereoscopy. The observations were made with 2-4-km horizontal spatial resolution by using the millimeter-wave temperature sounder (MTS) scanning spectrometer aboard the NASA ER-2 research aircraft during the Genesis of Atlantic Lows Experiment (GALE) and the Cooperative Huntsville Meteorological Experiment (COHMEX) in 1986. The neural network estimator applied to MTS spectral differences between clouds, and nearby clear air yielded an rms discrepancy of 1.76 km for a combined cumulus, mature, and dissipating cell set and 1.44 km for the cumulus-only set. An improvement in rms discrepancy to 1.36 km was achieved by including additional MTS information on the absolute atmospheric temperature profile. An incremental method for training neural networks was developed that yielded robust results, despite the use of as few as 56 training spectra. Comparison of these results with a nonlinear statistical estimator shows that superior results can be obtained with a neural network retrieval system. Imagery of estimated cell-top altitudes was created from 118-GHz spectral imagery gathered from CAMEX, September through October 1993, and from cyclone Oliver, February 7, 1993     

Error control using retransmission schemes in multicast transportprotocols for real-time media

We analyze different retransmission (ARQ) schemes for error control in multicast protocols geared toward real-time, multimedia applications. We discuss why retransmission schemes are not inappropriate for such applications, but in fact can be quite effective. We present a quantitative analysis of such schemes, as well as simulation results, taking into account four different parameters (and not just the source throughput): (1) the probability of dropping a packet due to limited time for retransmissions; (2) the average time required to deliver a packet correctly to end receivers; (3) the number of times a packet will be retransmitted; and (4) the cost to the network, in terms of packet duplications, of retransmitting a packet. We reach the counter-intuitive conclusion that the optimum scheme, in terms of all four of the above parameters, in the most general scenarios (where several hosts with widely varying propagation delays and `quality of connections' are participating in the session) is to immediately retransmit packets-preferably multicast-upon reception of a NACK from any receiver. We also demonstrate, again through quantitative analysis, the circumstances under which it would be beneficial (as well as those under which it would be counter-productive) to multicast control messages in the hope of suppressing duplicates and preventing the source from being overwhelmed by control messages     

Reliability of local area networks with bus and ring topologies

The reliability of local area networks with bus and ring topologies with a simple transfer medium are critically analysed. A double transfer medium is used to increase reliability. The efficiencies of these approaches are compared.