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31.
A pilot-scale sludge treatment plant was built to investigate the feasibility of ozonation processes for waste activated sludge treatment. Ozonation of wastewater sludge resulted in mass reduction by mineralization as well as by supernatant and filtrate recycle. Another advantage of sludge ozonation is a significant improvement of settleability and dewaterability. Experimental results showed that mass reduction of 70% and volume reduction of 85% compared with the control sludge was achieved through the sludge ozonation at a dose of 0.5?gO3/gDS. It is also interesting to note that the filterability deteriorates up to ozone dose of 0.2?gO3/gDS and then improves considerably at a higher ozone dose. The filterability could be improved by chemical conditioning even at a low ozone dose. The economic feasibility by cost analysis reveals that ozonation processes can be more economical than other alternative processes for sludge treatment and disposal at small-sized wastewater treatment plants. 相似文献
32.
Jong-Ho Ryu Jong Hyun Seo Jae-Han Jeong Sung-Kap Kim Dong Nyung Lee 《Journal of Applied Electrochemistry》2004,34(9):879-884
A study has been made of the electrochemical etching of 99.99% aluminum foils at a current density of 50 mA cm–2in AlCl3–HCl solutions (1 m Cl–) at 80 °C. The solutions were made by dissolving metallic aluminum into 1m HCl solution, to give a Cl– concentration of 1 m. The number density of etch tunnels and the homogeneity of tunnel length decreased, and the mean pit size and its standard deviation increased with increasing Al3+ concentration. The results were discussed based on potential transients at a current density of 50 mA cm–2, current–potential curves at a scan rate of 10 m Vs–1 and electrochemical impedance spectra. 相似文献
33.
Seong‐Ho Choi Min‐Seok Kim Jae Jeong Ryoo Kwang‐Pill Lee Hyun‐Dong Shin Sun‐Hwa Kim Yong‐Hyun Lee 《应用聚合物科学杂志》2002,85(11):2451-2457
Carboxylic acid groups were introduced onto polyethylene (PE) film by radiation‐induced graft copolymerization. Subsequently, the clodextrin glucanotransferase (CGTase) was immobilized on the PE film with a carboxylic acid group. The activity of the immobilized CGTase on PE film was in the range of 0.40–1.04 U/cm2 per min. The production of cyclodextrins (CDs) from corn starch was examined using the CGTase‐immobilized PE film. The production ratios of CDs using CGTase‐immobilized PE film was in the following order: α–CD > β–CD > γ–CD. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2451–2457, 2002 相似文献
34.
Do‐Hung Han Jae‐Hyuk Jang Hye‐Young Kim Byung‐Nam Kim Boo‐Young Shin 《Polymer Engineering and Science》2006,46(4):431-437
The high melt viscosity of polypropylene was studied by grafting bifunctional monomers, 1,6‐hexanediol diacrylate (HDDA) and tripropylene glycol diacrylate (TPGDA), onto homopolypropylene (HPP) and random ter‐polypropylene (RTPP) under electron‐beam irradiation. Creation of the high‐melt‐viscosity polypropylene was possible at low radiation dosage and low monomer content, under a prohibition of both radiation degradation and homopolymerization. TPGDA monomer was more effective in increasing the melt viscosity of HPP compared with RTPP, whereas HDDA monomer was more effective for enhancing the melt viscosity of RTPP. Such different effects of monomers on melt viscosity may arise from different monomer structures, namely, TPGDA has additional three methyl groups, but HDDA has no methyl groups. Electron‐beam radiation technology, on an increase of the melt viscosity, was much more effective in HPP than RTPP, when compared with virgin polymers. Modified RTPP and HPP with high melt viscosity were capable of foaming with numerous fine cells, of which the modified HPP with 1.5 mmol TPGDA and 0.5 kGy could create more spherical foam cells and its bending strength was 1.5 times more than that of the foamed RTPP. POLYM. ENG. SCI., 46:431–437, 2006. © 2006 Society of Plastics Engineers. 相似文献
35.
The reactive compatibilization of syndiotactic polystyrene (sPS)/oxazoline‐styrene copolymer (RPS)/maleic anhydride grafted ethylene‐propylene copolymer (EPR‐MA) blends is investigated in this study. First, the miscibility of sPS/RPS blends is examined by thermal analysis. The cold crystallization peak (Tcc) moved toward higher temperature with increased PRS, and, concerning enthalpy relaxation behaviors, only a single enthalpy relation peak was found in all aged samples. These results indicate that the sPS/RPS blend is miscible along the various compositions and RPS can be used in the reactive compatibilization of sPS/RPS/EPR‐MA blends. The reactive compatibilized sPS/RPS/EPR‐MA blends showed finer morphology than sPS/EPR‐MA physical blends and higher storage modulus (G') and complex viscosity (η*) when RPS contents were increased. Moreover, the impact strength of sPS/RPS/EPR‐MA increased significantly compared to sPS/EPR‐MA blend, and SEM micrographs after impact testing show that the sPS/RPS/EPR‐MA blend has better adhesion between the sPS matrix and the dispersed EPR‐MA phase. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2084–2091, 2002 相似文献
36.
Neung‐Ju Lee Ja‐Chul Koo Sung‐Suk Ju Seong‐Bae Moon Won‐Jei Cho In‐Cheol Jeong Song‐Jae Lee Moo‐Youn Cho Emmanuel A Theodorakis 《Polymer International》2002,51(7):569-576
The attachment of anticancer agents to polymers is a promising approach towards reducing the toxic side‐effects and retaining the potent antitumour activity of these agents. A new tetrahydrophthalimido monomer containing 5‐fluorouracil (ETPFU) and its homopolymer and copolymers with acrylic acid (AA) and with vinyl acetate (VAc) have been synthesized and spectroscopically characterized. The ETPFU contents in poly(ETPFU‐co‐AA) and poly(ETPFU‐co‐VAc) obtained by elemental analysis were 21 mol% and 20 mol%, respectively. The average molecular weights of the polymers determined by gel permeation chromatography were as follows: Mn = 8900 g mol?1, Mw = 13 300 g mol?1, Mw/Mn = 1.5 for poly(ETPFU); Mn = 13 500 g mol?1, Mw = 16 600 g mol?1, Mw/Mn = 1.2 for poly(ETPFU‐co‐AA); Mn = 8300 g mol?1, Mw = 11 600 g mol?1, Mw/Mn = 1.4 poly(ETPFU‐co‐VAc). The in vitro cytotoxicity of the compounds against FM3A and U937 cancer cell lines increased in the following order: ETPFU > 5‐FU > poly(ETPFU) > poly(ETPFU‐co‐AA) > poly(ETPFU‐co‐VAc). The in vivo antitumour activities of all the polymers in Balb/C mice bearing the sarcoma 180 tumour cell line were greater than those of 5‐FU and monomer at the highest dose (800 mg kg?1). © 2002 Society of Chemical Industry 相似文献
37.
Yongwon Seo Sung-Ho Jo Ho-Jung Ryu Hee Dal Bae Chong Kul Ryu Chang-Keun Yi 《Korean Journal of Chemical Engineering》2007,24(3):457-460
A bubbling fluidized bed reactor was used to study CO2 capture from flue gas by using a potassium-based solid sorbent, sorbKX35 which was manufactured by the Korea Electric Power
Research Institute. A dry sorbent, sorbKX35, consists of K2CO3 for absorption and supporters for mechanical strength. To increase initial CO2 removal, some amount of H2O was absorbed in the sorbent before injecting simulated flue gas. It was possible to achieve 100% CO2 removal for more than 10 minutes at 60°C and a residence time of 2 s with H2O pretreatment. When H2O pretreatment time was long enough to convert K2CO3 of sorbKX35 into K2CO3 · 1.5H2O, CO2 removal was excellent. The results obtained in this study can be used as basic data for designing and operating a large scale
CO2 capture process with two fluidized bed reactors.
This work was presented at the 6
th
Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
38.
Multifunctional monomers, m‐xylylenedimaleimide, p‐phenylenedimaleimide, m‐phenylenedimaleimide, and p‐phenylenedinadimide, all of which have maleimide groups, were synthesized to increase thermal and radiation stabilities. The synthesized multifunctional monomers showed good compatibility with low‐density polyethylene (LDPE). Mixtures of LDPE and these multifunctional monomers were irradiated with γ‐rays from a Co‐60 source at room temperature in a nitrogen atmosphere. The absorbed dose ranged from 0 to 160 KGy. Among these multifunctional monomers, m‐xylylenedimaleimide was the best in gel fraction enhancement. Crosslinked LDPE with m‐xylylenedimaleimide displayed a higher modulus than that of crosslinked LDPE with triallyl cyanurate. For the elongation property, LDPE with m‐xylylenedimaleimide as a multifunctional monomer showed better results than that with commercial multifunctional monomers such as triallyl cyanurate (TAC) and trimethylol propane triacrylate (TMPTA). © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2339–2345, 2003 相似文献
39.
Sang?Sung?Lee Soo?Chool?Lee Jae?Chang?KimEmail author 《Korean Journal of Chemical Engineering》2002,19(3):406-410
O-alkylation reaction of hydroquinone with excess methanol was performed by using alkali metal ion-exchanged zeolite catalysts
in a slurry type reactor to substitute the solid zeolite catalysts for the homogeneous liquid phase catalysts. This was also
done to produce selectively mono-alkylated 4-methoxyphenol, a valuable intermediate for the perfume, flavor, food and photo
industries. The effects of the basicity of various zeolites and reaction conditions such as temperature, reaction time and
the amount of catalyst on the catalytic activity and selectivity were tested to maximize the yield of 4-methoxyphenol. Thus
far, 84% selectivity at 95% conversion of hydroquinone was obtained at the optimum reaction conditions (240 ‡C, reaction with
0.6 g catalyst for 16 h), which was thought to result from the strong basic property and shape selectivity of the Cs ion-exchanged
NaX zeolite. 相似文献
40.
Jae Ryong Kim Do-Hyeong Kim Chong Hee Kim 《Journal of the American Ceramic Society》1990,73(8):2567-2569
The effects of ZrO2 and Y2 O3 on the densification of hotpressed Si3 N4 -Zr(Y)O2 composites have been studied. High density could not be obtained by the addition of pure or 3-mol%-Y2 O3 -doped ZrO2 in this composite; however, nearly full density (>97%) could be obtained in Si3 N4 using 6- and 8-mol%-Y2 O3 -doped ZrO2 . It is concluded that Y2 O3 diffusing out from the added Zr(Y)O2 promoted the densification and that ZrO2 also had some role in the formation of an oxynitride glass. 相似文献