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We present simulation results for a simple lattice gas cellular automata model of passivation. The lattice sites representing the corrosion product are produced at the corroding surface and diffuse executing a random walk. Asymmetric simple exclusion rules of the random walk account for an attractive potential between the corrosion product particles. The particles can aggregate and when sufficiently numerous form a compact phase on the corroding surface. The model predicts a transition from the active to passive state when increasing the reactivity of the surface. The transition is characterized by a sudden increase in the surface coverage of the corrosion product interpreted as a passive layer formation. The layer blocks contact of the metal surface with the environment and reduces the corrosion rate. The model reproduces the known paradox of passivity—the surface must be reactive enough for the layer to form. A further increase in the bare reactivity reduces largely the observed reaction rate. The simulations yield information on the morphological changes of the surface layer before and after the transition. In terms of the corrosion current, the active state is described by the current increase with the polarizing potential according to the Tafel law while in the passive state the current is independent of the anodic potential. Our simple model reproduces principal features of passivation. 相似文献
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Janusz Nowicki Adam Soko?owski Dagmara Reksa 《Journal of surfactants and detergents》2011,14(2):179-184
The synthesis of new cationic carbohydrate surfactants is presented in this paper. The obtained surfactants have structures that are typical for saponins, which contain fatty amide hydrophobic chains and hydrophilic heads with cationic carbohydrate units. Their surface active properties and biodegradability have been studied. For two types, the biodegradability was above 85% and comparable to standard carbohydrate surfactants. 相似文献
55.
Raquel Saavedra Luis B. Rocha Dr. Janusz M. Dąbrowski Prof. Luis G. Arnaut 《ChemMedChem》2014,9(2):390-398
Intravenous (i.v.) formulations with various amounts of organic solvents [PEG400, propylene glycol (PG), cremophor EL (CrEL)] were used to deliver a fluorinated sulfonamide bacteriochlorin to mice, rats, and minipigs. Biodistribution studies in mice showed that a low‐content CrEL formulation combines high bioavailability with high tumor‐to‐muscle and tumor‐to‐skin ratios. This formulation was also the most successful in the photodynamic therapy of mice with subcutaneously implanted CT26 murine colon adenocarcinoma tumors. Pharmacokinetic studies in mice and minipigs revealed that with the same low CrEL formulation, the half‐life of the photosensitizer in the central compartment was longer in minipigs. Differences in biodistribution with the various formulations, and in pharmacokinetics between the two animal species with the same formulation, are attributed to the interaction of the formulations with low‐density lipoproteins (LDLs). Skin photosensitivity studies in rats showed that 30 min exposure of the skin to a solar simulator 7 days after i.v. administration of the fluorinated sulfonamide bacteriochlorin at 1 mg kg?1 did not elicit significant skin reactions. 相似文献
56.
The cycloaddition of CO2 to epoxides represents a green efficient method to form bis(cyclic carbonate)s. The main purpose of the work reported in this paper was to examine the effect of the gas flow rate (20, 40, 60 and 100 mL min–1) during carbonation on the conversion yield, chemical structure, rheological behaviour and thermal properties of the prepared compounds. A series of new bis(cyclic carbonate)s was obtained from bio‐based polyether polyol. The syntheses were performed in the absence of toxic solvents and the process did not require the use of elevated pressure. The progressive structural changes and the presence of characteristic chemical groups were monitored by attenuated total reflection Fourier transform infrared spectroscopy. The characterization of the structure by 1H NMR and 13C NMR also confirmed the formation of cyclic carbonate moieties. The non‐Newtonian behaviour and the optimal mathematical model (Herschel–Bulkley) were verified by rheological measurements. The materials obtained could be used as a chemical intermediate to synthesize advanced materials based upon polyurethanes without using isocyanates. © 2019 Society of Chemical Industry 相似文献
57.
Defect Chemistry of (La,Sr)MnO3 总被引:1,自引:0,他引:1
Defect-disorder models are derived for undoped and strontium-doped LaMnO3 . A random-defect model and a cluster-defect model are both considered within the regimes that correspond to oxygen deficit and oxygen excess. The models are constructed based on the experimental nonstoichiometry data that was reported by previous researchers. According to both models, the addition of strontium leads to an increase of the concentration of electron holes and oxygen nonstoichiometry. The defect clusters that are predicted by the cluster model have a marked concentration only at very low oxygen partial pressures. Both models are verified against the electrical-conductivity data. A good agreement between the random-defect model and the experimental data is shown. 相似文献
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59.
Bujnicki Janusz M.; Rotkiewicz Piotr; Kolinski Andrzej; Rychlewski Leszek 《Protein engineering, design & selection : PEDS》2001,14(10):717-721
Using a recent version of the SICHO algorithm for in silicoprotein folding, we made a blind prediction of the tertiarystructure of the N-terminal, independently folded, catalyticdomain (CD) of the I-TevI homing endonuclease, a representativeof the GIYYIG superfamily of homing endonucleases. Thesecondary structure of the I-TevI CD has been determined usingNMR spectroscopy, but computational sequence analysis failedto detect any protein of known tertiary structure related tothe GIYYIG nucleases (Kowalski et al., Nucleic AcidsRes., 1999, 27, 21152125). To provide further insightinto the structurefunction relationships of all GIYYIGsuperfamily members, including the recently described subfamilyof type II restriction enzymes (Bujnicki et al., Trends Biochem.Sci., 2000, 26, 911), we incorporated the experimentallydetermined and predicted secondary and tertiary restraints ina reduced (side chain only) protein model, which was minimizedby Monte Carlo dynamics and simulated annealing. The subsequentlyelaborated full atomic model of the I-TevI CD allows the availableexperimental data to be put into a structural context and suggeststhat the GIYYIG domain may dimerize in order to bringtogether the conserved residues of the active site. 相似文献
60.
Agata Winiarska Monika Knysak Katarzyna Nabrdalik Janusz Gumprecht Tomasz Stompr 《International journal of molecular sciences》2021,22(19)
The incidence of type 2 diabetes (T2D) has been increasing worldwide, and diabetic kidney disease (DKD) remains one of the leading long-term complications of T2D. Several lines of evidence indicate that glucose-lowering agents prevent the onset and progression of DKD in its early stages but are of limited efficacy in later stages of DKD. However, sodium-glucose cotransporter-2 inhibitors (SGLT2i) and glucagon-like peptide-1 receptor (GLP-1R) agonists were shown to exert nephroprotective effects in patients with established DKD, i.e., those who had a reduced glomerular filtration rate. These effects cannot be solely attributed to the improved metabolic control of diabetes. In our review, we attempted to discuss the interactions of both groups of agents with inflammation and oxidative stress—the key pathways contributing to organ damage in the course of diabetes. SGLT2i and GLP-1R agonists attenuate inflammation and oxidative stress in experimental in vitro and in vivo models of DKD in several ways. In addition, we have described experiments showing the same protective mechanisms as found in DKD in non-diabetic kidney injury models as well as in some tissues and organs other than the kidney. The interaction between both drug groups, inflammation and oxidative stress appears to have a universal mechanism of organ protection in diabetes and other diseases. 相似文献