Impact of Blend Morphology on Interface State Recombination in Bulk Heterojunction Organic Solar Cells

This work is a reinvestigation of the impact of blend morphology and thermal annealing on the electrical performance of regioregular‐P3HT:PC₆₀BM bulk heterojunction organic solar cells. The morphological, structural, and electrical properties of the blend are experimentally investigated with atomic force microscopy, X‐ray diffraction, and time‐of‐flight measurements. Current–voltage characteristics of photodiode devices are measured in the dark and under illumination. Finally, the existence of exponential electronic band tails due to gap states is experimentally confirmed by measuring the device spectral response in the subband gap regime. This method reveals the existence of a large density of gap states, which is partially and systematically reduced by thermal annealing. When the band tails are properly accounted for in the drift and diffusion simulations, experimentally measured charge transport characteristics, under both dark and illuminated conditions and as a function of annealing time, can be satisfactorily reproduced. This work further confirms the critical impact of tails states on the performance of solar cells.     

Cell‐Tethered Ligands Modulate Bone Remodeling by Osteoblasts and Osteoclasts

The goals of the present study are to establish an in vitro co‐culture model of osteoblast and osteoclast function and to quantify the resulting bone remodeling. The bone is tissue engineered using well‐defined silk protein biomaterials in 2D and 3D formats in combination with human cells. Parathyroid hormone (PTH) and glucose‐dependent insulinotropic peptide (GIP) are selected because of their roles in bone remodeling for expression in tethered format on human mesenchymal stem cells (hMSCs). The cell‐modified biomaterial surfaces are reconstructed from scanning electron microscopy images into 3D models for quantitative measurement of surface characteristics. Increased calcium deposition and surface roughness are found in 3D surface models of silk protein films remodeled by co‐cultures containing tethered PTH, and decreased surface roughness is found for the films remodeled by tethered GIP co‐cultures. Increased surface roughness is not found in monocultures of hMSCs expressing tethered PTH, suggesting that osteoclast‐osteoblast interactions in the presence of PTH signaling are responsible for the increased mineralization. These data point towards the design of in vitro bone models in which osteoblast‐osteoclast interactions are mimicked for a better understanding of bone remodeling.     

A Review of Three‐Dimensional Resistive Switching Cross‐Bar Array Memories from the Integration and Materials Property Points of View

Issues in the circuitry, integration, and material properties of the two‐dimensional (2D) and three‐dimensional (3D) crossbar array (CBA)‐type resistance switching memories are described. Two important quantitative guidelines for the memory integration are provided with respect to the required numbers of signal wires and sneak current paths. The advantage of 3D CBAs over 2D CBAs (i.e., the decrease in effect memory cell size) can be exploited only under certain limited conditions due to the increased area and layout complexity of the periphery circuits. The sneak current problem can be mitigated by the adoption of different voltage application schemes and various selection devices. These have critical correlations, however, and depend on the involved types of resistance switching memory. The problem is quantitatively dealt with using the generalized equation for the overall resistance of the parasitic current paths. Atomic layer deposition is discussed in detail as the most feasible fabrication process of 3D CBAs because it can provide the device with the necessary conformality and atomic‐level accuracy in thickness control. Other subsidiary issues related to the line resistance, maximum available current, and fabrication technologies are also reviewed. Finally, a summary and outlook on various other applications of 3D CBAs are provided.     

Vanadium Doping Enhanced Electrochemical Performance of Molybdenum Oxide in Lithium‐Ion Batteries

Molybdenum trioxide (MoO₃) suffers from poor conductivity, a low rate capability, and unsatisfactory cycling stability in lithium‐ion batteries. The aliovalent ion doping may present an effective way to improve the electrochemical performances of MoO₃. Here, it is shown, by first‐principle calculations, that doping MoO₃ with V by 12.5% can modulate significantly electronic structure and provide a small diffusion barrier for enhancing the electrochemical performance of MoO₃. The ultralong Mo_0.88V_0.12O_2.94 nanostructures, which retain the h‐MoO₃ structure and present an exceptionally high conductivity and fast ionic diffusion due to the substitution of V, facilitating lithiation/delithiation behavior, and induce a fine nanosized structure with a reduced volume change are prepared. As a result, the stress and strain are alleviated during the Li‐ion intercalation/deintercalation processes, improving the cycling stability and rate capability. Such a large improvement in the electrochemical properties can be ascribed to the stabilizing effect of V, the small migration energy barrier, and short diffusion path, which arise from the introduction of V into MoO₃. The unique engineering strategy and facile synthesis route open up a new avenue in modifying and developing other species of electrode materials.     

Analyse de la stabilité spectrale d’un laser DFB à trois sauts de phase (3PS-DFB)

The aim of this article is to analyze the spectral stability of the three phase shift distributed feedback (3ps-dfb) laser by using Time domain model (tdm). We have developed a software that simulates static and dynamic properties of distributed feedback (dfb) multi-sections laser at large signal. The best single-mode stability operation up to 18mW of the 3ps-dfb is achieved for three phase shifts at (π, π, π) whatever the phase position. These results showed that the 3ps-dfb laser was a much more suitable structure to realize stable single-mode high-power operation for a coherent optical communication system.     

Solid‐State Electrode Materials with Ionic‐Liquid Properties for Energy Storage: the Lithium Solid‐State Ionic‐Liquid Concept.

Herein, the novel concept of a solid‐state electrode materials with ionic‐liquid (IL) properties is presented. These composite materials are a mixture of electroactive matter, an electronic conductor, a solid‐state ionic conductor and a polymeric binder. The approach of a solid‐state ionic conductor combines the high safety of an IL with the nanoconfinement of such a liquid in a mesoporous silica framework, an ionogel, thus leading to a solid with liquid‐like ionic properties. The same ionic conductor is also used as a solid‐state separator to evaluate the properties of our solid‐state electrode materials in all‐solid‐state batteries. Such a concept of a solid‐state electrode material contributes to addressing the challenge of energy storage, which is one of the major challenges of the 21^st century. The ionogel, along with its processability, allows a single‐step preparation of the assembly of the solid‐state electrode and solid‐electrolyte separator and can be applied without specific adaptation to present, thick electrodes prepared by the widespread tape‐casting technique. The filling of the electrode porosity by an ionogel is shown by elemental mapping using scanning electron microscopy, and is subsequently confirmed by electrochemical measurements. The ionogel approach is successfully applied without specific adaptation to two state‐of‐the‐art, positive electroactive materials developed for future‐generation lithium‐ion batteries, namely LiFePO₄ and LiNi_1/3Mn_1/3Co_1/3O₂.     

New CMOS Class AB Transmitter for 10 Gb/s Serial Links

This paper presents a new fully differential CMOS class AB transmitter for 10 Gb/s serial links. The transmitter consists of a fully differential multiplexer, a rail-to-rail configured pre-amplification stage, and a push-pull output stage. The multiplexer achieves a high multiplexing speed by using modified pseudo-NMOS logic where pull-up networks are replaced with self-biased active inductors. The rail-to-rail configured pre-amplification stage with active inductors amplifies the signals from the multiplexer. The fully differential output current is generated by a class AB output stage operated in a push-pull mode. High data rates of the transmitter are obtained by ensuring that the transistors in both the pre-amplification and output stages are always in saturation and the voltage swing of all critical nodes is small. The fully differential configuration of the transmitter effectively suppresses common-mode disturbances, particularly those coupled from the power and ground rails, the electro-magnetic interference exerted from channels to neighboring devices is also minimized. The transmitter minimizes switching noise by drawing a constant current from the supply voltage. The transmitter has been implemented in TSMC 0.18 μm 1.8 V 6-metal CMOS technology and analyzed using Spectre from Cadence Design Systems with BSIM3.3 device models. Simulation results demonstrate that the transmitter provides a 5 mA peak-to-peak differential output current with 100 ps eye-width and >5 mA eye-height at 10 Gb/s. The transmitter consumes 18 mW with a total transistor area of 100 μm² approximately. Jean Jiang received the B.Eng. degree in Electrical Engineering from Wuhan University of Technology, Wuhan, China in 1995, and the M.A.Sc. degree in Electrical and Computer Engineering from Ryerson University, Toronto, Ontario, Canada in 2004. From 1999 to 2001, she worked for Ericsson Global IT Services where she was a technical staff to maintain computer networks. From 2002 to 2004, she was a research assistant and a M.A.Sc. student with the Microsystem Research Laboratory in the Department of Electrical and Computer Engineering at Ryerson University. She is now with Intel Corp., CA. as an IC design engineer. Her research interests are in analog CMOS circuit design for high-speed data communications. Jean Jiang was awarded the Ontario Graduate Scholarship in 2003–2005 for academic excellence. Fei Yuan received the B.Eng. degree in electrical engineering from Shandong University, Jinan, China in 1985, the M.A.Sc. degree in chemical engineering and Ph.D. degree in electrical engineering from University of Waterloo, Waterloo, Ontario, Canada in 1995 and 1999, respectively. During 1985–1989, he was a Lecturer in the Department of Electrical Engineering, Changzhou Institute of Technology, Jiangsu, China. In 1989 he was a Visiting Professor at Humber College of Applied Arts and Technology, Toronto, Ontario, Canada, and Lambton College of Applied Arts and Technology, Sarnia, Ontario, Canada. He was with Paton Controls Limited, Sarnia, Ontario, Canada as a Controls Engineer during 1989–1994. Since 1999 he has been with the Department of Electrical and Computer Engineering, Ryerson University, Toronto, Ontario, Canada, where he is currently an Associate Professor and the Associate Chair for Undergraduate Studies and Faculty Affairs. He is the co-author of the book Computer Methods for Analysis of Mixed-Mode Switching Circuits (Springer-Verlag, 2004, with Ajoy Opal). Dr. Yuan received the Ryerson Research Chair award from Ryerson University in Jan. 2005, the Research Excellence Award from the Faculty of Engineering and Applied Science of Ryerson University in 2004, the post-graduate scholarship from Natural Science and Engineering Research Council of Canada during 1997–1998, and the Teaching Excellence Award from Changzhou Institute of Technology in 1988. Dr. Yuan is a senior member of IEEE and a registered professional engineer in the province of Ontario, Canada.     

Model-based implementation of distributed systems with priorities

Model-based application development aims at increasing the application’s integrity by using models employed in clearly defined transformation steps leading to correct-by-construction artifacts. In this paper, we introduce a novel model-based approach for constructing correct distributed implementation of component-based models constrained by priorities. We argue that model-based methods are especially of interest in the context of distributed embedded systems due to their inherent complexity (e.g., caused by non-deterministic nature of distributed systems). Our method is designed based on three phases of transformation. The input is a model specified in terms of a set of behavioral components that interact through a set of high-level synchronization primitives (e.g., rendezvous and broadcasts) and priority rules for scheduling purposes. The first phase transforms the input model into a model that has no priorities. Then, the second phase transforms the deprioritized model into another model that resolves distributed conflicts by incorporating a solution to the committee coordination problem. Finally, the third phase generates distributed code using asynchronous point-to-point message passing primitives (e.g., TCP sockets). All transformations preserve the properties of their input model by ensuring observational equivalence. All the transformations are implemented and our experiments validate their effectiveness.     

A New Criteria Decision Applied on the Primary Synchronization in the DS-WCDMA Interface of the UMTS System

In DS-WCDMA mobile systems such the UMTS, asynchronous cell site operation,assigning different long spreading code to each cell, yields the advantageof flexible system deployment. We can design an indoor system basedon an outdoor one. However, in general, much longer search time isrequired in asynchronous operation than in synchronous. This paperproposes three techniques to take decisions about synchronizationbased on observation of correlated signals. Classical decision criterialike maximum and threshold criterion are presented. A new decisioncriteria that we call Threshold&Max combined decision criteriais analyzed. The results of this new introduced technique is comparedwith the classical ones.