An X-ray absorption spectroscopy study of Mo oxidation in Pb at elevated temperatures

The corrosion of fuel cladding and structural materials by lead and lead-bismuth eutectic in the liquid state at elevated temperatures is an issue that must be considered when designing advanced nuclear systems and high-power spallation neutron targets. In this work, lead corrosion studies of molybdenum were performed to investigate the interaction layer as a function of temperature by X-ray absorption spectroscopy. In situ X-ray absorption measurements on a Mo substrate with a 3-6 μm layer of Pb deposited by thermal evaporation were performed at temperatures up to 900 °C and at a 15° angle to the incident X-rays. The changes in the local atomic structure of the corrosion layer are visible in the difference extended X-ray absorption fine structure and the linear combination fitting of the X-ray absorption near-edge structure to as-deposited molybdenum sample and molybdenum oxide (MoO₂ and MoO₃) standards. The data are consistent with the appearance of MoO₃ in an intermediate temperature range (650-800 °C) and the more stable MoO₂ phase dominating at high and low temperatures.     

TPS6108x:极具多功能的升压转换器

引言 TPS61080与TPS61081是高集成度升压转换器,这两种器件的可调输出电压可达27 V,而输入电压则可低至2.5V.     

Quantitative analysis of micro structural and conductivity evolution of Ni-YSZ anodes during thermal cycling based on nano-computed tomography

Understanding the mechanism of degradation in solid oxide fuel cells (SOFCs) using nickel/yttria-stabilized zirconia (Ni-YSZ) as the anode material is very important for the optimization of cell performance. In this work, the effects of thermal cycling on the microstructure of the Ni-YSZ anode are explored using the three-dimensional X-ray nano computed tomography (nano-CT) imaging technique. It is found that the average Ni particle size increased with thermal cycling, which is associated with the decreased connectivity of the Ni phase and the three-phase-boundary (TPB) length. Moreover, the conductivities of the anode samples are also reduced with the increase in thermal cycle times. The implication of these observations is discussed in terms of the relationship between the conductivity and connectivity of the Ni phase.     

SoSyM significantly reduces its backlog

Software and Systems Modeling -     

Does Kripke’s Argument Against Functionalism Undermine the Standard View of What Computers Are?

Kripke’s argument against functionalism extended to physical computers poses a deep philosophical problem (not previously addressed in the literature) for understanding the standard view of what computers are. The problem puts into jeopardy the definition in the standard view that computers are physical machines for performing physical computations. Indeed, it is entirely possible that, unless this philosophical problem is resolved, we will never have a good understanding of computers and may never know just what they are.     

Computational analysis of citric acid pertraction in emulsion liquid membranes

Citric acid is one of the most widely used acids in industry, and its recovery from waste streams is critical. Emulsion liquid membrane (ELM) is one of the most effective recovery methods that has been investigated in recent years. Numerous transport phenomena parameters affect the efficiency of this process. From the process equipment design point of view, optimization based on overall cost is of great importance, and important equipment sizing decisions/constraints must be considered. A physics-based model for a full-scale simulation of ELM systems is very useful. This work is focused on developing and verifying such a model. A coupled particle/mixture simulation was carried out in this work, and the modelling results were fitted on the experimental data. The novelty of this modelling work is physics-based results based on the system's geometry and its effects on the mass transfer resistances. Since the model is physics-based, the model is capable of simulating similar systems with any geometry or experimental conditions.