Energy efficient office buildings with passive cooling – Results and experiences from a research and demonstration programme

To gain access to information on energy use in office buildings, the German Federal Ministry for Economy launched an intensive research and demonstration programme in 1995. In advance of the 2002 EU energy performance directive a limited primary energy coefficient of about 100 kW h m⁻² a⁻¹ as a goal for the complete building services technology was postulated (HVAC + lighting) for all demonstration buildings to be supported. A further condition was that active cooling be avoided. Techniques such as natural or mechanical night ventilation or heat removal by slab cooling with vertical ground pipes as well as earth-to-air heat exchangers in the ventilation system were applied. An accompanying research was established to keep track of the results and the lessons learned from about 22 demonstration buildings realized and monitored until the end of 2005. As one outcome this paper summarises the energy performance of a selection of characteristic buildings together with an overview on the summer thermal comfort situations achieved. The research program will proceed during the next five years. Detailed reports and future results may be downloaded from the internet: www.enbau-monitor.de.     

Reversible and irreversible degradation of organic solar cell performance by oxygen

The effect of oxygen on the degradation of inverted bulk heterojunction solar cells based on poly(3-hexylthiophene):[6,6]-phenyl-C₆₁-butyric acid methyl ester (P3HT:PCBM) blends has been investigated by monitoring current-voltage (jV)-curves, impedance spectra and charge extraction by linearly increasing voltage (CELIV) traces during the degradation process. The use of gas permeable top electrodes allows monitoring the kinetics of degradation without being limited by the diffusion through a compact metal electrode. A computational model is used to provide a phenomenological explanation of the experimental results. The charge distribution inside the device is modeled by solving the fully coupled set of nonlinear differential equations for the quasi-one-dimensional transport of electrons and holes.Degradation of the cells in the presence of oxygen results mainly in the reduction of short circuit current (j_sc), while the concomitant loss in light absorption is negligible. The rate of degradation is enhanced significantly by illumination. A significant part of the loss in j_sc is reversible upon annealing under nitrogen or in vacuum.The irreversible part of the degradation is assigned to the photochemical formation of carbonyl and carboxylic groups, which act as traps for electrons. The reversible component of degradation is due to p-doping of the photoactive layer by oxygen, which results in the formation of mobile holes and immobile superoxide anions. This leads to the formation of a space charge region in front of the electron extracting electrode whose width depends on the doping level as well as on the applied bias. The space charge region shields the electric field inside the photoactive layer and hence hampers charge carrier extraction, which leads to the observed loss in short circuit current.     

Indium doped niobium phosphates as intermediate temperature proton conductors

Indium doped niobium phosphates were prepared from precursors of trivalent indium oxide, pentavalent niobium oxide and phosphoric acid. The obtained materials were characterized by X-ray diffraction, impedance spectroscopy, FT-IR spectroscopy and scanning electron microscopy. It was found that the indium doping promoted formation of the cubic Nb₂P₄O₁₅ phase instead of the monoclinic Nb₅P₇O₃₀ phase in the pristine niobium phosphates and enhanced the preservation of OH functional groups in the phosphates. The preserved OH functionalities in the phosphates after the heat treatment at 650 °C contributed to the anhydrous proton conductivity. The Nb_0.9In_0.1 phosphate exhibited a proton conductivity of five times higher than that of the un-doped analog at 250 °C. The conductivity was stabilized at a level of above 0.02 S cm⁻¹ under dry atmosphere at 250 °C during the stability evaluation for 3 days.     

Flexible organic P3HT:PCBM bulk-heterojunction modules with more than 1 year outdoor lifetime

Flexible organic solar cells and modules based on P3ht:PCBM bulk-heterojunctions were fabricated and their lifetime was investigated under laboratory and outdoor conditions. In the laboratory cells were exposed to 1 sun illumination at 65 °C in order to accelerate the degradation. The outdoor behavior of modules was investigated at the Konarka rooftop testing setup in Lowell, MA (USA). We show that these flexible polymer solar cells have a good light stability, passing 1000 h under accelerated light soaking conditions in the laboratory, and that flexible modules survived over 1 year of outdoor exposure without performance losses.     

A new linear time algorithm to compute the genomic distance via the double cut and join distance

The genomic distance problem in the Hannenhalli–Pevzner (HP) theory is the following: Given two genomes whose chromosomes are linear, calculate the minimum number of translocations, fusions, fissions and inversions that transform one genome into the other. This paper presents a new distance formula based on a simple tree structure that captures all the delicate features of this problem in a unifying way, and a linear time algorithm for computing this distance.     

Doping front migration in intrinsically conductive polymers and its application

Doping front migration is a recently discovered effect occurring in sandwich structures composed of intrinsically conductive polymers. A system based on chemical or electrochemical doping is capable of controlling an integrated display and modifying the electrical resistance of the conductive polymer. The effect does not require a battery and is capable of monitoring time and temperature exposure. Low-cost devices using doping front migration could be the basis of a new class of smart labels for applications such as electronic “best before” labels on food and drink.     

The Falling Lake Victoria Water Level: GRACE,TRIMM and CHAMP Satellite Analysis of the Lake Basin

In the last 5 years, Lake Victoria water level has seen a dramatic fall that has caused alarm to water resource managers. Since the lake basin contributes about 20% of the lakes water in form of discharge, with 80% coming from direct rainfall, this study undertook a satellite analysis of the entire lake basin in an attempt to establish the cause of the decline. Gravity Recovery And Climate Experiment (GRACE), Tropical Rainfall Measuring Mission (TRMM) and CHAllenging Minisatellite Payload (CHAMP) satellites were employed in the analysis. Using 45 months of data spanning a period of 4 years (2002–2006), GRACE satellite data are used to analyse the variation of the geoid (equipotential surface approximating the mean sea level) triggered by variation in the stored waters within the lake basin. TRMM Level 3 monthly data for the same period of time are used to compute mean rainfall for a spatial coverage of .25°×.25° (25×25 km) and the rainfall trend over the same period analyzed. To assess the effect of evaporation, 59 CHAMP satellite’s occultation for the period 2001 to 2006 are analyzed for tropopause warming. GRACE results indicate an annual fall in the geoid by 1.574 mm/year during the study period 2002–2006. This fall clearly demonstrates the basin losing water over these period. TRMM results on the other hand indicate the rainfall over the basin (and directly over the lake) to have been stable during this period. The CHAMP satellite results indicate the tropopause temperature to have fallen in 2002 by about 3.9 K and increased by 2.2 K in 2003 and remained above the 189.5 K value of 2002. The tropopause heights have shown a steady increase from a height of 16.72 m in 2001 and has remained above this value reaching a maximum of 17.59 km in 2005, an increase in height by 0.87 m. Though the basin discharge contributes only 20%, its decline has contributed to the fall in the lake waters. Since rainfall over the period remained stable, and temperatures did not increase drastically to cause massive evaporation, the remaining major contributor is the discharge from the expanded Owen Falls dam.