干熄焦高温矩形膨胀节在线修复与维护

针对鞍钢股份有限公司炼焦总厂4#干熄焦系统高温矩形膨胀节内部浇筑料脱落问题,分析了膨胀节损坏原因,提出了在线修复与维护技术。通过采取减少锅炉入口温度波动、膨胀节内部挂件改型、改进膨胀节浇筑方式、增加膨胀节膨胀缝的密封、强化升温前养护与升温过程控制等措施,有效延长了干熄焦年修周期,实现了年修周期为2年的目标,年修时长缩短了20%,年修费用降低了约41.4%,干熄焦生产效率由98%提高至98.3%。     

Closure of Internal Porosity in Continuous Casting Bloom During Heavy Reduction Process

Metallurgical and Materials Transactions B - To investigate the closure behavior of internal porosity (also referred to as internal void) in continuous casting bloom during heavy reduction (HR) and...     

主链型偶氮苯改性聚芳酰胺的合成及表征

在以N,N二甲基乙酰胺为溶剂,三乙胺为酸吸收剂的条件下,将自制的反式-4,4'-偶氮苯二甲酰氯与对苯二胺进行低温缩聚反应,合成了1种新型的反式偶氮苯聚芳酰胺.用红外光谱、示差热扫描量热分析,热重分析,偏光显微镜,紫外光谱对其结构及性能进行了表征.合成的聚合物表现出了一定的结晶性能,聚合物的稀溶液呈现出溶致液晶行为.     

沉积压力对Parylene C膜性能的影响

采用X射线衍射(XRD),MOCON透湿仪等研究了不同沉积压力下制备ParyleneC膜的结晶度、水蒸汽透过性、拉伸强度、雾度、透明度随沉积压力的变化规律.结果表明,随着沉积室压力升高,Parylee C膜相对结晶度、透湿性能、拉伸强度、透明度下降,雾度增大.     

加入世贸组织后的我国无损检测

论述加入世贸组织（WTO）后,我国无损检测面临的挑战与机遇。为了增强制造工业的国际竞争力,无损检测将出现空前良好的机遇,必须抓住这一机遇,以发展新技术为主,实现技术的跨越,并提出在实施技术跨越发展时需要注意的若干方面。     

有限元网格质量和材料黏度模型对注塑件翘曲分析的影响

利用Moldflow分析了吸尘器轴承座的成型过程,通过细化构件的有限元网格和对比网格质量,检验了有限元分析结果收敛性,确认需要结合网格质量来改进计算过程。构件变形的有限元分析结果与实测数据进行比较,在最大翘曲的估计方面效果较好,显示了对注塑过程和构件进行精确分析的重要性。文中也尝试采用不同的黏度模型对注塑件翘曲进行分析,保证分析方法的一致和完整,为基于有限元分析的模具设计和加工过程优化积累经验。     

刺梨果汁饮料的贮藏稳定性及其货架期预测

目的 提高刺梨果汁饮料的贮藏稳定性及评估其保质期。方法 刺梨果汁饮料经均质、微波杀菌等处理后于25 ℃贮藏30 d,探究加工工艺(均质时间、杀菌时间、稳定剂种类)对饮料理化性质的影响。根据主要活性成分的含量随贮藏时间及贮藏温度的变化,利用动力学方程和Arrhenius方程建立刺梨果汁饮料的货架期模型并预测其货架期。结果 当均质时间为3~5 min、微波杀菌时间2~4 min,添加0.1% l-卡拉胶时,刺梨果汁饮料的稳定性较好;贮藏试验显示,相比总黄酮含量,刺梨果汁饮料中Vc含量与贮藏时间相关性更高,且符合零级反应(R2> 0.900);根据Arrhenius方程预测出刺梨果汁饮料在4、25、45 ℃的货架期分别为226、126、78 d。验证试验表明,预测Vc含量与实测Vc含量之间的相对误差均低于10%。结论 适当的加工处理可提高刺梨果汁饮料的贮藏品质,延长其保质期。Arrhenius方程适合于刺梨果汁饮料品质及货架期的评估。     

Supercritical CO2 oil extraction from Chinese star anise seed and simultaneous compositional analysis using HPLC by fluorescence detection and online atmospheric CI‐MS identification

BACKGROUND: Supercritical CO₂ was utilised to extract Chinese star anise seed oil (CSASO), and a three‐level Box–Behnken factorial design from response surface methodology was applied to optimise the extraction conditions, including pressure, temperature and amount of modifier (ethanol). The compositional analysis of fatty acids in CSASO was performed by HPLC with fluorescence detection using 2‐(11H‐benzo[a]carbazol‐11‐yl)‐ethyl‐4‐methylbenzenesulfonate (BCETS) as labelling reagent. Identification was carried out by online atmospheric chemical ionisation–mass spectrometry. RESULTS: The optimum extraction conditions were as follows: extraction pressure, 27.72 MPa, extraction temperature, 46.22 °C, and amount of modifier, 8.58 vol.%. The experimental result showed that the maximum extraction yield was 25.31 ± 0.22% (w/w) under the conditions proposed. The compositional analysis indicated that CSASO mainly contained C18:2, C18:1, C18:3, C20:4, C16, C18 and C20 fatty acids. CONCLUSION: In this study, a fast, simple and high‐efficiency supercritical technique for extracting oil from Chinese star anise seed was developed. Simultaneous determination of fatty acids in CSASO using BCETS as the labelling reagent with HPLC fluorescence detection and online mass spectroscopy identification has been successfully achieved. Copyright © 2010 Society of Chemical Industry