基于增量型广义预测控制协调控制系统研究

在分析协调控制对象动态特性的基础上,将广义预测控制应用于协调控制系统锅炉主调节器中。预测控制对处理大迟延对象具有独特的优势,实现参数的在线、实时自调整。仿真结果表明,采用的控制算法具有良好的控制品质,是一种可行的控制方案。对于研究非线性、参数时变的控制系统提供了一种新的思路,具有一定的理论意义和工程应用价值。     

陶瓷超滤膜用于盐湖卤水提锂合格液的中试研究

为解决纳滤膜用于盐湖卤水镁锂分离中长时间运行后出现通量下降、膜污染和分离效率下降的问题,开展了将陶瓷超滤膜作为纳滤预处理措施用于盐湖卤水提锂合格液的中试研究。中试设在吸附提锂车间,进水为提锂工序中的合格液。结果表明,在冬天低温环境合格液浊度<50 NTU的条件下,以及在合格液浊度上升至50~170 NTU的极端进水水质条件下,陶瓷超滤膜均可在300 L/（m ²·h）的测试通量下稳定运行,过滤时间为30~50 min/周期。产水浊度稳定<0.1 NTU,优于后续纳滤系统进水要求。     

用于盐湖卤水吸附法提锂的连续离子交换工艺研究

采用连续离子交换技术用于盐湖卤水的吸附法提锂。针对青海一里坪盐湖老卤体系,开发了连续离子交换吸附提锂工艺,研究了操作参数对连续离子交换系统提锂性能的影响,并在优化的工艺条件下进行了长周期的稳定性评价。结果表明,在转动步进周期为20 min、卤水进料量为3.2 BV/h、淋洗水量为2.9 BV/h、解吸水量为9.3 BV/h、解吸温度为15~25 ℃时,连续离子交换系统可以稳定获得镁锂质量浓度比（简称镁锂比）在3左右、锂质量浓度接近1.1 g/L的合格液,锂回收率为98.5%以上。     

多点驱动带式输送机功率平衡机制研究

针对多点驱动带式输送机功率不平衡降低输送效率及生产寿命问题,对多电机间的协调控制进行研究。对传统偏差耦合多电机协调控制结构进行了改进,增加了基于转速功率控制的同步误差补偿器,通过求取所有电机的平均转速和单台电机的转速差,利用PI控制器,同时结合每台电机的系统转速跟踪误差,反馈补偿到每台电机的控制回路进行多电机协调控制。仿真结果表明,系统可以在负载变化扰动的情况下有效降低各电机的同步误差,特别是对系统刚启动时负载不均衡导致的电机功率不平衡问题,改进结构可以有效实现多电机间的功率平衡分配。     

Physicochemical characteristics,antioxidant capacity and thermodynamic properties of purple-fleshed potatos dried by radio frequency energy

Abstract

The impacts of using radio frequency (RF) energy to dry purple-fleshed potatoes were investigated and compared to infrared radiation (IR) and microwave (MW) drying techniques. The gelatinization rate, color, flavor, morphological, and structural characteristics, thermodynamic properties, as well as antioxidant capacity were examined. The results indicated that the drying time of RF (70?min) and MW (21?min) were shorter than IR (105?min). The gelatinization ratio of MW, RF, and IR were 94.4?±?2.0, 88.3?±?1.4, and 64.5?±?1.1%, respectively. The degree of crystallization of purple-fleshed potato powder decreased with all three drying methods. RF-dried potatoes were able to retain higher polyphenols (loss rate: 4.3%), total anthocyanin (3.7%), and total flavonoid content (35.1%), whereas IR showed the lowest retention. The content of polyphenols also decreased significantly. Furthermore, after RF heating, the scavenging of free radicals was higher compared to MW and IR.     

亲水性PET共混材料的制备及性能研究

以机械共混法制备亲水性聚对苯二甲酸乙二醇酯（PET）共混材料,并通过接触角测定仪、差示扫描量热仪(DSC)和电子万能材料试验机等对共混材料的亲水性能、热性能和力学性能等进行研究与分析。结果表明,亲水处理剂聚乙二醇（PEG）、聚丙烯酸钠（PAAS）、聚乙烯吡咯烷酮（PVP）均能改善PET的亲水性能,影响PET的结晶性能,但亲水处理剂对PET的力学性能影响较小,其中PET/PEG共混材料的亲水性最优;随着PEG含量的增加,PET/PEG共混材料的亲水性先逐渐增强,当PEG含量高于5 %后,共混材料的亲水性变化很小;且PET的结晶度随着PEG的加入呈现先增大后减小的趋势。     

粉末注射成型技术的研究和应用

介绍了粉末注射成型技术的概念和工艺,包括金属粉末注射成型(MIM)、陶瓷粉末注射成型(CIM),讲述了黏结剂的使用发展情况;阐述了粉末注射成型专用注射成型机的特点,PIM粉末注射专用塑化系统,PIM专用料斗滑块装置,镶套式机筒座等,介绍了PIM技术在诸多行业中的应用,3C行业,医疗行业,汽车行业等,并展望了PIM研究的发展方向。     

Fast Chemo‐Responsive Shape Memory of Stretchable Polymer Nanocomposite Aerogels Fabricated by One‐Step Method

A new type of stretchable poly(caprolactone)/graphene oxide (PCL/GO) aerogel with fast chemo‐responsive shape memory effect is fabricated by one‐step method of a sol‐gel procedure. The PCL/GO aerogels show uniformly circular and interconnected pores formed by twisted PCL nanolayers. GO platelets improve the crystallinity of PCL and increase the fracture stress and strain by 150% and 300% respectively, although the GO loading is only 0.5%. The dramatic increment of break strain is attributed to the uniform and circular pores that can afford large deformation and the interaction of GO and PCL. The aerogels can be programmed by external stress at ambient temperature without heating and recover upon ethyl acetate (EA) in 1 s. The fast chemo‐responsive shape recovery is ascribed to the fast wrinkle of the PCL nanolayers that decrease the diffusion time greatly and the interconnected micrometer pores that are in favor of penetrating for EA molecules.     

Highly efficient synthesis of(R)-1,3-butanediol via anti-Prelog reduction of 4-hydroxy-2-butanone with absolute stereoselectivity by a newly isolated Pichia kudriavzevii

(R)-1,3-butanediol is an important pharmaceutical intermediate, and the synthesis of(R)-1,3-butanediol using green biological methods has recently been of interest for industrial application. Here, a novel strain QC-1 that efficiently transforms 4-hydroxy-2-butanone to(R)-1,3-butanediol was isolated from soil samples. Based on morphological, physiological, and biochemical tests and 5.8 S-internal transcribed spacer sequencing, the strain was identified as Pichia kudriavzevii QC-1. The reaction conditions were optimized to 35 ℃, pH 8.0, rotation speed 200 rpm, and 6:5 mass ratio of glucose to 4-hydroxy-2-butanone. Evaluation of the effects of 4-hydroxy-2-butanone concentrations on yield and cell survival rate showed that 85.60 g·L~(-1) product accumulated, with an enantiomeric excess of more than 99%, when 30 g·L~(-1)4-hydroxy-2-butanone was added at 0, 10, and 30 h in a 3-L bioreactor. Thus, strain QC-1 showed excellent catalytic activity and stereoselectivity for the synthesis of(R)-1,3-butanediol from 4-hydroxy-2-butanone.