地震厚度趋势法在乐乡关地垒剥蚀量恢复中的应用

应用地震厚度趋势法恢复乐乡关隆起地层剥蚀量,探讨盆地沉积充填特征、构造旋回阶段划分及其演化,分析各期潜北断层活动强度及对沉积的控制和影响。总体上,潜北断层在荆河镇-潜一段、潜四下沉积时期对地层沉积具有强烈的控制作用,在荆河镇组、潜四下沉积时期潜北断层下降盘应存在陡坡扇三角洲沉积。     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

纳豆芽孢杆菌菌剂的制备工艺

采用单因素及正交试验对纳豆芽孢杆菌发酵培养基、pH、温度、发酵时间等条件进行了考察,利用喷雾干燥法制备菌剂,考察了β-环糊精、蔗糖、可溶性淀粉及脱脂奶粉作为保护剂对菌剂制备的影响,并研究了储藏时间及条件对菌剂发酵活力的影响.研究结果表明:纳豆芽孢杆菌发酵培养基为黄豆浸汁培养基:黄豆以5倍水体积浸泡8~14h,121℃~126℃,0.1~0.15MPa处理1h,滤除黄豆,取豆水,加入5%的葡萄糖和0.02%的K2HPO4,调节pH至7.0;最优发酵工艺:初始pH7.0,37℃发酵10h;喷雾干燥最佳保护剂为5%脱脂奶粉;菌剂4℃冷藏180d以内不影响发酵活力.上述工艺下所制得的纳豆芽孢杆菌菌剂活菌数为6.5×108 CFU/g,发酵生产纳豆激酶性能良好.发酵生产纳豆激酶酶活为2 000~2 200IU/g.本研究为纳豆芽孢杆菌菌剂制备提供了一条较为合理的工艺路线.     

Hydrophobically modified melamine-formaldehyde sponge used for conformance control and water shutoff during oil production

Polymer or polymer gels have been widely used to control excessive water during oil production by homogenizing injection profile and reducing water cut in the produced fluids. However, the gels used are generally unable to selectively minimize water production, and face the challenge of syneresis of gels under high temperature and high salinity environment. In this work, melamine-formaldehyde sponge was modified with AlCl₃ solution, rendering a transition from hydrophilic to hydrophobic state with a water contact angle of 130° on the surface of the modified product. Filtration results show that mineral oil and water can be selectively separated with the hydrophobically modified sponge powders. Simulated water shutoff experiments demonstrated the blockage efficiency against water was 30% higher than that against oil, and the oil production was increased 7.4% after blocking. The parallel profile control tests confirmed that the fraction flow of high permeable channel decreased about 75%, accompanied with 60% rise of oil recovery factor. These results indicated that such hydrophobic materials can significantly reduce excessive water production, and this work provided a new idea to offer a low-cost hydrophobic material for conformance control and water shutoff during oil production.     

Engineering oxygen vacancy-rich Co3O4 nanowire as high-efficiency and durable bifunctional electrocatalyst for overall alkaline water splitting

A novel kind of vacancy-rich nanowire arrays were prepared by reducing rough Co₃O₄ nanowires with NaBH₄ solution on 3D nickel foam at room temperature for overall water splitting. Co₃O₄/NF treated by NaBH₄ for 10 min was highly active for oxygen evolution reaction (OER) and simultaneously efficient for hydrogen evolution reaction (HER) with the need of the overpotentials of 240 and 132 mV to drive 10 mA·cm^-2 in alkaline media, respectively. Furthermore, the electrocatalysts as both cathode and anode in a two-electrode system presented excellent durability for over 60 h at 10 mA·cm^-2, maintaining the cell voltage of merely 1.63 V. This work provides new methods and ideas for the preparation of transition metal oxide bifunctional electrocatalysts rich in oxygen vacancies.     

脉冲MIG焊接电弧的闭环控制

作者研究成功了一种用于脉冲MIG焊接电弧的闭环控制系统,称为QH-ARC-102控制法。它具有优异的静态及动态品质。无论脉冲或者维弧阶段,电弧的工作点均位于三极管焊接电源阶梯形外特性的恒流段上。因此,电弧稳定,始终保持喷射过渡,飞溅极少,电流的调节范围也较宽广.在每个脉冲期间,均对弧长讯号进行采样以实现对弧长的闭环控制。因此电弧具有很强的抗弧长干扰能力,而且其脉冲工艺参数能够自动优化,可以适应送丝速度大范围的突变。本控制系统对脉动送丝或程序送丝MIG 焊接新工艺比较适用。如用于实现全位置焊接、焊缝成型控制、线能量控制以及熔深的闭环自动控制等,特别是对机器人焊接更为适用。文章论述了本系统的工作原理,介绍了实用的电路图,并且给出了一些焊接结果。     

Ti和V对Fe中氢与位错交互作用的影响

研究了Fe-0.5wt-%Ti和Fe-0.5wt-%V合金中由氢与位错交互作用所形成的氢致冷加工内耗峰(H-CWP)。实验结果表明:合金元素对H-CWP、对氢与位错之间的交互作用有显著的影响,与氢作用愈强的元素,对H-CWP的影响愈大,内耗实验结果与力学性能之间存在着一定的联系.     

电磁动态金属粉末注射成型型坯结构性能的研究

利用自行设计的电磁动态注射机DPII-90，对不锈钢金属粉末316L和粘结剂的混合喂料进行稳态和动态注塑成型实验，研究振动参数对金属粉末和粘结剂混合喂料的均匀化和密实机理的影响。实验结果表明，各动态成型条件下的型坯密度明显大于稳态成型条件下的密度。当振动频率（或振幅）不变时，随着振幅（频率）的增大，型坯密度呈非线性增大，达到最大值后缓慢下降，存在一个最佳值。在频率7Hz-10Hz，振幅50μm～150μm的范围内，注射出的型坯密度较高，密实性好。电镜扫描（SEM）发现，金属粉末与粘结剂的分散均匀和完善程度的变化规律和型坯密度随着振幅（频率）的变化规律基本一致。     

LD7铝合金阳极氧化膜的不同封闭方法耐蚀性评价

研究了不同封闭方法对LD7铝合金阳极氧化膜在NaCl溶液中耐蚀性的影响,包括沸水封闭、氟化镍封闭、重铬酸钾封闭和醋酸镍封闭.利用动电位极化和电化学阻抗谱（EIS）研究了封闭后阳极氧化膜的腐蚀行为.利用扫描电子显微镜（SEM）观察了封闭后阳极氧化膜的表面形貌.结果表明在酸性溶液和碱性溶液中醋酸镍封闭能提供更高的耐蚀性,而沸水封闭在中性溶液中较耐蚀.工业生产中普遍采用的重铬酸钾封闭对LD7铝合金阳极氧化膜封闭效果并不理想,封闭后的阳极氧化膜在不同pH值的溶液中耐蚀性均不高,氟化镍封闭的阳极氧化膜层耐酸性不强.     

加入WTO给当代大学生带来的若干思考

入世对大学人才培养目标、社会人才需求、大学生知识结构、学习理念、就业市场等提出了新的要求，当代大学生必须提高自身的综合素质，培养创新能力，开阔国际视野，重视非智力因素的培养等，以此来适应WTO对人才的需求。