Solitary wave trains in granular chains: experiments,theory and simulations

The features of solitary waves observed in horizontal monodisperse chain of barely touching beads not only depend on geometrical and material properties of the beads but also on the initial perturbation provided at the edge of the chain. An impact of a large striker on a monodisperse chain, and similarly a sharp decrease of bead radius in a stepped chain, generates a solitary wave train containing many single solitary waves ordered by decreasing amplitudes. We find, by simple analytical arguments, that the unloading of compression force at the chain edge has a nearly exponential decrease. The characteristic time is mainly a function involving the grains’ masses and the striker mass. Numerical calculations and experiments corroborate these findings.     

Trace metal concentration in water and sediments of satellite lakes within Lake Victoria (Kenya) basin

Lakes Kanyaboli, Sare and Namboyo are three important freshwater satellite lakes in the northern region of the Lake Victoria (Kenya) basin. Lake Simbi, a small alkaline -saline crater-lake is located near the southern shoreline of the Nyanza Gulf of Lake Victoria. The three freshwater lakes provide unique aquatic habitats for the important indigenous fish species and other aquatic biodiversity, as well as serving as water resources for the surrounding communities. Surface and sediment samples were collected and examined to characterize these lake systems. Metal partitioning among the various defined geochemical phases also was determined. Based on the measured concentrations, the satellite lake waters are relatively uncontaminated with regard to Al (aluminium), manganese (Mn), zinc (Zn), copper (Cu) and chromium (Cr). Levels of most elements were below detection limits, as well as being well below the desirable drinking water guideline values proposed by the World Health Organization. The exception was the elevated iron (Fe) contents (>300 μg L⁻¹). The sediments exhibited a relatively low level of contamination with regard to heavy metals. The mean values of the measured metals in the sediments were compared to levels in adjacent Lake Victoria. The study results from these poorly-studied, and relatively unperturbed ecosystems, compared to the main body of lake Victoria, highlight their importance as conservation areas, despite the small-scale fishery activity, potential threats from human activities and their sensitivity to fluctuating environmental conditions.     

Thermal inkjet printing of polyaniline on paper

The development of organic devices requires the fabrication of thin films, and inkjet printing has been shown to be a suitable method to reach this goal. This work describes the printing process and characterisation of polyaniline (PANI) printed on bond and photographic papers using a desktop inkjet thermal printer. To enable printing, a solution composed by PANI, n-methyl-2-pyrrolidone, ethylene glycol, alcohol and water must be prepared. PANI is printed on bond and photographic paper and then doping of PANI is performed by hydrochloric acid vapour exposure. Micro-Raman spectroscopy showed that PANI printed on paper keeps its basic characteristics. The results from electrical measurements showed that the surface resistivity of the printed PANI samples decreases by increasing the printing number, i.e. the number of layers that were deposited, and depends slightly on the paper type. A stretched semicircle followed by a linear upward tail, attributed to Warburg impedance combined with other intrinsic mechanisms of PANI on porous media, are always present on the Cole-Cole plots obtained for doped-PANI on bond paper. It was shown that these parameters significantly change with the relative humidity, opening the possibility to apply PANI/paper-based devices as humidity sensors.     

Synthesis of transition metal-doped carbon xerogels by solubilization of metal salts in resorcinol–formaldehyde aqueous solution

The pore texture of carbon materials obtained from evaporative drying and pyrolysis of resorcinol–formaldehyde aqueous gels is controlled by the initial pH of the precursors solution. In order to produce transition metal-containing carbons with tailored texture, various metallic salts were dissolved in the precursors solution. When necessary, a complexing agent (HEDTA or DTPA) was added to render the metal ions soluble. Ni, Fe and Pd loaded carbon xerogels were synthesized and their pore texture was studied after evaporative drying and after pyrolysis. The carbon texture was also studied with regard to the nature of the metal and the amount of complexing agent. The solubilization of transition metal salts in the resorcinol–formaldehyde aqueous solution does not prevent the texture regulation, even though this texture control is influenced: the limits of the pH interval leading to micro–mesoporous carbon materials can slightly differ when a metal salt and/or a complexing agent are added. The pH range shift depends mainly on the amount and nature of the complexing agent, but also slightly on the nature of the metal ion. Nevertheless, the metal particles obtained are rather big (diameter > 15 nm). For catalytic applications, the metal dispersion must be enhanced, especially in the case of expensive metals.     

Motor vehicle accidents, fatigue and optimism bias in taxi drivers

The H2-receptor antagonist cimetidine reduces appetite and weight in overweight healthy subjects and in overweight subjects with type II diabetes mellitus. The aim of this study was to characterize the mechanisms of this effect in rodents. Drugs were administered three times a day, 30 min before 1 h periods of free access to food. In one group of rats (n = 9), cimetidine (8 mg) treatment resulted in significantly lower cumulative food intake than in a control group (n = 9). The total intakes of food during the observation period of 22 days were 325.3 +/- 29.1 g and 346.3 +/- 16.7 g in the cimetidine and control groups, respectively. During the observation period, the weight gain in the cimetidine group was 63.3 +/- 15.8 g, which was significantly lower than the weight gain of 74.8 +/- 14.2 g in the control group, i.e. the cimetidine induced a 15.4% reduction in the weight gain during the observation period of 22 days. The weight gained per weight of food ingested was 0.20 +/- 0.04 (g/g) and 0.22 +/- 0.04 (g/g) in the cimetidine and control groups, respectively (NS). In other experiments, ranitidine (3 mg) and famotidine (0.4 mg), but not omeprazole (0.4 mg), taken three times a day for 8 days reduced the weight gain when compared with a control group (n = 7 in each group). We therefore conclude that the effects of the H2-receptor antagonists are not mediated by inhibitory mechanisms on the gastric acid secretion.     

Self-assembly route for photonic crystals with a bandgap in the visible region

Three-dimensional photonic crystals, or periodic materials, that do not allow the propagation of photons in all directions with a wavelength in the visible region have not been experimentally fabricated, despite there being several potential structures and the interesting applications and physics that this would lead to. We show using computer simulations that two structures that would enable a bandgap in the visible region, diamond and pyrochlore, can be self-assembled in one crystal structure from a binary colloidal dispersion. In our approach, these two structures are obtained as the large (Mg) and small (Cu) sphere components of the colloidal analogue of the MgCu(2) Laves phase, whose growth can be selected and directed using appropriate wall patterning. The method requires that the particles consist of different materials, so that one of them can be removed selectively after drying (for example, by burning or dissolution). Photonic calculations show that gaps appear at relatively low frequencies indicating that they are robust and open for modest contrast, enabling fabrication from more materials.     

Assessment of maize yield gap and major determinant factors between smallholder farmers in the Dedza district of Malawi

This study explored the effect of soil nutrient status, agronomic practices and socio-economic factors on maize yield attained by smallholder farmers in the Dedza District of Malawi. Results show that maize yield ranged between 0.4 and 12 t ha^?1 with a mean value of 4.1 t ha^?1. Observed high yields (>8.0 t ha^?1) were associated with households using improved varieties combined with improved management practices such as NPK, urea and animal manure. With regards to soil factors, boron (B) and nitrogen (N) which are critically deficient in the area were significantly (β = 21.1, p < 0.01) associated with maize yield increase. From agronomic factors, weeds, seed spacing, plant density and fertilizer application played significant role in maize yield. Weed rating inversely impacted yield (β = ?0.5; p < 0.001) where fields with the lowest weed rating had the highest yield (4.6 t ha^?1) than those with the highest rating (2.3 t ha^?1). Socio-economic factors such as household wealth, household members with off-farm employment, number of years the household head has been involved in farming decision making, access to agricultural advice and group membership also influenced agronomic practices and resulted in yield gap. Household wealth and off-farm employment contributed to increased yield while household head experience in farming had negative impact. Extension service impacted yield negatively which can be attributed to the low extension worker to farmer ratio. The study demonstrated that closing yield gap in maize mixed farming systems requires integrated approach to addressing agronomic, biophysical and socio-economic constraints.