Aquatic passive sampling of herbicides on naked particle loaded membranes: accelerated measurement and empirical estimation of kinetic parameters

Water-sampler equilibrium partitioning coefficients and aqueous boundary layer mass transfer coefficients for atrazine, diuron, hexazionone and fluometuron onto C18 and SDB-RPS Empore disk-based aquatic passive samplers have been determined experimentally under a laminar flow regime (Re = 5400). The method involved accelerating the time to equilibrium of the samplers by exposing them to three water concentrations, decreasing stepwise to 50% and then 25% of the original concentration. Assuming first-order Fickian kinetics across a rate-limiting aqueous boundary layer, both parameters are determined computationally by unconstrained nonlinear optimization. In addition, a method of estimation of mass transfer coefficients--therefore sampling rates--using the dimension-less Sherwood correlation developed for laminar flow over a flat plate is applied. For each of the herbicides, this correlation is validated to within 40% of the experimental data.The study demonstrates that for trace concentrations (sub 0.1 microg/L) and these flow conditions, a naked Empore disk performs well as an integrative sampler over short deployments (up to 7 days) for the range of polar herbicides investigated. The SDB-RPS disk allows a longer integrative period than the C18 disk due to its higher sorbent mass and/or its more polar sorbent chemistry. This work also suggests that for certain passive sampler designs, empirical estimation of sampling rates may be possible using correlations that have been available in the chemical engineering literature for some time.     

The Influence of System Pressure on Bubble Coalescence in Nucleate Boiling

Boiling is one of the most effective heat transfer mechanisms. In spite of a long time of research, the physical fundamentals are still not sufficiently understood. Pursuing the objective to predict heat transfer based on physical and geometrical properties, experimental and numerical investigations are conducted at the institute of the authors. The focus of the presented research is the coalescence of two single bubbles under varying pressure conditions. In the experiment a thin stainless-steel foil is used as a Joule heater. The experiments were performed in a pressure range of 300–1000 mbar using FC72 as working fluid. Two types of heaters with a distance between two artificial nucleation sites of 300 μm (type 3) and 500 μm (type 5) were used. The experimental results indicate a strong dependence of the occurrence of bubble coalescence on pressure. For the type 5 heater, a Gaussian distribution for the coalescence frequency when plotted over pressure is observed. Experimental results with the type 3 heater show a similar distribution of the frequency with a shifted maximum. Further, it is shown that during bubble coalescence a small droplet can remain inside the bubble and enhance the heat transfer, which is attributed to an additional thin film region. The formation of this remaining droplet is sensitive to system pressure. Numerical investigations of bubble coalescence were conducted with the computational fluid dynamics (CFD) software OpenFOAM. In OpenFOAM, dynamic mesh handling allows high spatial resolution at the phase boundary, which is captured with the volume-of fluid method. Evaporation and a subgrid microscale model were implemented in the flow solver to account for evaporation at the phase boundary and the three-phase contact line. The results show a strong dependence of bubble dynamics and coalescence on contact angle and bubble growth rate. Although it was possible to observe the creation of the residual droplet, more effort needs to be put into finding appropriate initial conditions.     

Effects of growth and breed on the fatty acid composition of the muscle lipids in cattle

 The adipose tissue development in muscle and the fatty acid composition of intramuscular fat of 200 bulls from three different breeds during growth was investigated. There were significant differences in quantitative and qualitative fat deposition which were genetically caused. The muscle of Galloway and White-blue Belgian bulls contained a high n–3 fatty acid content which is positive for human nutrition. During growth an increased deposition of saturated fatty acids into the adipocytes of muscle was observed.     

Improved mapping of in-mouth creaminess of semi-solid dairy products by combining rheology,particle size,and tribology data

The effects of fat, protein, and casein to whey protein ratio on lubricating properties of stirred yogurt were determined and the relation of those to the sensory properties graininess, viscosity, and creaminess was assessed. Results demonstrated decreased friction effects with increasing fat and protein level, and decreasing proportion of whey protein. The predictive ability of in-mouth viscosity (r² = 0.91) and in-mouth creaminess (r² = 0.97) could be improved by combined assessments of rheological, particle size, and tribological characteristics. Graininess was not affected by friction data. To this end, the applicability of generated models has been tested. This study depicts a better understanding of the key drivers for creaminess and enables food manufacturers to develop fat-reduced dairy products without compromise on sensory properties.     

Das Management des Produktionsfaktors Anlage – Von der betrieblichen Instandhaltung zur ganzheitlichen integrierten Anlagenbewirtschaftung

This article discusses the development of maintenance management connected to the research at the Department of Economics and Business Management (WBW), Montanuniversität Leoben. Beginning with functionally oriented approaches of maintenance management systems, the article shows the evolution to sophisticated management systems for an integrated plant asset management as well as further research needs in this area.     

Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis,Characterization, and Single-Molecule Force Spectroscopy

Self-assembly by H-bonding and by metal-coordination of functionalized calix[4]arenes and cavitands to large supramolecular capsules is described. In addition, a new method of analyzing supramolecular recognition processes at the single molecule level is discussed. By measuring interaction forces in a hydrogen-bonded assembly using single-molecule force spectroscopy (SMFS), the dynamics of the self-assembly process can be evaluated. In the future, consequent application of this new technique will influence supramolecular design principles and the use of non-covalent interactions as construction elements in the field of nanotechnology.     

Verhalten von Mauerwerksbauten unter Erdbebeneinwirkung: Auswertung der Schäden des Albstadt‐Erdbebens vom 3. September 1978

Numerische Untersuchungen zum Verhalten von Mauerwerksbauten unter Erdbebeneinwirkung führen oft zu pessimistischen Schadensprognosen, welche im Gegensatz zu den Beobachtungen stehen. Um diesen Widerspruch aufzulösen, werden erfahrungsbasierte Verletzbarkeitsfunktionen für typische Mauerwerksgebäude auf der Grundlage der durch das Erdbeben vom 3. September 1978 bei Albstadt (mit einer Lokalmagnitude M_L von 5,7 und Epizentralintensität I₀ = VII—VIII) verursachten Schäden entwickelt. Anhand des Bauwerksbestandes von 1978 erfolgt die Einordnung der beobachteten Schäden in Schadensgrade auf Basis der European Macroseismic Scale EMS‐98 [1]. Die für den Bauwerksbestand repräsentativen Bauweisen werden herausgearbeitet; für die vorherrschenden Gebäude aus unbewehrtem Mauerwerk ist eine weitere Unterscheidung nach Baualter, Geschosszahl und phänomenologischen Gesichtspunkten möglich. Vulnerability of masonry structures under seismic action: Damage analysis of the September 3, 1978 Albstadt earthquake. Numerical studies of the earthquake behavior of masonry buildings in Central Europe based on national building codes acc. to the Eurocode 8 lead to pessimistic damage prognoses, which are in contradiction to the observed behavior. In order to eliminate this discrepancy realistic experience‐based vulnerability and displacement functions for typical masonry constructions are developed. Because of the rather limited number of earthquake damage observations, the Magnitude M_L 5.7 Albstadt earthquake from September 3, 1978 (intensity VII—VIII) in South Germany also based on its excellent documentation is reconstructed with the building stock existing at that time. The prevailing building types and for these the characteristic damage cases are investigated in close cooperation with the local authorities. The presented unreinforced masonry structures are divided by year of construction, number of storeys and phenomenological aspects.