Systematische Erfassung und Bewertung von Spätfolgen des Steinkohlenbergbaus in Südlimburg/Niederlande

Currently a basis is established for a scientifically sound and sustainable handling of the potential consequences of former hard coal mining in the South Limburg hard coal mining district. Hard coal mining was abandoned by 1975; however, protective dewatering was conducted until 1993. Mine water has been rising over a wide area since that time.     

Estimation of mass transfer velocity based on measured turbulence parameters

The aim of this study is to quantify the mass transfer velocity using turbulence parameters from simultaneous measurements of oxygen concentration fields and velocity fields. The surface divergence model was considered in more detail, using data obtained for the lower range of β (surface divergence). It is shown that the existing models that use the divergence concept furnish good predictions for the transfer velocity also for low values of β, in the range of this study. Additionally, traditional conceptual models, such as the film model, the penetration‐renewal model, and the large eddy model, were tested using the simultaneous information of concentration and velocity fields. It is shown that the film and the surface divergence models predicted the mass transfer velocity for all the range of the equipment Reynolds number used here. The velocity measurements showed viscosity effects close to the surface, which indicates that the surface was contaminated with some surfactant. Considering the results, this contamination can be considered slight for the mass transfer predictions. © 2009 American Institute of Chemical Engineers AIChE J, 2010     

Nitrogen management in organic farming: comparison of crop rotation residual effects on yields,N leaching and soil conditions

After 3 years of different crop rotations in an organic farming experiment on a sandy soil in northwest Germany, spring triticale was cultivated on all plots in the fourth year to investigate residual effects on yield, nitrogen (N) leaching and nutrient status in the soil. Previous crop rotations differed in the way N was supplied, either by farmyard manure (FYM, 100 and 200 kg N ha⁻¹ year⁻¹) or by arable legumes like grass-red clover and field beans, or as a control with no N. Other crops in the rotations were maize, winter triticale and spring barley. Additional plots had a 3-year grass-clover ley, that was ploughed-in for spring triticale in the fourth year. Yields of spring triticale were moderate and largest for ploughed-in grassland leys and grass-red clover and plots that had previously received farmyard manure. The former crop rotation, including grassland break-up, had a significant effect on most yield and environmental parameters like residual soil mineral nitrogen (SMN) and N leaching and on the level of available K in the soil. The single crop harvested in the year before spring triticale had a significant effect on yield parameters of spring triticale, less so on SMN and N leaching in the fourth year and no effect on available nutrients (P, K, Mg) and pH in the soil. We conclude that the effects of arable legumes were rather short lived while ploughing of 3-year grassland leys had a profound influence on mineralization processes and subsequently on yield and N losses.     

Entwurf und Konstruktion der Egg‐Graben Brücke

Aufgrund der hohen Erhaltungskosten von Brücken gibt es mittlerweile unterschiedliche Ansätze, um die Dauerhaftigkeit zu erhöhen. Vorgespannte Brücken ohne Betonstahl stellen hierfür einen neuen Ansatz dar. Zur Erforschung des Tragverhaltens solcher Strukturen wurde ein Forschungsprojekt gestartet und Großversuche durchgeführt. Die Landesbaudirektion Salzburg war von dieser innovativen Idee überzeugt und hat deshalb die Technologie beim Bau der Egg‐Graben Brücke ausgeschrieben. Die Egg‐Graben Brücke ist eine im Grundriss gekrümmte Bogenbrücke mit einer Länge von 50 m. Nach einer Bauzeit von 18 Monaten erfolgte im November 2009 die Freigabe für den Verkehr. Der vorliegende Aufsatz beschreibt die Technologie, den Entwurf sowie die beim Bau der Brücke gesammelte Erfahrung. Design and Construction of the Egg‐Graben Bridge Due to the high maintenance costs of bridges, there are now various approaches to enhance the durability. Post tensioned bridges without steel reinforcement represent one of these approaches. To investigate the structural behaviour of such constructions, a research project was started and large‐scale tests were carried out. The government of the province of Salzburg could be convinced of this innovative technology and tendered out the method for the construction of the Egg‐Graben Bridge. For the arch bridge, which is curved in plan, the superstructure is prestressed without using further steel reinforcement. After a construction period of 18 months the bridge was opened to traffic in November 2009. The paper describes the technology, the design and the experience gained from the construction of the bridge.     

Beyond low-level activity: on a "non-radioactive" gas mantle

Gas mantles for camping gas lanterns sometimes contain thorium compounds. During the last years, the use of thorium-free gas mantles has become more and more popular due to the avoidance of a radioactive heavy metal. We investigated a gas mantle type that is declared to be "non-radioactive" and that can be bought in Austria at the moment. Methods used were Instrumental Neutron Activation Analysis (INAA), gamma-spectroscopy, and Liquid Scintillation Counting (LSC). We found massive thorium contents of up to 259 mg per gas mantle. Leaching experiments showed that only 0.4% of the Th but approximately 90% of the decay products of (232)Th can be leached under conditions simulating sucking and chewing with human saliva. In this paper, the investigation of these gas mantles including the consideration of the environmental hazard caused by disposed mantles and the health hazard for unsuspecting consumers is presented and legal consequences are discussed for this fraud.     

Exposure assessment of a burning ground for chemical ammunition on the Great War battlefields of Verdun

The destruction of arsenical shells from the 1914/18 war in the vicinity of Verdun (France) during the 1920s resulted in a locally limited but severe soil contamination by arsenic and heavy metals. At the study site, the main part of the contaminant inventory occurs in the upper 20 cm of the topsoil which is essentially composed of combustion residues. Besides, some Cu (cmax.=16,877 mg/kg) and Pb (cmax.=26,398 mg/kg) in this layer, As (cmax.=175,907 mg/kg) and Zn (cmax.=133,237 mg/kg) were detected in very high concentrations. The mobilities of Cu, Mn, Pb and Zn in the soil system were derived from ammonium nitrate eluates. They are strongly influenced by the soil pH and can be described by quadratic regression curves from which threshold pH values were calculated. Below these values more than 10% of the element content was available as mobile species. Within the examined pH range, this method could not be adopted for arsenic, because the mobility of As was only slightly controlled by the soil pH. In the heavily contaminated topsoil, Cu and Pb were fixed by the moderately acidic soil pH which varied from 4.8 to 5.8. No migration to the underlying horizons occurred. A different behavior was observed for As and Zn. The calculated threshold pH of Zn was 5.5, so certain amount of this element was transferred to the subsoil and the leachate (cmax.=350 microg/l). However, a major dispersion of Zn was prevented by a rise of the soil pH in the carbonate-containing subsoil. Elevated concentrations of As were found in all soil horizons up to a depth of 2 m and also in the leachate (cmax.=2377 microg/l). Contrary to Cu, Pb and Zn the mobility of As evidently was less affected by the subsoil. Regarding organic contaminants, nitroaromatic explosives were detected only in minor concentrations in the soil (cmax.=14.7 mg/kg) and the leachate (cmax.=13.5 microg/l). No aromatic organoarsenicals were detected in the soil and the leachate samples. The main hazard of the site is the severe arsenic contamination and the transfer of this carcinogen by leachate, surface runoff and probably by wind. Nevertheless, some studies on the effects of the contaminant inventory on the local vegetation revealed that ammonium nitrate elutable zinc is responsible for the spatial distribution of some tolerant plant species and not arsenic. Previously undetected buried munitions from the former delaboration facility can be an other source of environmental contaminants. This is supported by elevated concentrations of chlorate (cmax.=71 mg/l) and perchlorate (cmax.=0.8 mg/l) detected in the leachate samples. This is the second report about environmental contamination related to post-war ammunition destruction activities along the 1914/18 Western Front.     

Phosphorus speciation in manure and manure-amended soils using XANES spectroscopy

Previous studies suggested an increase in the proportion of calcium phosphates (CaP) of the total phosphorus (P) pool in soils with a long-term poultry manure application history versus those with no or limited application histories. To understand and predict long-term P accumulation and release dynamics in these highly amended soils, it is important to understand what specific P species are being formed. We assessed forms of CaP formed in poultry manure and originally acidic soil in response to different lengths of mostly poultry manure applications using P K-edge X-ray absorption near-edge structure (XANES) spectroscopy. Phosphorus K-edge XANES spectra of poultry manure showed no evidences of crystalline P minerals but dominance of soluble CaP species and free and weakly bound phosphates (aqueous phosphate and phosphate adsorbed on soil minerals). Phosphate in an unamended neighboring forest soil (pH 4.3) was mainly associated with iron (Fe) compounds such as strengite and Fe-oxides. Soils with a short-term manure history contained both Fe-associated phosphates and soluble CaP species such as dibasic calcium phosphate (DCP) and amorphous calcium phosphate (ACP). Long-term manure application resulted in a dominance of CaP forms confirming our earlier results obtained with sequential extractions, and a transformation from soluble to more stable CaP species such as beta-tricalcium calcium phosphate (TCP). Even after long-term manure application (> 25 yr and total P in soil up to 13,307 mg kg(-1)), however, none of the manure-amended soils showed the presence of crystalline CaP. With a reduction or elimination of poultry manure application to naturally acidic soils, the pH of the soil is likely to decrease, thereby increasing the solubility of Ca-bonded inorganic P minerals. Maintaining a high pH is therefore an important strategy to minimize P leaching in these soils.     

Critical review of models for H2-permeation through polymers with focus on the differential pressure method

To reduce loss of hydrogen in storage vessels with high energy-to-weight-ratio, new materials, especially polymers, have to be developed as barrier materials. Very established methods for characterization of barrier materials with permeation measurements are the time-lag and flow rate method along with the differential pressure method, which resembles the nature of hydrogen vessel systems very well. Long measurement durations are necessary to gain suitable measurement data for these evaluation methods, and often restrictive conditions have to be fullfilled. For these reasons, common models for hydrogen permeation through single-layer and multi-layer membranes, as well as models for hydrogen gas properties were collected and reviewed. Using current computer power together with these models can reduce measurement time for characterization of the barrier properties of materials, while additional information about the quality of the measurement results is obtained.     

A two-dimensional homogenized model for a pile of thin elastic sheets with frictional contact

The present paper deals with the computational simulation of a pile of thin sheets. The sheets are not laminated or glued, but they interact by frictional contact. In general, it is not possible to perform a full-scale finite element contact computation for piles containing thousands of sheets; the problem size becomes too large, and numerical solution methods suffer from severe convergence problems due to the large number of strongly coupled contact conditions. In this paper, a macroscopic material model is presented for the two-dimensional case. The pile of sheets is homogenized by introducing an effective anisotropic constitutive law, which is motivated by formulations of the theory of elasto-plasticity. This macroscopic material law models the behavior of a pile of sheets, allowing for no tensile stresses in the direction normal to the sheets and obeying Coulomb??s law of friction in the tangential contact plane. Applying this macroscopic material model, an equivalent homogeneous body can be treated using much coarser discretizations. Computational results for the problems are provided, and a comparison with simplified contact computations is done.     

Gesetze als Vorbild für Security Policies

Gesetzestexte und den Gesetzgebungsprozess daraufhin zu untersuchen, ob sich von ihnen etwas für Unternehmensrichtlinien zur Informationssicherheit lernen l?sst, scheint auf den ersten Blick ein fragwürdiges Unterfangen zu sein — immerhin ist die Unverst?ndlichkeit der Rechtssprache fast legend?r. Dass das Ringen der Juristen um „gute“ Gesetze dennoch nützliche Anregungen für Policy-Autoren hergibt, hat einen guten Grund: Genau dort, wo die Sprachreformer unter den Juristen aufgrund der Sachzw?nge, in denen sie stecken, nur ?u?erst mühevoll weiterkommen, k?nnen IT-Verantwortliche von ihnen lernen, wenn sie die Rechtstexte und ihren Entstehungsprozess nicht einfach nachzuahmen versuchen. Unternehmen n?mlich stehen zur Optimierung von Regeln kommunikative Ans?tze zur Verfügung, die der Gesetzgeber nicht nutzen darf oder kann.