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91.
A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl4, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present work is close to 7 nm.  相似文献   
92.
93.
Joshua Israelsohn 《电子设计技术》2005,12(7):68-68,70,72,74-75
几乎所有电子OEM领域的功能密度正在日益增长,使宝贵的硅片更易于受到真实世界的损害。采取花钱较少的简单措施,就可以保护您的产品和您公司的声望,还能在极端情况下保护您的客户。  相似文献   
94.
There are many variables in the preparation of aqueous polyurethane (PU) dispersions. Carboxylic acid content, solid content, degree of pre/postneutralization of the carboxylic acids, and chain extension all impact dispersion particle size, viscosity, pH, molecular weights, and glass transition temperature. This study evaluated the impact of these variables on a given PU dispersion formulation prepared from isophorone diisocyanate, an aliphatic polyester polyol, dimethylol propionic acid, and hexamethylene diamine with triethyl amine as the neutralizing base and N‐methyl pyrrolidone as the cosolvent. Changes in carboxylic acid content, degree of preneutralization, and chain extension were found to have the expected impacts on dispersions properties. Increased ionic content in the dispersion step led to lower particle size and higher viscosity, increased chain extension with its concurrent increase in molecular improved subsequent film properties. Surprising results were obtained by varying the amount of postneutralization and from increased solids content at the time of dispersion. Unexpectedly, both of these variations led to much higher dispersion viscosities and particle size in solution. To have these changes take place, it is theorized that there is a major change in solution morphology caused by these modifications. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2514–2520, 2005  相似文献   
95.
Nanostructured polymer blends prepared via anionic ring opening polymerizations of cyclic monomers in the presence of a pre-made polymer melt exhibit a number of special properties over traditional polymer blends and homopolymers. Here, we report on a simple and versatile method of in situ polymerization of macrocyclic carbonates in the presence of a maleic anhydride polypropylene (mPP) matrix and a surface-active compatibilizer (i.e. PC grafted onto a mPP backbone generated in situ) to yield a micro- and nanostructured polymer blends consisting of a polycarbonate (PC) minor phase, and a polypropylene (PP) major phase. By varying the processing conditions and concentration of the macrocyclic carbonate it was possible to reduce the size of the PC dispersions to an average minor diameter of 150 nm. NMR and TEM characterizations indicate that the PC dispersions do not influence crystal content in the PP phase. Overall, the results point to a simple strategy and versatile route to new polymeric materials with enhanced benefits.  相似文献   
96.
It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established.  相似文献   
97.
Some approximate solutions for predicting the stress intensity factor of a short crack penetrating an inclusion of arbitrary shape have been developed under mode I and mode II loading conditions. The derivation of the fundamental formula is based on the transformation toughening theory. The transformation strains in the inclusion are induced by the crack-tip field and remotely applied stresses, and approximately evaluated by the Eshelby equivalent inclusion theory. As validated by detailed finite element (FE) analyses, the developed solutions have good accuracy for different inclusion shape and for a wide range of modulus ratio between inclusion and matrix material.  相似文献   
98.
An overview of nondestructive evaluation methods   总被引:1,自引:0,他引:1  
ondestructive evaluation is described as nondestructive testing (NDT), nondestructive inspection (NDI), and nondestructive examination (NDE). The activities associated with the evaluation include testing, inspection, and examination and primarily involve looking at (or through) and/or measuring some characteristic of an object. Frequently there is a desire to determine some characteristic of the object or to determine whether the object contains irregularities, discontinuities, or flaws. These examinations, inspections, or tests are used to determine the physical soundness of a material without impairing its usefulness. Nondestructive evaluation is a powerful tool that can help assure safety, quality, and reliability; increase productivity; decrease liability; protect the environment; and save money. In this article, nondestructive evaluation is represented by the acronym NDE.  相似文献   
99.
Nanocrystalline LaFeO3 is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO3 nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size.  相似文献   
100.
Functionalized polyanilines containing biphenyl, terphenyl, carbazole, anthracene, and 4-n-hexylphenyl moieties were synthesized though the reaction of polyaniline in emeraldine base form with sodium salt of corresponding vinylketoaromatics with quantitative yields. Polymers were characterized with Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and thermogravimetry. The emission characteristics of these polymers in N-methyl-2-pyrrolidone solution were examined. The functionalized polyanilines exhibited an intense green emission.  相似文献   
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