Optimizing Chain Topology of Bottle Brush Copolymer for Promoting the Disorder-to-Order Transition

The order-disorder transitions (ODT) of core-shell bottle brush copolymer and its structural isomers were investigated by dissipative particle dynamics simulations and theoretically by random phase approximation. Introducing a chain topology parameter λ which parametrizes linking points between M diblock chains each with N monomers, the degree of incompatibility at ODT ((χN)ODT; χ being the Flory–Huggins interaction parameter between constituent monomers) was predicted as a function of chain topology parameter (λ) and the number of linked diblock chains per bottle brush copolymer (M). It was found that there exists an optimal chain topology about λ at which (χN)ODT gets a minimum while the domain spacing remains nearly unchanged. The prediction provides a theoretical guideline for designing an optimal copolymer architecture capable of forming sub-10 nm periodic structures even with non-high χ components.     

Enhanced heat transfer performance of alumina sponge-like nano-porous structures through surface wettability control in nucleate pool boiling

For several decades, a porous surface has been recognized as an efficient medium to increase boiling performance in a nucleate boiling regime. Most feasible porous surfaces have been studied in millimeter and micron-sized domains. It has been believed that a higher wall superheat is required to commence incipient nucleate boiling under a submicron regime. In this study, we demonstrate that a significantly enhanced pool boiling heat transfer is observed in a submicron regime through three dimensionally interconnected hybrid pores: the Alumina sponge-like nano-porous structure (ASNPS). The structural uniqueness of the ASNPS leads to an enlarged surface area, increases the potential number of the active nucleation site density, and improves the vapor–liquid menisci through the reentrant pore. Simultaneously, by changing the surface wettability with a hydrophobic self-assembled monolayer (SAM) coating, the number of active nucleation site density is improved. Eventually, the combination of the ASNPS and hydrophobic SAM coating can achieve substantial heat transfer coefficient (HTC) enhancement in the nucleate boiling. Also, the thickness of the ASNPS is a critical issue to adequately augment the HTC in pool boiling. The thickness of the ASNPS is optimized by examining the boiling performance of the ASNPS fabricated in different amounts of anodizing times. A classical mechanistic model from literature was modified and compared with the experimentally obtained data. The modified mechanistic model – with the combination of forced-convection and thin liquid film evaporation – showed reasonable predictions.     

Cartier手工的秘密

<正>从绘制草图、铸模、雕琢、镶嵌到成型,一件闪耀的卡地亚高级珠宝,需要几千小时甚至更多时间才能诞生。顶级珠宝的背后,到底有怎样的手工秘密?和平街是巴黎最时尚美丽的街道,1897年,当卡地亚创始人阿尔弗雷德·卡地亚将店址定于和平街13号,百余年来,它从没对外关闭过敞开的大门,也未曾拒绝过任何一位进店的顾客。但顺着深红色地毯延伸而至的阁楼,却不是人人都有幸能进入。内行人说,那是神秘的卡地亚高级珠宝工作坊的所在地。     

Local stiffness control for reducing vehicle interior noise by using FRF-based synthesis method

This paper explores the feasibility of estimating the interior noise of a vehicle compartment when the attachment stiffness (i.e., the local stiffness of the mounting point at which operational force is applied) is altered. In order to change the local stiffness of the vehicle body, it was assumed that the local stiffness could be changed by attaching some additional systems to the vehicle body. The frequency response function (FRF)-based synthesis method is used herein to estimate the change in the local stiffness of the modified vehicle body. In addition, the change in the noise transfer function (NTF) can also be estimated using this method. Since the operational force transmitted from the source excitation to the body attachment is required to predict the interior noise of the vehicle body in the operational condition, a transfer path analysis (TPA) technique was performed. Various vehicles and additional systems were utilized to estimate the dynamic properties of the modified vehicle body. Results indicated that the synthesis technique is an appropriate method to estimate the change in the local stiffness and NTF of the modified vehicle body. The results also show that the interior noise of the body can be estimated accurately by using the synthesis technique and TPA procedure when the vehicle body is locally modified.     

Structural parameters identification using improved normal frequency response function method

An improved method that is based on a normal frequency response function (FRF) is proposed in this study in order to identify structural parameters such as mass, stiffness and damping matrices directly from the FRFs of a linear mechanical system. This paper demonstrates that the characteristic matrices may be extracted more accurately by using a weighted equation and by eliminating the matrix inverse operation. The method is verified for a four degrees-of-freedom lumped parameter system and an eight degrees-of-freedom finite element beam. Experimental verification is also performed for a free–free steel beam whose size and physical properties are the same as those of the finite element beam. The results show that the structural parameters, especially the damping matrix, can be estimated more accurately by the proposed method.     

A new synthesis procedure for titanium-containing zeolites under strong alkaline conditions and the catalytic activity for partial oxidation and photocatalytic decomposition

A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H₂O₂ as an oxidant and the photocatalytic decomposition of trichloroethene using water.     

Ontogeny of the testicular excurrent duct system of male Japanese quail (Coturnix japonica): A histological,ultrastructural, and histometric study

The testicular excurrent duct system undergoes several physiological and morphological changes during the reproductive stage or breeding season in mammals, birds, and reptiles. Studies on normal age-related histomorphological changes in the excurrent duct system of Japanese quails (Coturnix japonica) remain unreported, despite the extensive use of this bird as an avian model in research studies. The current study investigated the histological, ultrastructural, and histometric changes in the testicular excurrent duct system of the Japanese quail during three reproductive stages, namely prepubertal, pubertal, and adult. Simple squamous to low cuboidal cells formed the epithelia of the rete testis in prepubertal and pubertal birds, while in adult birds the lining was low cuboidal to cuboidal. In pubertal and adult birds, the nonciliated Type I epithelial cells of the proximal efferent duct displayed a subapical endocytotic apparatus comprising coated pits, coated apical tubules, and endosomes. There was a significant increase (p ≤ .001) in epithelial heights of all ducts of the excurrent duct system in the mature, sexually active, adult birds when compared to the other age groups. The luminal and tubular diameters, and the cross-sectional areas of efferent ducts and the epididymal duct unit increased significantly (p ≤ .001) with age. It is concluded that the morphology and morphometry of the excurrent ducts of the testis of the Japanese quail change as birds mature.     

Effect of contact angle and drop spacing on the bulging frequency of inkjet-printed silver lines on FC-coated glass

The morphologies of inkjet-printed narrow silver lines on fluorocarbon film-coated glass substrates were measured with varying contact angles and drop spacing to study the actual stability of line printing by using a practical inkjet system. From a practical stability point of view, three types of the lines were observed: stable, unstable, and meta-stable. The stable lines were free from any bulging or breaking; the unstable lines had repetitive and periodic instabilities; and the meta-stable lines had no repetitive instability but had irregular bulges that appear sparsely. Unstable line printing resulted from either the dynamic or static instability of bead flow, which arose when the pressure-driven bead flow was too large or too small compared with droplet deposition rate, respectively. Whether the printing would be stable or meta-stable was determined by the anti-bulging stability of the flow against other disturbances. The anti-bulging stability increased when the bead flow rate was balanced with the printing rate, whereas it decreased for the present system when the flow-balance became sensitive to drop spacing.     

CO hydrogenation over potassium-promoted Fe/carbon catalysts

The effects of potassium on the catalytic behavior in CO hydrogenation over K-promoted Fe/carbon catalysts having low K/Fe ratios were investigated. Even though the doses of potassium were low the promotional effects were pronounced, especially on the olefin-to-paraffin ratio, and theC ₃ toC ₄ olefin selectivities of the K-promoted catalysts were as high as 51 to 66 mol%. Over the catalysts having no or low potassium content the olefin-to-paraffin ratio and the ratio of the CO₂ formation rate to the rate of CO conversion to hydrocarbons remained roughly the same regardless of temperature, while over the K-promoted catalysts having higher potassium content they increased with temperature. Formation of significant amounts of filamentous carbon was observed in the K-promoted catalysts; however, the carbon deposition did not appear to affect the inherent activity and selectivity of the K-promoted catalysts.     

A cross-sectional analysis of composite beams based on asymptotic framework

This paper presents the accurate prediction of static behavior of composite beams with arbitrary cross-sections. The asymptotic recursive formulation is reviewed first, where the initial three-dimensional problems are split into the macroscopic 1D problems and the microscopic 2D problems. The finite element formulation for the microscopic 2D problems is then presented in order to find the crosssectional warping solutions. The warping solutions obtained contribute the cross-sectional properties to the macroscopic 1D problems. The end effect of the 1D beam problem is also considered via the kinematic correction for a displacement prescribed boundary. The approach presented is applied to the beams with relatively complicated material distributions and cross-sectional geometry. As numerical test-beds, a three-layered sandwich beam and a composite beam with the multi-cell cross-section are taken to analyze the local deformation. A parametric study is also carried out to investigate the significance of shear deformation due to the cross-sectional orthotropic characteristics. The cross-sectional deformation is predicted based on the asymptotic framework. The accuracy of the present approach is assessed by comparing the results obtained with the 3D FEM solutions obtained by ANSYS.