Assessment of EU policy: Implications for the implementation of autonomous desalination units powered by renewable resources in the Mediterranean region

Small-scale autonomous desalination systems (ADS) powered by renewable energy are ideal for implementation in arid or semi-arid regions like the Mediterranean, especially in remote coastal or inland locations. The technology has made significant progress but wide scale implementation may face administrative barriers. This paper analyses the possible barriers imposed on ADS by the Water Framework Directive, the Drinking Water Directive, the EU Water Initiative, the European Mediterranean Partnership, and the European Neighbourhood Policy. It has been found that ADS developers have to comply with unnecessary strict regulations that apply to all drinking water supplies, while the consumers and the environment are not adequately protected from possible effects of desalination. A careful review of the relevant directives and standards has to be undertaken and adapt the documents to prepare for widespread use of ADS. On the other hand, there is widespread support for ADS within EU policy, mainly in the form of support for non-conventional water resources as well as for sustainable and rural development. The ADS community has to make use of this support and form a technology platform that will convince decision makers to improve policy and institutional framework conditions and will raise general awareness on the ADS benefits.     

Fluorogenic polydiacetylene supramolecules: immobilization, micropatterning, and application to label-free chemosensors

This Account describes a new strategy for the preparation of label-free sensor systems based on the fluorogenic properties of the conjugated polymer, polydiacetylene (PDA). PDA has been extensively investigated as a sensor matrix, owing to a brilliant blue-to-red color transition that takes place in response to environmental perturbations. It has been known for some time that "blue-phase" PDAs are nonfluorescent while their "red-phase" counterparts fluoresce. For the most part, however, the significance of the different fluorogenic properties of PDAs has been ignored in the context of sensor applications. In the course of developing PDA-based sensors, we discovered that PDA vesicles can be readily immobilized on solid substrates. This is an attractive property of PDAs since it leads to the combined advantages of the vesicle sensors (which have three-dimensional interactions between sensor and target molecules) and film sensors (which are applicable to a two-dimensional array or chip format). Stable blue-phase immobilized PDAs can be prepared by employing one of three strategies involving the formation of covalent adducts, biotin-avidin complexes, or complexes formed through nonspecific physical adsorption. A procedure for generating well-patterned fluorescence images is necessary for the immobilized PDAs to function in chip-based sensor systems. Patterned fluorescence images are readily constructed by employing (1) the photolithographic technique, (2) the micromolding in capillaries (MIMIC) method, or (3) an array spotting system. Heat treatment of the patterned "blue-phase" PDA vesicles transforms the nonfluorescent images into their fluorescent red forms. The observation that finely resolved fluorescence patterns can be generated by heat treatment of microarrayed PDAs is highly significant in that it indicates that fluorescence signals might be produced by specific molecular recognition events. Indeed, red fluorescence emission is observed when immobilized PDAs are subjected to specific molecular recognition events, such as ligand--cyclodextrin or protein-protein interactions. The facile immobilization of PDA vesicles on solid substrates and the affinity-induced fluorescence emission combine to make this system applicable to the fabrication of label-free PDA sensors. Since in theory any molecular recognition event that promotes the blue-to-red color transition of PDAs should result in the generation of fluorescence, it should be possible to reformat a variety of previously described colorimetric PDA sensors into fluorescence-based sensor systems. The fluorescence properties of PDAs, when combined with modern methods for the fabrication of microarrays, should stimulate the development of a number of new label-free chemosensor systems.     

Mode change design for capacity modulation in reciprocating compressor

Due to environmental issues, the development of low energy consumption products has become one of the main topics in the home appliance industry. The energy consumption of a refrigerator depends on the efficiency of its compressor as well as on the refrigerator cycle design, such as the capacity modulation. This study features the design of a novel capacity modulation reciprocating compressor, i.e., two-step capacity modulation (TCM). In a TCM compressor, capacity modulation is achieved by changing the dead volume in the cylinder. Instead of a concentric sleeve, an eccentric sleeve is used to change the dead volume for the clockwise and counterclockwise rotation of a motor. For stable capacity modulation, a new latching system with a key, a spring, and an eccentric sleeve is introduced, and the mode change reliability is verified by dynamic analysis.