Assessment of four different cathode materials at different initial pHs using unbuffered catholytes in microbial electrolysis cells

Nickel foam (NF), stainless steel wool (SSW), platinum coated stainless steel mesh (Pt), and molybdenum disulfide coated stainless steel mesh (MoS₂) electrodes have been proposed as catalysts for hydrogen gas production, but previous tests have primarily examined their performance in well buffered solutions. These materials were compared using two-chamber microbial electrolysis cells (MECs), and linear sweep voltammetry (LSV) in unbuffered saline solutions at two different initial pHs (7 and 12). There was generally no appreciable effect of initial pH on production rates or total gas production. NF produced hydrogen gas at a rate of 1.1 m³ H₂/m³·d, which was only slightly less than that using Pt (1.4 m³ H₂/m³·d), but larger than that obtained with SSW (0.52 m³ H₂/m³·d) or MoS₂ (0.67 m³ H₂/m³·d). Overall hydrogen gas recoveries with SSW (29.7 ± 0.5 mL), MoS₂ (28.6 ± 1.3 mL) and NF (32.4 ± 2 mL) were only slightly less than that of Pt (37.9 ± 0.5 mL). Total energy recoveries, based on the gas produced versus electrical energy input, ranged from 0.75 ± 0.02 for Pt, to 0.55 ± 0.02 for SSW. An LSV analysis showed no effect of pH for NF and Pt, but overpotentials were reduced for MoS₂ and SSW by using an initial lower pH. At cathode potentials more negative than −0.85 V (vs Ag/AgCl), NF had lower overpotentials than the MoS₂. These results provide the first assessment of these materials under practical conditions of high pH in unbuffered saline catholytes, and position NF as the most promising inexpensive alternative to Pt.     

Reservoir Inflow Monitoring for Improved Management of Treated Water Quality—A South Australian Experience

Large tributary inflows into water supply reservoirs caused by heavy catchment rain may be of concern due to problems associated with high levels of natural organic matter (NOM) present in the inflows. The movement of these inflows within a reservoir is dependent on its relative density to the receiving waters. For example, if the inflow is denser (colder) than the recipient water it will travel along the base of the reservoir as an underflow and can penetrate as far as the dam wall water off-take to a water treatment plant (WTP). Field studies were conducted to track the passage of underflows through two South Australian reservoirs, Little Para and Myponga. Samples were collected before and during storm event inflows and analyses undertaken to determine NOM concentration, alum demand, disinfection by-product formation potential, and quality of the water. We demonstrate that by monitoring the movement of inflows into reservoirs, combined with changes in reservoir off-take levels, that the risk of NOM entering a water treatment plant can be reduced which in turn will lower water treatment costs by reducing alum dosing levels and lessen the risk to human health by reducing disinfection by-product formation.     

Application of nanosilver surface modification to RO membrane and spacer for mitigating biofouling in seawater desalination

Biofouling is one the most critical problems in seawater desalination plants and science has not yet found effective ways to control it. Silver compounds and ions are historically recognized for their effective antimicrobial activity. Nanosilver particles have been applied as a biocide in many aspects of disinfection, including healthcare products and water treatment. This study proposes an innovative biofouling control approach by surface modification of the RO membrane and spacer with nanosilver coating. A chemical reduction method was used for directly coating nanosilver particles on the membrane sheet and spacer. The surface-modified membrane and spacer were tested for their antifouling performance in a cross-flow flat-sheet membrane cell, which is a part of a pilot plant in Wukan desalination plant. The silver-coating membranes and spacers, along with an unmodified membrane sheet, were tested in the membrane cell and compared on the basis of their antifouling performance. Permeate flux decline and salt rejection was continuously monitored through the testing period. Meanwhile regrowth of microbial populations on the membrane cell was quantified by a unique microbial counting every three to four days. The results showed that both silver-coated membrane (Ag-cM) with uncoated spacer and silver-coated spacer (Ag-cS) with uncoated membrane perforemed better than the unmodified membrane and spacer (Un-MS), in terms of much slower decrease in permeate flux and TDS rejection. However, the effect of silver-coated spacer on antimicrobial activity was more lasting. In the silver-coated spacer test, there was almost no multiplication of cells detected on the membrane during the whole testing period. Besides, the cells adhering to the membrane seemed to lose their activity quickly. According to the RO performance and microbial growth morphology, the nanosilver coating technology is valuable for use in biofouling control in seawater desalination.     

Olefin Metathesis for Site‐Selective Protein Modification

Protein compatible . Olefin metathesis has emerged as a viable strategy for site‐selective protein modification. This minireview traces its development from early peptide models and metathesis in water to its ultimate application to protein substrates. Prospects in chemistry and biology are also discussed.

     

可热插拔的可编程逻辑器件提高系统高效性

互联网的兴起、无线通信和存储业的发展促进了实时数据业务的快速增长,系统的高效性成为其关键的需求,每个下一代系统的延迟会直接影响到利润的损失.系统设计为可热插拔性能够维持零系统延迟.热插拔是指在系统运行期间把板子插入背板或拔出背板而不会对主系统造成不良影响的能力,综也指热切换或热插入.     

Development and validation of a rapid real-time PCR based method for the specific detection of Salmonella on fresh meat

In this study, a combined enrichment/real-time PCR method for the rapid detection of Salmonella on fresh meat carcasses, was designed, developed and validated in-house following requirements outlined in ISO 16140:2003. The method included an 18 h non-selective enrichment in buffered peptone water (BPW) and a 6 h selective enrichment in Rappaport Vasilliadis Soya (RVS) broth, based on the traditional culture method, ISO 6579:2002. The real-time PCR assay included an internal amplification control (IAC), was 100% specific and was sensitive to one cell equivalent. The alternative method was validated against the traditional culture method and relative accuracy of 94.9%, sensitivity of 94.7% and specificity of 100% were determined using 150 fresh meat carcass swabs. This alternative method had a detection limit of 1–10 CFU/100 cm² for fresh meat carcass swabs and was performed in 26 h. Following further inter-laboratory studies, this alternative method could be suitable for implementation in testing laboratories for the analysis of carcass swabs.     

Brief Historical Perspective in Thermal Management and the Shift Toward Management at the Nanoscale

Since the early days of computing, excess heat has been a major road block in the design and development of faster, more efficient, and more compact electronic devices. Coupled with improvements in thermal management has been a reduction in the size of major electronic components, primarily transistors. This has expanded the field of thermal management down into the nanoscale, where the “rules” of thermal transport become more complicated. This paper presents a brief perspective on the historical challenges in thermal management and outlines the major length scale regimes where thermal management is being developed. In particular, the expansion of thermal management into the nanoscale is presented due to the consequence that as the feature size of most nano-devices continues to diminish, the impact of thermal transport across solid-solid interfaces on device performance, reliability, and lifetime becomes increasingly important.     

Extrusion modifies some physicochemical properties of milk protein concentrate for improved performance in high‐protein nutrition bars

BACKGROUND

Extruded and ground milk protein concentrate powders, specifically those with 800 g kg^–1 protein (i.e. MPC80), imparted softness, cohesion and textural stability to high‐protein nutrition (HPN) bars. The present study evaluated some physicochemical properties of extruded and conventionally produced (i.e. spray‐dried) MPC80 to explain these improvements. Protein chemical changes and aggregations within MPC80‐formulated HPN bars during storage were characterized.

RESULTS

Extruded MPC80 powders had broader particle size distribution (P < 0.05) and smaller volume‐weighted mean diameter (P < 0.05) than the spray‐dried control. Loose, tapped and particle densities increased (P < 0.05) and correspondingly occluded and interstitial air volumes decreased (P < 0.05) after extruding and milling MPC80. Extrusion decreased water holding capacity (P < 0.05) and solubility (P < 0.05), yet improved the wettability (P < 0.05) of MPC80. MPC80 free sulfhydryl (P < 0.05) and free amine (P < 0.05) concentrations decreased after extrusion. Sulfhydryl and amine concentrations changed (P < 0.05) and disulfide‐linked and, more prominently, Maillard‐induced aggregates developed during HPN bar storage.

CONCLUSION

Extrusion and milling together changed the physicochemical properties of MPC80. Chemical changes and protein aggregations occurred in HPN bars prepared with either type of MPC80. Thus, the physicochemical properties of the formulating powder require consideration for desired HPN bar texture and stability. © 2017 Society of Chemical Industry     

Floating membraneless PV-electrolyzer based on buoyancy-driven product separation

This paper describes the design and performance of a scalable, stand-alone photovoltaic (PV) electrolysis device used for hydrogen (H₂) production by solar-driven water electrolysis. The electrolyzer component of this device is based on a simple, membraneless design that enables efficient operation with high product purity and without active pumping of the electrolyte. Key to the operation of this PV-electrolyzer is a novel electrode configuration comprised of mesh flow-through electrodes that are coated with catalyst on only one side. These asymmetric electrodes promote the evolution of gaseous H₂ and O₂ products on the outer surfaces of the electrodes, followed by buoyancy-driven separation of the detached bubbles into separate overhead collection chambers. The successful demonstration of this concept was verified with high-speed video and analysis of product gas composition with gas chromatography. While the device based on asymmetric electrodes achieved product cross-over rates as low as 1%, a control device based on mesh electrodes that were coated on both sides with catalyst had cross-over rates typically exceeding 7%. The asymmetric electrode configuration was then incorporated into a standalone, floating PV-electrolyzer and shown to achieve a solar-to-hydrogen efficiency of 5.3% for 1 sun illumination intensity. The simplicity of this membraneless prototype, as characterized by the lack of a membrane, scaffolding, or actively pumped electrolyte, makes it attractive for low-cost production of hydrogen.     

Structural elucidation and quantification of phenolic conjugates present in human urine after tea intake

In dietary polyphenol exposure studies, annotation and identification of urinary metabolites present at low (micromolar) concentrations are major obstacles. To determine the biological activity of specific components, it is necessary to have the correct structures and the quantification of the polyphenol-derived conjugates present in the human body. We present a procedure for identification and quantification of metabolites and conjugates excreted in human urine after single bolus intake of black or green tea. A combination of a solid-phase extraction (SPE) preparation step and two high pressure liquid chromatography (HPLC)-based analytical platforms was used, namely, accurate mass fragmentation (HPLC-FTMS(n)) and mass-guided SPE-trapping of selected compounds for nuclear magnetic resonance spectroscopy (NMR) measurements (HPLC-TOFMS-SPE-NMR). HPLC-FTMS(n) analysis led to the annotation of 138 urinary metabolites, including 48 valerolactone and valeric acid conjugates. By combining the results from MS(n) fragmentation with the one-dimensional (1D)-(1)H NMR spectra of HPLC-TOFMS-SPE-trapped compounds, we elucidated the structures of 36 phenolic conjugates, including the glucuronides of 3',4'-di- and 3',4',5'-trihydroxyphenyl-γ-valerolactone, three urolithin glucuronides, and indole-3-acetic acid glucuronide. We also obtained 26 h-quantitative excretion profiles for specific valerolactone conjugates. The combination of the HPLC-FTMS(n) and HPLC-TOFMS-SPE-NMR platforms results in the efficient identification and quantification of less abundant phenolic conjugates down to nanomoles of trapped amounts of metabolite corresponding to micromolar metabolite concentrations in urine.