A study of a water-reducing agent from cashew nutshell liquid

The water-reducing agent better known as superplasticizer is a recent development. A number of base materials have been used for the development of such water-reducing agents which can act better than ordinary plasticizers in concrete. The sulphonated salts of melamine, napthalene, lignin, hydroxycarboxylic acids and hydroxylated polymers are some typical compounds. Recently cashew nutshell liquid obtained from a natural product waste as a thick black phenolic compound has been converted into a water-reducing agent. This paper describes the results obtained on its effectiveness in influencing the rheological properties of flow, viscosity, particle size distribution, etc, of cement particles in hydrating cements and the water-reducing capabilities in cement mortars and concretes.     

Effect of agitation, turbidity, aluminium foil reflectors and container volume on the inactivation efficiency of batch-process solar disinfectors

We report the results of experiments designed to improve the efficacy of the solar disinfection of drinking water, inactivation process. The effects of periodic agitation, covering the rear surface of the container with aluminium foil, container volume and turbidity on the solar inactivation kinetics of Escherichia coli (starting population = 10(6) CFU ml(-1)) were investigated. It was shown that agitation promoted the release of dissolved oxygen from water with subsequent decrease in the inactivation rates of E. coli. In contrast, covering the rear surface of the solar disinfection container with aluminium foil improved the inactivation efficiency of the system. The mean decay constant for bacterial populations in foil-backed bottles was found to be a factor of 1.85 (std. dev. = 0.43) higher than that of non-foil-backed bottles. Inactivation rates decrease as turbidity increases. However, total inactivation was achievable in 300 NTU samples within 8 h exposure to strong sunshine. Inactivation kinetics was not dependent on the volume of the water container for volumes in the range 500-1500 ml.     

Reinforcement of foundations as part of reconstruction of the stebnikov potash plant

The effectiveness of using drilled injection piles to reinforce foundations while reconstructing an operating plant without shutting it down was shown.Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 14–17, July–August, 1992.     

Limit analysis of reinforced concrete cylindrical shell roofs

Two approximate yield criteria are proposed for reinforced concrete cylindrical shell element. Three lower bound solutions are developed for cylindrical shell roofs with free longitudinal edges. Two shells with different geometric parameters are analysed. Elastic analysis is also done at working load. Graphs are presented to show the variation of stress resultants at critical sections.     

Determination of labile and strongly bound metals in lake water

Differential pulse anodic stripping voltammetry is applied to differentiate and determine the labile and strongly bound forms of Zn, Cd, Pb and Cu in lake water without preconcentration of the sample. The sensitivities as established for an oxidation peak current of 0·020 μA are: 0·2 ppb for Zn. 0·4 ppb Cd. 0·7 ppb Pb and 0·5 ppb for Cu. For the analysis of a lake water containing 5·0–24·5 ppb of the four metals, the relative S.D. ranged from 1·6 to 10 per cent. Interferences of cations and anions and the choice of a buffer system have been discussed. The method has been applied to study a number of small lakes in the Sudbury area. Ontario.     

Oxygen consumption and activity of the white sucker (Catostomus commersoni), in lethal and nonlethal levels of the organochlorine insecticide, methoxychlor

The survival, oxygen consumption and spontaneous activity of suckers were determined at 15°C in water containing different concentrations of methoxychlor in ethanol, ethanol, and no added substances. A dynamic bioassay was used to estimate the 96 h LC50, which was found to be 0·0345 ppm. Routine oxygen consumption was determined in a continuous-flow respirometer, and the activity was recorded in separate experiments by measuring the water disturbance using silver wire electrodes.After 24 h fish exposed to untreated, ethanol-treated and 0.01 ppm methoxychlor-treated water had oxygen uptake rates which were relatively constant and near standard levels. At 0.10 ppm methoxychlor (lethal to all fish within 85 h), oxygen consumption rates were 2–3.5 × as high as those of control fish. Activity also greatly increased. The fish lost their balance along with the coordination between opercular and locomotor movements. Suckers that died in 0.04 ppm methoxychlor showed oxygen uptake rates and poisoning symptoms similar to 0.10 ppm treated fish, while those that survived this treatment had rates similar to control fish. The increase in ventilation which accompanies this hyperactivity may result in increased uptake of insecticide and thereby explain the irreversible nature of the response.