Martensitic transformation in alloys of the system TiNi-TiCu prepared by ultrarapid melt cooling

Conclusion In alloys of the TiNi-TiCu system prepared in the form of thin tapes by ultrarapid melt cooling the B2-phase, which is unstable towards martensitic transformation B2B19, contains up to 35% Cu, whereas in bulk alloys prepared in the form of an ingot cooled at normal rates it contains about 10% Cu close to the M_S. In alloys containing up to 35% Cu there are no untransformed brittle phases preventing development of martensitic transformation throughout the volume of the material. The structure of alloys is quite uniform, particularly those obtained by crystallizing from the amorphous condition, and the grain size of the high-temperature phase is a fraction of a micron. The fine structure of alloys close to a globular at a high cooling rate. Thus, range of practically important alloys of the B2 type with inelastic behavior effects, e.g., the shape memory effect, is considerably expanded.Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 11, pp. 38–41, November, 1988.     

Pharmacokinetics of anthracycline antibiotics deposited by polymers

An increase of doxorubicin concentration in different organs and tissues and its decrease in the peripheral blood were observed when studying pharmacokinetics of this drug administered in the 10% solution of polyvinylpyrrolidone. A prolonged and stable release of carminomycin from glue composition MK-10-0 "carminacryl" confirms an expediency of alpha-cyanoacrylate use for deposition of anthracycline antibiotics with the aim of loco-regional chemotherapy.     

Laser glazing of an Fe-C-Sn alloy

Morphology and geometry of melted zones, cooling rates, microstructure and microhardness in the laser-glazed Fe-4%C-10%Sn alloy have been investigated. The computer simulation on the basis of the moving gaussian source model was used successfully to predict the maximum width and depth of the melted zone and the cooling rate. The microstructure from the surface to the bottom of the laser-melted zone is a non-crystalline phase, dendritic grains and a microcrystalline zone successively. Values of the averaged-spacing of the non-crystalline phase are 0.205⁶ and 0.121⁹nm, respectively; twinned martensites, having an axial ratioc/a of 1.128, existed in dendritic grains, and carbides of Fe₃ C at the interdendritic regions; the microcrystalline zone was composed of -Fe and a new bet (a=0.415 nm,c=0.955 nm) phase. The different microstructure in the melted zone can be explained by the results of the heat flow calculation. A fine eutectic structure (-Fe + Fe₃C) was observed in heat-affected zones. Microhardness of the eutectic structure can be predicted by the empirical relation of fracture stress to the interlamellar spacing of pearlite.     

Solid-liquid phase equilibria of benzene + 2-methyl-2-propanol system under high pressures

Solid-liquid phase equilibria of the benzene + 2-methyl-2-propanol system have been investigated at temperatures from 278 to 323 K and pressures up to 300 MPa using a high-pressure optical vessel. The uncertainties of the measurements of temperature, pressure and composition are within ±0.1 K, ±0.5 MPa, and ±0.001 mole fraction, respectively. The freezing pressure at a constant composition increases monotonously with pressure. The eutectic point shifts to a higher temperature and benzene-rich composition with increasing pressure. In order to describe the pressure-temperature-composition relation of high-pressure solid-liquid phase equilibria, a new simple equation has been proposed as follows:

Experimental determination of dynamic Young's modulus and mechanical damping,and theoretical prediction of dislocation density for depleted uranium-0.75 wt% titanium using the PUCOT

Dynamic Young's modulus (E) and mechanical damping (Q ^–1) measurements were made for three microstructures (, + , and ) of a depleted uranium-0.75 wt% titanium alloy. The temperature range covered was 298 to 1123 K. The apparatus was the piezoelectric ultrasonic composite oscillator technique (PUCOT) operated at 80 kHz. The ranges of values for E and Q ^–1 were 193 to 99 GPa and 3×10^–3 to 8×10^–2, respectively. Correlations for E of each heat treatment as functions of temperature are presented. In addition, the mechanical damping against strain amplitude plots generated from PUCOT data were analysed using the Granato-Luecke zero Kelvin and high-temperature theories of dislocation damping. Computed dislocation densities ranged up to 10¹⁶m^–2.     

Thin-film ferroelectrics of PZT of sol-gel processing

The ferroelectric effect has been demonstrated for sol-gel derived lead zirconate titanate (PZT) (53/47) thin films. The respective values of coercive field and remanent polarization were 4x10(6) V/m and 0.36 C/m(2). The thin-film fabrication process is simple and compatible with Si planar technology, and offers a wide variety of potential uses for counting, memory, and integrated optical circuit applications.     

On finding optimal and near-optimal lineal spanning trees

The search for good lineal, or depth-first, spanning trees is an important aspect in the implementation of a wide assortment of graph algorithms. We consider the complexity of findingoptimal lineal spanning trees under various notions of optimality. In particular, we show that several natural problems, such as constructing a shortest or a tallest lineal tree, are NP-hard. We also address the issue of polynomial-time, near-optimization strategies for these difficult problems, showing that efficient absolute approximation algorithms cannot exist unlessP = NP.     

The incorporation of yield surface distortion into a unified constitutive model,part 2: Predictive capabilities

Summary The MATMOD-4V-DISTORTION model has been derived [1] with the intent of improving the MATMOD-4V model by adding the capability to predict distortions of small strain offset yield surfaces. This model is compared against a variety of experimental data to verify its behavior. Model simulations are compared with experimental data for proportional and nonproportional prestress histories and the effect of yield definition is also investigated. Finally, the same model which predicts a flattening of the yield surface in space is used to predict a rotation of the yield surface in ₁-₂ coordinates.With 9 Figures