低雾化低挥发性汽车用新型聚氨酯泡沫塑料助剂

康普顿公司开发了一系列适用于消除或减少汽车内饰件中胺扩散或雾化的添加剂，其中包括快速、有效的生产用零扩散催化剂和低雾化表面活性剂。该系列添加剂能大大降低泡沫制品中的胺扩散，与异氰酸酯和多元醇原料能组成最佳组合，以保持良好的泡沫物理性能。     

Synthesis and physicochemical characterization of amphiphilic block copolymer self‐aggregates formed by poly(ethylene glycol)‐block‐poly(ϵ‐caprolactone)

Diblock copolymers with different poly(ε‐caprolactone) (PCL) block lengths were synthesized by ring‐opening polymerization of ε‐caprolactone in the presence of monomethoxy poly(ethylene glycol) (mPEG‐OH, MW 2000) as initiator. The self‐aggregation behaviors and microscopic characteristics of the diblock copolymer self‐aggregates, prepared by the diafiltration method, were investigated by using ¹H NMR, dynamic light scattering (DLS), and fluorescence spectroscopy. The PEG–PCL block copolymers formed the self‐aggregate in an aqueous environment by intra‐ and/or intermolecular association between hydrophobic PCL chains. The critical aggregation concentrations of the block copolymer self‐aggregate became lower with increasing hydrophobic PCL block length. On the other hand, reverse trends of mean hydrodynamic diameters were measured by DLS owing to the increasing bulkiness of the hydrophobic chains and hydrophobic interaction between the PCL microdomains. The partition equilibrium constants (K_v) of pyrene, measured by fluorescence spectroscopy, revealed that the inner core hydrophobicity of the nanoparticles increased with increasing PCL chain length. The aggregation number of PCL chain per one hydrophobic microdomain, investigated by the fluorescence quenching method using cetylpyridinium chloride as a quencher, revealed that 4–20 block copolymer chains were needed to form a hydrophobic microdomain, depending on PCL block length. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3520–3527, 2006     

均三甲苯氧化合成间二甲基苯甲酸的宏观动力学

研究了由均三甲苯液相富氧催化氧化制备间二甲基苯甲酸的动力学规律 ,考察了反应时间、温度、通气量和氧浓度等因素对均三甲苯和间二甲基苯甲酸浓度的影响 ,根据双膜理论建立了该反应的宏观动力学模型 ,并由实验数据拟合出模型参数 ,经检验模型计算值能较好地与实验数据相吻合     

Miscibility of poly(methoxymethyl methacrylate) and poly(methylthiomethyl methacrylate) with poly(vinylidene fluoride)

Summary The miscibility behaviour of poly(methoxymethyl methacrylate) (PMOMA) and poly(methylthiomethyl methacrylate) (PMTMA) with poly(vinylidene fluoride) (PVDF) was examined by differential scanning calorimetry. PMOMA/PVDF blend system was judged to be miscible on the bases of the presence of a single, composition-dependent glass transition for the blend and a pronounced melting point depression of the PVDF component. Furthermore, lower critical solution temperature (LCST) behaviour was observed for all PMOMA/PVDF blends. PMTMA/PVDF blends were found to be immiscible. Based on the melting point depression of PVDF in PMOMA/PVDF blends, the interaction parameter B was found to be -14.5 J/cm³.     

改性水性硝化纤维素乳液研究

采用醇酸树脂转相乳化法和丙烯酸酯类单体互穿聚合物网络聚合法制备改性硝化纤维素乳液。研究了醇酸树脂、丙烯酸酯类单体乳化剂用量等因素对乳液性能的影响。结果表明，丙烯酸酯类单体改性互穿聚合物网络聚合法制得的乳液效果好.     

一种多参数优化的联合信源信道编码方法*

针对JPEG2000码流的渐进传输特性,提出了一种多参数优化的联合信源信道编码方法,即MPO-JSCC。在码率分配的基础上,动态地选择Turbo码交织长度、迭代译码次数,通过优化编码器多个参数更好地执行不等差错保护策略,同时加入JPEG2000容错工具,在接收端利用错误掩藏机制以提高图像解码成功率。将该方法应用于噪声信道的图像传输系统中,仿真结果表明,MPO-JSCC既能在不增加系统复杂度及延迟时间的同时提高重建图像的质量,又能节省系统发射功率,具有一定的现实指导意义。     

基于一次反馈的色彩-空间图像检索技术研究

基于颜色-空间二维直方图的图像检索方法简便易行,检索效率较高,但此方法对图像主体的检索不够突出,对检索精度造成了一定的影响.基于一次反馈的色彩-空间图像检索技术,在传统的色彩-空间的图像检索技术中加入了检索者对于检索结果的判断,通过检索者的一次反馈要求,选择是否进行图像的二次筛选,即结合人的智能识别来提高搜索精度,从而...     

基于数字化控制的核电站反应堆功率控制系统

秦山一期工程300 MW反应堆控制棒控制和棒位监测系统（以下简称反应堆功率控制系统）采用基于PLC技术、数字化通信技术以及冗余技术设计,实现了反应堆功率的自动调节和集中控制.本文对反应堆功率控制的仪控系统特点及其数字化改造的硬件设计方法进行了介绍.数字化改造后的秦山一期工程反应堆功率控制系统能为人机交互作业提供丰富的信息,方便了系统的运行和维护,系统的可靠性得以极大改善.     

基于照度补偿的人脸图像遮挡阴影消除处理*

为了消除人脸图像中的遮挡阴影对识别精度的影响,采用数学形态学处理对阴影进行检测分离,根据其照度损失不同划分为阴影边缘区和阴影主体区,分别实施照度补偿,并将非阴影区、阴影边缘区和阴影主体区光强光顺过渡,实现对图像阴影区域的恢复处理。基于该照度补偿原理处理实例表明,该方法可以较好地去除人脸图像中部因遮挡造成的阴影,显著改善图像质量。     

电子商务配送速度与客户退单的关联建模仿真

在电子商务中,产品的配送速度与客户的退单率之间存在着较为复杂的关联性,这种关联性受到所在地域、购买时间、运输能力、订单处理能力、人为因素等多方因素的影响十分复杂.传统的建模方法只能利用多个简单的线性关系进行描述,加入了更多的复杂约束过程的描述,模型复杂,无法准确反映两者关系.为解决上述问题,提出基于PLS_SEM算法的电子商务中产品的配送速度与客户退单的关系建模方法.根据PLS_SEM算法的构建复杂模型特有的优势,建立电子商务客户退单评价模型,并利用退单校验因子定量分析了电子商务中不同的变量对于客户退单的影响,可以较好地解决模型中存在的过多约束问题,保证建模准确性.仿真结果表明,利用PLS_SEM算法能够实现对电子商务中产品配送速度与客户退单的关系进行准确分析,效果令人满意.